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Photocatalytic activity of layered perovskite-like oxides in practically valuable chemical reactions. / Rodionov, I. A.; Zvereva, I. A.
In: Russian Chemical Reviews, Vol. 85, No. 3, 01.01.2016, p. 248-279.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Photocatalytic activity of layered perovskite-like oxides in practically valuable chemical reactions
AU - Rodionov, I. A.
AU - Zvereva, I. A.
PY - 2016/1/1
Y1 - 2016/1/1
N2 - The photocatalytic properties of layered perovskite-like oxides corresponding to the Ruddlesen-Popper, Dion-Jacobson and Aurivillius phases are considered. Of the photocatalytic reactions, the focus is on the reactions of water splitting, hydrogen evolution from aqueous solutions of organic substances and degradation of model organic pollutants. Possibilities to conduct these reactions under UV and visible light in the presence of layered perovskite-like oxides and composite photocatalysts based on them are shown. The specific surface area, band gap energy, particle morphology, cation and anion doping and surface modification are considered as factors that affect the photocatalytic activity. Special attention is paid to the possibilities to enhance the photocatalytic activity by intercalation, ion exchange and exfoliation, which are inherent in this class of compounds. Conclusions are made about the prospects for the use of layered perovskite-like oxides in photocatalysis.
AB - The photocatalytic properties of layered perovskite-like oxides corresponding to the Ruddlesen-Popper, Dion-Jacobson and Aurivillius phases are considered. Of the photocatalytic reactions, the focus is on the reactions of water splitting, hydrogen evolution from aqueous solutions of organic substances and degradation of model organic pollutants. Possibilities to conduct these reactions under UV and visible light in the presence of layered perovskite-like oxides and composite photocatalysts based on them are shown. The specific surface area, band gap energy, particle morphology, cation and anion doping and surface modification are considered as factors that affect the photocatalytic activity. Special attention is paid to the possibilities to enhance the photocatalytic activity by intercalation, ion exchange and exfoliation, which are inherent in this class of compounds. Conclusions are made about the prospects for the use of layered perovskite-like oxides in photocatalysis.
UR - http://www.scopus.com/inward/record.url?scp=84963625860&partnerID=8YFLogxK
U2 - 10.1070/RCR4547
DO - 10.1070/RCR4547
M3 - Article
AN - SCOPUS:84963625860
VL - 85
SP - 248
EP - 279
JO - Russian Chemical Reviews
JF - Russian Chemical Reviews
SN - 0036-021X
IS - 3
ER -
ID: 51342743