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POTASSIUM SELECTIVITY OF FILM-TYPE VALINOMYCIN MEMBRANES PLASTICIZED WITH PHTHALATES AND ADIPATES. / Mikhel'son, K. N.; Grekovich, A. L.; Materova, E. A.; Dement'eva, L. P.

In: SOVIET ELECTROCHEMISTRY, Vol. 18, No. 9, 1982, p. 1102-1106.

Research output: Contribution to journalArticlepeer-review

Harvard

Mikhel'son, KN, Grekovich, AL, Materova, EA & Dement'eva, LP 1982, 'POTASSIUM SELECTIVITY OF FILM-TYPE VALINOMYCIN MEMBRANES PLASTICIZED WITH PHTHALATES AND ADIPATES.', SOVIET ELECTROCHEMISTRY, vol. 18, no. 9, pp. 1102-1106.

APA

Mikhel'son, K. N., Grekovich, A. L., Materova, E. A., & Dement'eva, L. P. (1982). POTASSIUM SELECTIVITY OF FILM-TYPE VALINOMYCIN MEMBRANES PLASTICIZED WITH PHTHALATES AND ADIPATES. SOVIET ELECTROCHEMISTRY, 18(9), 1102-1106.

Vancouver

Mikhel'son KN, Grekovich AL, Materova EA, Dement'eva LP. POTASSIUM SELECTIVITY OF FILM-TYPE VALINOMYCIN MEMBRANES PLASTICIZED WITH PHTHALATES AND ADIPATES. SOVIET ELECTROCHEMISTRY. 1982;18(9):1102-1106.

Author

Mikhel'son, K. N. ; Grekovich, A. L. ; Materova, E. A. ; Dement'eva, L. P. / POTASSIUM SELECTIVITY OF FILM-TYPE VALINOMYCIN MEMBRANES PLASTICIZED WITH PHTHALATES AND ADIPATES. In: SOVIET ELECTROCHEMISTRY. 1982 ; Vol. 18, No. 9. pp. 1102-1106.

BibTeX

@article{37d22702d1c64f63946534011d2a5c7a,
title = "POTASSIUM SELECTIVITY OF FILM-TYPE VALINOMYCIN MEMBRANES PLASTICIZED WITH PHTHALATES AND ADIPATES.",
abstract = "Potassium selectivity was studied with film-type membranes which contained different valinomycin concentrations and were plasticized with dioctyl phthalate, didecyl phthalate, or dihexyl adipate. The results obtained are in harmony with the concept that the plasticizing solvent is one particular neutral chelating agent. It was reasoned theoretically and confirmed experimentally that a certain limiting selectivity can be attained which will not improve when an even higher valinomycin concentration is used, and which is independent of the type of solvent used. Ionometric data are used to estimate the ratios of formation constants for the valinomycin complexes of potassium, sodium, ammonium, and cesium in different plasticizing solvents.",
author = "Mikhel'son, {K. N.} and Grekovich, {A. L.} and Materova, {E. A.} and Dement'eva, {L. P.}",
year = "1982",
language = "English",
volume = "18",
pages = "1102--1106",
journal = "Russian Journal of Electrochemistry",
issn = "1023-1935",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "9",

}

RIS

TY - JOUR

T1 - POTASSIUM SELECTIVITY OF FILM-TYPE VALINOMYCIN MEMBRANES PLASTICIZED WITH PHTHALATES AND ADIPATES.

AU - Mikhel'son, K. N.

AU - Grekovich, A. L.

AU - Materova, E. A.

AU - Dement'eva, L. P.

PY - 1982

Y1 - 1982

N2 - Potassium selectivity was studied with film-type membranes which contained different valinomycin concentrations and were plasticized with dioctyl phthalate, didecyl phthalate, or dihexyl adipate. The results obtained are in harmony with the concept that the plasticizing solvent is one particular neutral chelating agent. It was reasoned theoretically and confirmed experimentally that a certain limiting selectivity can be attained which will not improve when an even higher valinomycin concentration is used, and which is independent of the type of solvent used. Ionometric data are used to estimate the ratios of formation constants for the valinomycin complexes of potassium, sodium, ammonium, and cesium in different plasticizing solvents.

AB - Potassium selectivity was studied with film-type membranes which contained different valinomycin concentrations and were plasticized with dioctyl phthalate, didecyl phthalate, or dihexyl adipate. The results obtained are in harmony with the concept that the plasticizing solvent is one particular neutral chelating agent. It was reasoned theoretically and confirmed experimentally that a certain limiting selectivity can be attained which will not improve when an even higher valinomycin concentration is used, and which is independent of the type of solvent used. Ionometric data are used to estimate the ratios of formation constants for the valinomycin complexes of potassium, sodium, ammonium, and cesium in different plasticizing solvents.

UR - http://www.scopus.com/inward/record.url?scp=0020176561&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0020176561

VL - 18

SP - 1102

EP - 1106

JO - Russian Journal of Electrochemistry

JF - Russian Journal of Electrochemistry

SN - 1023-1935

IS - 9

ER -

ID: 92362203