Research output: Contribution to journal › Article › peer-review
Photometric determination of trace selenium in aqueous media. / Moskvin, L. N.; Bulatov, A. V.; Rudenko, E. A.; Navolotskii, D. V.; Koldobskii, G. I.
In: Journal of Analytical Chemistry, Vol. 61, No. 1, 01.2006, p. 25-27.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Photometric determination of trace selenium in aqueous media
AU - Moskvin, L. N.
AU - Bulatov, A. V.
AU - Rudenko, E. A.
AU - Navolotskii, D. V.
AU - Koldobskii, G. I.
PY - 2006/1
Y1 - 2006/1
N2 - A new procedure is developed for the photometric determination of trace selenium in aqueous solutions. The selection of 2-(p-nitrophenyl)-3,5- diphenyltetrazolium chloride as a reagent for selenium is justified. The proposed sample preparation procedure involves gas extraction of selenium as hydrogen selenide followed by its liquid-adsorption extraction from the gas phase to an aqueous reagent solution with the formation of a water-insoluble formazan. Formazan formed upon the absorption of hydrogen selenide is extracted with isoamyl alcohol. The concentration of selenium is determined from the absorbance of the formazan extract in the isoamyl alcohol. The procedure allows the determination of 10-120 μg/L selenium.
AB - A new procedure is developed for the photometric determination of trace selenium in aqueous solutions. The selection of 2-(p-nitrophenyl)-3,5- diphenyltetrazolium chloride as a reagent for selenium is justified. The proposed sample preparation procedure involves gas extraction of selenium as hydrogen selenide followed by its liquid-adsorption extraction from the gas phase to an aqueous reagent solution with the formation of a water-insoluble formazan. Formazan formed upon the absorption of hydrogen selenide is extracted with isoamyl alcohol. The concentration of selenium is determined from the absorbance of the formazan extract in the isoamyl alcohol. The procedure allows the determination of 10-120 μg/L selenium.
UR - http://www.scopus.com/inward/record.url?scp=33644541459&partnerID=8YFLogxK
U2 - 10.1134/S1061934806010060
DO - 10.1134/S1061934806010060
M3 - Article
AN - SCOPUS:33644541459
VL - 61
SP - 25
EP - 27
JO - Journal of Analytical Chemistry
JF - Journal of Analytical Chemistry
SN - 1061-9348
IS - 1
ER -
ID: 93275438