Standard

Phosphporylated calixarenes as perspective extractants for TPE, REE, technetium and palladium. / Smirnov, I. V.; Babain, V. A.; Efremova, T. I.

Global 2003: Atoms for Prosperity: Updating Eisenhowers Global Vision for Nuclear Energy. 2003. p. 702-706 (Global 2003: Atoms for Prosperity: Updating Eisenhowers Global Vision for Nuclear Energy).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Research › peer-review

Harvard

Smirnov, IV, Babain, VA & Efremova, TI 2003, Phosphporylated calixarenes as perspective extractants for TPE, REE, technetium and palladium. in Global 2003: Atoms for Prosperity: Updating Eisenhowers Global Vision for Nuclear Energy. Global 2003: Atoms for Prosperity: Updating Eisenhowers Global Vision for Nuclear Energy, pp. 702-706, Global 2003: Atoms for Prosperity: Updating Eisenhower's Global Vision for Nuclear Energy, New Orleans, LA, United States, 16/11/03.

APA

Smirnov, I. V., Babain, V. A., & Efremova, T. I. (2003). Phosphporylated calixarenes as perspective extractants for TPE, REE, technetium and palladium. In Global 2003: Atoms for Prosperity: Updating Eisenhowers Global Vision for Nuclear Energy (pp. 702-706). (Global 2003: Atoms for Prosperity: Updating Eisenhowers Global Vision for Nuclear Energy).

Vancouver

Smirnov IV, Babain VA, Efremova TI. Phosphporylated calixarenes as perspective extractants for TPE, REE, technetium and palladium. In Global 2003: Atoms for Prosperity: Updating Eisenhowers Global Vision for Nuclear Energy. 2003. p. 702-706. (Global 2003: Atoms for Prosperity: Updating Eisenhowers Global Vision for Nuclear Energy).

Author

Smirnov, I. V. ; Babain, V. A. ; Efremova, T. I. / Phosphporylated calixarenes as perspective extractants for TPE, REE, technetium and palladium. Global 2003: Atoms for Prosperity: Updating Eisenhowers Global Vision for Nuclear Energy. 2003. pp. 702-706 (Global 2003: Atoms for Prosperity: Updating Eisenhowers Global Vision for Nuclear Energy).

BibTeX

@inproceedings{be31aa04bd81480aa76c5c0882d84859,
title = "Phosphporylated calixarenes as perspective extractants for TPE, REE, technetium and palladium",
abstract = "Extraction of Eu, Am, Tc and Pd by 20 new phosphorylated calixarenes was investigated. In contrast to routine phosphine oxides, with decreasing the length of alkyl substituent at phosphorus atom in calix[4] arenes, the Eu and Am extraction maximum is shifted to more acidic region. Similar effect is observed in Tc and Pd extraction. All calixarenes effectively extract technetium from acidic (to 1 M HNO3) media. There is practically no {"}cooperative effect{"}: phosphorylated calix[4]arenes extracts technetium only two times better than monodentate analog. With decreasing the phosphoryl oxygen basicity the distribution coefficients of technetium and palladium decrease. The calixarene ring size, structure and length of bridge group and position of phosphoryl groups on upper or lower rims do not considerably affect technetium and palladium extraction. As to palladium extraction by phosphorylated calix[4]arenes, there is observed the moderate {"}cooperative effect{"} (around 10). As distinct from routine extractants, the phosphorylated calix[4] arenes afford the combined recovery of REE, TPE, technetium and palladium from acidic media.",
author = "Smirnov, {I. V.} and Babain, {V. A.} and Efremova, {T. I.}",
year = "2003",
month = dec,
day = "1",
language = "English",
isbn = "0894486772",
series = "Global 2003: Atoms for Prosperity: Updating Eisenhowers Global Vision for Nuclear Energy",
pages = "702--706",
booktitle = "Global 2003",
note = "Global 2003: Atoms for Prosperity: Updating Eisenhower's Global Vision for Nuclear Energy ; Conference date: 16-11-2003 Through 20-11-2003",

}

RIS

TY - GEN

T1 - Phosphporylated calixarenes as perspective extractants for TPE, REE, technetium and palladium

AU - Smirnov, I. V.

AU - Babain, V. A.

AU - Efremova, T. I.

PY - 2003/12/1

Y1 - 2003/12/1

N2 - Extraction of Eu, Am, Tc and Pd by 20 new phosphorylated calixarenes was investigated. In contrast to routine phosphine oxides, with decreasing the length of alkyl substituent at phosphorus atom in calix[4] arenes, the Eu and Am extraction maximum is shifted to more acidic region. Similar effect is observed in Tc and Pd extraction. All calixarenes effectively extract technetium from acidic (to 1 M HNO3) media. There is practically no "cooperative effect": phosphorylated calix[4]arenes extracts technetium only two times better than monodentate analog. With decreasing the phosphoryl oxygen basicity the distribution coefficients of technetium and palladium decrease. The calixarene ring size, structure and length of bridge group and position of phosphoryl groups on upper or lower rims do not considerably affect technetium and palladium extraction. As to palladium extraction by phosphorylated calix[4]arenes, there is observed the moderate "cooperative effect" (around 10). As distinct from routine extractants, the phosphorylated calix[4] arenes afford the combined recovery of REE, TPE, technetium and palladium from acidic media.

AB - Extraction of Eu, Am, Tc and Pd by 20 new phosphorylated calixarenes was investigated. In contrast to routine phosphine oxides, with decreasing the length of alkyl substituent at phosphorus atom in calix[4] arenes, the Eu and Am extraction maximum is shifted to more acidic region. Similar effect is observed in Tc and Pd extraction. All calixarenes effectively extract technetium from acidic (to 1 M HNO3) media. There is practically no "cooperative effect": phosphorylated calix[4]arenes extracts technetium only two times better than monodentate analog. With decreasing the phosphoryl oxygen basicity the distribution coefficients of technetium and palladium decrease. The calixarene ring size, structure and length of bridge group and position of phosphoryl groups on upper or lower rims do not considerably affect technetium and palladium extraction. As to palladium extraction by phosphorylated calix[4]arenes, there is observed the moderate "cooperative effect" (around 10). As distinct from routine extractants, the phosphorylated calix[4] arenes afford the combined recovery of REE, TPE, technetium and palladium from acidic media.

UR - http://www.scopus.com/inward/record.url?scp=2642585786&partnerID=8YFLogxK

M3 - Conference contribution

AN - SCOPUS:2642585786

SN - 0894486772

T3 - Global 2003: Atoms for Prosperity: Updating Eisenhowers Global Vision for Nuclear Energy

SP - 702

EP - 706

BT - Global 2003

T2 - Global 2003: Atoms for Prosperity: Updating Eisenhower's Global Vision for Nuclear Energy

Y2 - 16 November 2003 through 20 November 2003

ER -

ID: 53580690