Research output: Contribution to journal › Article › peer-review
Post-modified FAU zeolites as efficient catalysts for the synthesis of coumarins. / Zaitceva, O.; Louis, B.; Beneteau, V.; Pale, P.; Shanmugam, S.; Evstigneyev, E. I.; Vasiliev, A. V.
In: Catalysis Today, Vol. 367, 01.05.2021, p. 111 - 116.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Post-modified FAU zeolites as efficient catalysts for the synthesis of coumarins
AU - Zaitceva, O.
AU - Louis, B.
AU - Beneteau, V.
AU - Pale, P.
AU - Shanmugam, S.
AU - Evstigneyev, E. I.
AU - Vasiliev, A. V.
N1 - Funding Information: The authors thank the CNRS, the French Ministry of Research and the Estonia – Russia Cross Border Cooperation Program 2014-2020 , project number is ER30 (BioStyrene). OZ thanks the Russian Science Foundation for her PhD fellowship. Publisher Copyright: © 2020 Elsevier B.V. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.
PY - 2021/5/1
Y1 - 2021/5/1
N2 - Herein, the effect of various treatments subjected to FAU zeolites to introduce mesoporosity has been examined on their efficiency as catalyst in the cyclisation of O-aryl 3-arylpropynoic acid ester to its corresponding coumarin. The addition of bio-sourced lignin residues in the alkaline desilication treatment induced the generation of supplementary mesoporosity, thus offering an optimal micro- and mesopores combination with respect to targeted activity and selectivity. The so-called bio-sourced secondary template (BSST) concept in the design of zeolite-based catalysts could be assessed. The use of renewable wood feedstocks can therefore be a valuable strategy for the zeolite post-modification, thus for the design of porous zeolite catalysts.
AB - Herein, the effect of various treatments subjected to FAU zeolites to introduce mesoporosity has been examined on their efficiency as catalyst in the cyclisation of O-aryl 3-arylpropynoic acid ester to its corresponding coumarin. The addition of bio-sourced lignin residues in the alkaline desilication treatment induced the generation of supplementary mesoporosity, thus offering an optimal micro- and mesopores combination with respect to targeted activity and selectivity. The so-called bio-sourced secondary template (BSST) concept in the design of zeolite-based catalysts could be assessed. The use of renewable wood feedstocks can therefore be a valuable strategy for the zeolite post-modification, thus for the design of porous zeolite catalysts.
KW - Biorefinery
KW - Coumarins
KW - Desilication
KW - FAU
KW - Lignin
KW - Zeolite
UR - http://www.scopus.com/inward/record.url?scp=85089544833&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/5614e757-c36d-374e-bc34-c78adbc44189/
U2 - 10.1016/j.cattod.2020.06.081
DO - 10.1016/j.cattod.2020.06.081
M3 - Article
AN - SCOPUS:85089544833
VL - 367
SP - 111
EP - 116
JO - Catalysis Today
JF - Catalysis Today
SN - 0920-5861
ER -
ID: 70664952