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Platinum(II)-mediated aminonitrone–isocyanide interplay : A new route to acyclic diaminocarbene complexes. / Il'in, Mikhail V.; Bolotin, Dmitrii S.; Novikov, Alexander S.; Kolesnikov, Ilya E.; Suslonov, Vitalii V.

In: Inorganica Chimica Acta, Vol. 490, 01.05.2019, p. 267-271.

Research output: Contribution to journal › Article › peer-review

Harvard

Il'in, MV, Bolotin, DS, Novikov, AS, Kolesnikov, IE & Suslonov, VV 2019, 'Platinum(II)-mediated aminonitrone–isocyanide interplay: A new route to acyclic diaminocarbene complexes', Inorganica Chimica Acta, vol. 490, pp. 267-271. https://doi.org/10.1016/j.ica.2019.03.026

APA

Il'in, M. V., Bolotin, D. S., Novikov, A. S., Kolesnikov, I. E., & Suslonov, V. V. (2019). Platinum(II)-mediated aminonitrone–isocyanide interplay: A new route to acyclic diaminocarbene complexes. Inorganica Chimica Acta, 490, 267-271. https://doi.org/10.1016/j.ica.2019.03.026

Vancouver

Il'in MV, Bolotin DS, Novikov AS, Kolesnikov IE, Suslonov VV. Platinum(II)-mediated aminonitrone–isocyanide interplay: A new route to acyclic diaminocarbene complexes. Inorganica Chimica Acta. 2019 May 1;490:267-271. https://doi.org/10.1016/j.ica.2019.03.026

Author

Il'in, Mikhail V. ; Bolotin, Dmitrii S. ; Novikov, Alexander S. ; Kolesnikov, Ilya E. ; Suslonov, Vitalii V. / Platinum(II)-mediated aminonitrone–isocyanide interplay : A new route to acyclic diaminocarbene complexes. In: Inorganica Chimica Acta. 2019 ; Vol. 490. pp. 267-271.

BibTeX

@article{9e3844df17c84b5bbbd479826efd5086,
title = "Platinum(II)-mediated aminonitrone–isocyanide interplay: A new route to acyclic diaminocarbene complexes",
abstract = "The complex cis-[PtCl2(Me2SO)2] (1) reacts with 1 equiv. of C-4-trifluoromethylphenyl-N-methylaminonitrone (2) to give the product [PtCl(Me2SO){ON(Me)C(4-CF3C6H4)NH}] (3; 75%). Treatment of 3 with an excess cyclohexyl isocyanide, CyNC, leads to the acyclic diaminocarbene complex [PtCl(CNCy){N(Me)C(4-CF3C6H4)NC(=NHCy)}] (4; 28%). The latter exhibits solid-state phosphorescence with an emission maximum at 600 nm and 23% quantum yield. Complexes 3 and 4 were characterized by HRESI+-MS, FTIR, 1H and 13C{1H} NMR spectroscopic techniques. The complex 4 was additionally characterized by X-ray diffraction; short Pt[pdbond]Pt contacts (3.2360(5) {\AA}) were observed in the crystal structure. These non-covalent interactions have an attractive nature and their estimated strength is 4.6–5.6 kcal/mol.",
keywords = "Platinum(II) complex, Aminonitrone, Isocyanide, Luminescence, Metallophilic interactions, Aminonitrone, Isocyanide, Luminescence, Metallophilic interactions, Platinum(II) complex, MOLECULAR CALCULATIONS, TRANSITION-METAL-COMPLEXES, EFFECTIVE CORE POTENTIALS, ISOMERIZATION, CRYSTAL-STRUCTURES, PT(II) COMPLEXES, PD-II",
author = "Il'in, {Mikhail V.} and Bolotin, {Dmitrii S.} and Novikov, {Alexander S.} and Kolesnikov, {Ilya E.} and Suslonov, {Vitalii V.}",
note = "Publisher Copyright: {\textcopyright} 2019 Elsevier B.V.",
year = "2019",
month = may,
day = "1",
doi = "10.1016/j.ica.2019.03.026",
language = "English",
volume = "490",
pages = "267--271",
journal = "Inorganica Chimica Acta",
issn = "0020-1693",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Platinum(II)-mediated aminonitrone–isocyanide interplay

T2 - A new route to acyclic diaminocarbene complexes

AU - Il'in, Mikhail V.

AU - Bolotin, Dmitrii S.

AU - Novikov, Alexander S.

AU - Kolesnikov, Ilya E.

AU - Suslonov, Vitalii V.

N1 - Publisher Copyright: © 2019 Elsevier B.V.

PY - 2019/5/1

Y1 - 2019/5/1

N2 - The complex cis-[PtCl2(Me2SO)2] (1) reacts with 1 equiv. of C-4-trifluoromethylphenyl-N-methylaminonitrone (2) to give the product [PtCl(Me2SO){ON(Me)C(4-CF3C6H4)NH}] (3; 75%). Treatment of 3 with an excess cyclohexyl isocyanide, CyNC, leads to the acyclic diaminocarbene complex [PtCl(CNCy){N(Me)C(4-CF3C6H4)NC(=NHCy)}] (4; 28%). The latter exhibits solid-state phosphorescence with an emission maximum at 600 nm and 23% quantum yield. Complexes 3 and 4 were characterized by HRESI+-MS, FTIR, 1H and 13C{1H} NMR spectroscopic techniques. The complex 4 was additionally characterized by X-ray diffraction; short Pt[pdbond]Pt contacts (3.2360(5) Å) were observed in the crystal structure. These non-covalent interactions have an attractive nature and their estimated strength is 4.6–5.6 kcal/mol.

AB - The complex cis-[PtCl2(Me2SO)2] (1) reacts with 1 equiv. of C-4-trifluoromethylphenyl-N-methylaminonitrone (2) to give the product [PtCl(Me2SO){ON(Me)C(4-CF3C6H4)NH}] (3; 75%). Treatment of 3 with an excess cyclohexyl isocyanide, CyNC, leads to the acyclic diaminocarbene complex [PtCl(CNCy){N(Me)C(4-CF3C6H4)NC(=NHCy)}] (4; 28%). The latter exhibits solid-state phosphorescence with an emission maximum at 600 nm and 23% quantum yield. Complexes 3 and 4 were characterized by HRESI+-MS, FTIR, 1H and 13C{1H} NMR spectroscopic techniques. The complex 4 was additionally characterized by X-ray diffraction; short Pt[pdbond]Pt contacts (3.2360(5) Å) were observed in the crystal structure. These non-covalent interactions have an attractive nature and their estimated strength is 4.6–5.6 kcal/mol.

KW - Platinum(II) complex

KW - Aminonitrone

KW - Isocyanide

KW - Luminescence

KW - Metallophilic interactions

KW - Aminonitrone

KW - Isocyanide

KW - Luminescence

KW - Metallophilic interactions

KW - Platinum(II) complex

KW - MOLECULAR CALCULATIONS

KW - TRANSITION-METAL-COMPLEXES

KW - EFFECTIVE CORE POTENTIALS

KW - ISOMERIZATION

KW - CRYSTAL-STRUCTURES

KW - PT(II) COMPLEXES

KW - PD-II

UR - http://www.scopus.com/inward/record.url?scp=85063324071&partnerID=8YFLogxK

UR - http://www.mendeley.com/research/platinumiimediated-aminonitroneisocyanide-interplay-new-route-acyclic-diaminocarbene-complexes

U2 - 10.1016/j.ica.2019.03.026

DO - 10.1016/j.ica.2019.03.026

M3 - Article

VL - 490

SP - 267

EP - 271

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

ER -

ID: 39842042