Standard

Polar effect in reactions of substituted benzyl radicals with carbon tetrachloride. / Dneprovskii, A. S.; Boyarskii, V. P.; Iz''yurov, A. L.

In: Russian Journal of Organic Chemistry, Vol. 35, No. 10, 10.1999, p. 1495-1498.

Research output: Contribution to journal › Article › peer-review

Harvard

Dneprovskii, AS, Boyarskii, VP & Iz''yurov, AL 1999, 'Polar effect in reactions of substituted benzyl radicals with carbon tetrachloride', Russian Journal of Organic Chemistry, vol. 35, no. 10, pp. 1495-1498.

APA

Dneprovskii, A. S., Boyarskii, V. P., & Iz''yurov, A. L. (1999). Polar effect in reactions of substituted benzyl radicals with carbon tetrachloride. Russian Journal of Organic Chemistry, 35(10), 1495-1498.

Vancouver

Dneprovskii AS, Boyarskii VP, Iz''yurov AL. Polar effect in reactions of substituted benzyl radicals with carbon tetrachloride. Russian Journal of Organic Chemistry. 1999 Oct;35(10):1495-1498.

Author

Dneprovskii, A. S. ; Boyarskii, V. P. ; Iz''yurov, A. L. / Polar effect in reactions of substituted benzyl radicals with carbon tetrachloride. In: Russian Journal of Organic Chemistry. 1999 ; Vol. 35, No. 10. pp. 1495-1498.

BibTeX

@article{73dbe23ff85b4ad58796e9bea78f4f37,
title = "Polar effect in reactions of substituted benzyl radicals with carbon tetrachloride",
abstract = "The relative rates of chlorine atom transfer from carbon tetrachloride to substituted benzyl radicals were determined from the ratio of products formed by chlorine transfer and combination of the radicals. Electron-donor substituents in the benzyl radical accelerate the reaction (ρ = -0.89). The experimental results were interpreted in terms of charge separation in the transition state. The transition states in hydrogen transfer from substituted toluenes to electrophilic radicals were found to be similar to those formed in chlorine transfer to substituted benzyl radicals.",
author = "Dneprovskii, {A. S.} and Boyarskii, {V. P.} and Iz''yurov, {A. L.}",
year = "1999",
month = oct,
language = "English",
volume = "35",
pages = "1495--1498",
journal = "Russian Journal of Organic Chemistry",
issn = "1070-4280",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "10",

}

RIS

TY - JOUR

T1 - Polar effect in reactions of substituted benzyl radicals with carbon tetrachloride

AU - Dneprovskii, A. S.

AU - Boyarskii, V. P.

AU - Iz''yurov, A. L.

PY - 1999/10

Y1 - 1999/10

N2 - The relative rates of chlorine atom transfer from carbon tetrachloride to substituted benzyl radicals were determined from the ratio of products formed by chlorine transfer and combination of the radicals. Electron-donor substituents in the benzyl radical accelerate the reaction (ρ = -0.89). The experimental results were interpreted in terms of charge separation in the transition state. The transition states in hydrogen transfer from substituted toluenes to electrophilic radicals were found to be similar to those formed in chlorine transfer to substituted benzyl radicals.

AB - The relative rates of chlorine atom transfer from carbon tetrachloride to substituted benzyl radicals were determined from the ratio of products formed by chlorine transfer and combination of the radicals. Electron-donor substituents in the benzyl radical accelerate the reaction (ρ = -0.89). The experimental results were interpreted in terms of charge separation in the transition state. The transition states in hydrogen transfer from substituted toluenes to electrophilic radicals were found to be similar to those formed in chlorine transfer to substituted benzyl radicals.

UR - http://www.scopus.com/inward/record.url?scp=0033233886&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0033233886

VL - 35

SP - 1495

EP - 1498

JO - Russian Journal of Organic Chemistry

JF - Russian Journal of Organic Chemistry

SN - 1070-4280

IS - 10

ER -

ID: 87469570