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Polyelectrolyte-colloid complex formation via polymerization : reaction kinetics in direct micelles, inverted micelles, and homogeneous solution studied by NMR and conductometry. / Zorin, I. M.; Shcherbinina, T. M.; Demidov, E. I.; Mechtaeva, E. V.; Zorina, N. A.; Fetin, P. A.; Bilibin, A. Yu.

In: Colloid and Polymer Science, Vol. 297, No. 9, 01.09.2019, p. 1169-1176.

Research output: Contribution to journal › Article › peer-review

Harvard

Zorin, IM, Shcherbinina, TM, Demidov, EI, Mechtaeva, EV, Zorina, NA, Fetin, PA & Bilibin, AY 2019, 'Polyelectrolyte-colloid complex formation via polymerization: reaction kinetics in direct micelles, inverted micelles, and homogeneous solution studied by NMR and conductometry', Colloid and Polymer Science, vol. 297, no. 9, pp. 1169-1176. https://doi.org/10.1007/s00396-019-04531-4

APA

Zorin, I. M., Shcherbinina, T. M., Demidov, E. I., Mechtaeva, E. V., Zorina, N. A., Fetin, P. A., & Bilibin, A. Y. (2019). Polyelectrolyte-colloid complex formation via polymerization: reaction kinetics in direct micelles, inverted micelles, and homogeneous solution studied by NMR and conductometry. Colloid and Polymer Science, 297(9), 1169-1176. https://doi.org/10.1007/s00396-019-04531-4

Vancouver

Zorin IM, Shcherbinina TM, Demidov EI, Mechtaeva EV, Zorina NA, Fetin PA et al. Polyelectrolyte-colloid complex formation via polymerization: reaction kinetics in direct micelles, inverted micelles, and homogeneous solution studied by NMR and conductometry. Colloid and Polymer Science. 2019 Sep 1;297(9):1169-1176. https://doi.org/10.1007/s00396-019-04531-4

Author

Zorin, I. M. ; Shcherbinina, T. M. ; Demidov, E. I. ; Mechtaeva, E. V. ; Zorina, N. A. ; Fetin, P. A. ; Bilibin, A. Yu. / Polyelectrolyte-colloid complex formation via polymerization : reaction kinetics in direct micelles, inverted micelles, and homogeneous solution studied by NMR and conductometry. In: Colloid and Polymer Science. 2019 ; Vol. 297, No. 9. pp. 1169-1176.

BibTeX

@article{0a88e5db5fc846e19103fd7efd7f1349,
title = "Polyelectrolyte-colloid complex formation via polymerization: reaction kinetics in direct micelles, inverted micelles, and homogeneous solution studied by NMR and conductometry",
abstract = "Formation of polyelectrolyte-surfactant complexes (PESCs) in polymerization process of corresponding amphiphilic monomer is a promising way of pure stoichiometric PESC obtained in salt-free systems. Polymerization of micelle-forming monomer dodecylammonium 2-acrylamido-2-methylpropanesulfonate (DDA-AMPS) in different media was studied by means of 1H-NMR and conductance measurements. Kinetics of polymerization in direct micelles, inverted micelles, and homogeneous solution was considered in terms of classical solution polymerization and microemulsion polymerization. Reaction orders on monomer and initiator were measured in water and dioxane. The rate of polymerization is strongly dependent on monomer micelle existence, being considerably higher in micellar solution than in homogeneous one. [Figure not available: see fulltext.]",
keywords = "Kinetics, Micellar polymerization, Microemulsion polymerization, Polyelectrolyte-surfactant complex, Surfmer",
author = "Zorin, {I. M.} and Shcherbinina, {T. M.} and Demidov, {E. I.} and Mechtaeva, {E. V.} and Zorina, {N. A.} and Fetin, {P. A.} and Bilibin, {A. Yu}",
year = "2019",
month = sep,
day = "1",
doi = "10.1007/s00396-019-04531-4",
language = "English",
volume = "297",
pages = "1169--1176",
journal = "Colloid and Polymer Science",
issn = "0303-402X",
publisher = "Springer Nature",
number = "9",

}

RIS

TY - JOUR

T1 - Polyelectrolyte-colloid complex formation via polymerization

T2 - reaction kinetics in direct micelles, inverted micelles, and homogeneous solution studied by NMR and conductometry

AU - Zorin, I. M.

AU - Shcherbinina, T. M.

AU - Demidov, E. I.

AU - Mechtaeva, E. V.

AU - Zorina, N. A.

AU - Fetin, P. A.

AU - Bilibin, A. Yu

PY - 2019/9/1

Y1 - 2019/9/1

N2 - Formation of polyelectrolyte-surfactant complexes (PESCs) in polymerization process of corresponding amphiphilic monomer is a promising way of pure stoichiometric PESC obtained in salt-free systems. Polymerization of micelle-forming monomer dodecylammonium 2-acrylamido-2-methylpropanesulfonate (DDA-AMPS) in different media was studied by means of 1H-NMR and conductance measurements. Kinetics of polymerization in direct micelles, inverted micelles, and homogeneous solution was considered in terms of classical solution polymerization and microemulsion polymerization. Reaction orders on monomer and initiator were measured in water and dioxane. The rate of polymerization is strongly dependent on monomer micelle existence, being considerably higher in micellar solution than in homogeneous one. [Figure not available: see fulltext.]

AB - Formation of polyelectrolyte-surfactant complexes (PESCs) in polymerization process of corresponding amphiphilic monomer is a promising way of pure stoichiometric PESC obtained in salt-free systems. Polymerization of micelle-forming monomer dodecylammonium 2-acrylamido-2-methylpropanesulfonate (DDA-AMPS) in different media was studied by means of 1H-NMR and conductance measurements. Kinetics of polymerization in direct micelles, inverted micelles, and homogeneous solution was considered in terms of classical solution polymerization and microemulsion polymerization. Reaction orders on monomer and initiator were measured in water and dioxane. The rate of polymerization is strongly dependent on monomer micelle existence, being considerably higher in micellar solution than in homogeneous one. [Figure not available: see fulltext.]

KW - Kinetics

KW - Micellar polymerization

KW - Microemulsion polymerization

KW - Polyelectrolyte-surfactant complex

KW - Surfmer

UR - http://www.scopus.com/inward/record.url?scp=85069452714&partnerID=8YFLogxK

U2 - 10.1007/s00396-019-04531-4

DO - 10.1007/s00396-019-04531-4

M3 - Article

AN - SCOPUS:85069452714

VL - 297

SP - 1169

EP - 1176

JO - Colloid and Polymer Science

JF - Colloid and Polymer Science

SN - 0303-402X

IS - 9

ER -

ID: 50507023