Research output: Contribution to journal › Article › peer-review
Metal-mediated self-assembly of isocyanides and methyl 4-aminopyrimidine-5-carboxylate leads to luminescent Pd II and Pt II complexes featuring C,N-cyclometalated acyclic diaminocarbene (ADC) ligands. The solid-state luminescent properties of these diaminocarbene derivatives are attributed to their triplet-state metal/metal-to-ligand charge-transfer ( 3MMLCT) nature, which is driven by attractive intermolecular M···M interactions further reinforced by the intramolecular π-π interactions even in the structure of the Pd compound, which is the first Pd-ADC phosphor reported.
Original language | English |
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Pages (from-to) | 5315–5319 |
Number of pages | 5 |
Journal | Inorganic Chemistry |
Volume | 63 |
Issue number | 12 |
DOIs | |
State | Published - 25 Mar 2024 |
ID: 119333750