Phase equilibria liquid-liquid for ternary systems n-amyl alcohol – water – (acetic acid, n-amyl acetate), n-amyl acetate – water – acetic acid at 293.15 K, 303.15 K, 313.15 K and 323.15 K

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Phase equilibria liquid-liquid for ternary systems n-amyl alcohol – water – (acetic acid, n-amyl acetate), n-amyl acetate – water – acetic acid at 293.15 K, 303.15 K, 313.15 K and 323.15 K. / Misikov, Georgii ; Toikka, Maria ; Samarov, Artemiy ; Toikka, Alexander.

In: Fluid Phase Equilibria, Vol. 552, 113265, 15.01.2022.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{78e94b652e7049c9819dad19c4a3b01d,

title = "Phase equilibria liquid-liquid for ternary systems n-amyl alcohol – water – (acetic acid, n-amyl acetate), n-amyl acetate – water – acetic acid at 293.15 K, 303.15 K, 313.15 K and 323.15 K",

abstract = "Experimental data on liquid-liquid equilibrium for the ternary systems acetic acid – n-amyl alcohol – water, acetic acid – n-amyl acetate – water, n-amyl alcohol – n-amyl acetate – water and for the quaternary system acetic acid – n-amyl alcohol – n-amyl acetate – water at 293.15 K, 303.15 K, 313.15 K and 323.15 K and atmospheric pressure were obtained by gas chromatography method. Phase diagrams are presented using Gibbs composition triangle and composition tetrahedron. Sufficient agreement of experimental tie-lines with calculated by NRTL model is observed: standard deviation does not exceed 1.2%.",

keywords = "Liquid-liquid equilibrium, Modeling, N-amyl acetate, NRTL",

author = "Georgii Misikov and Maria Toikka and Artemiy Samarov and Alexander Toikka",

note = "Publisher Copyright: {\textcopyright} 2021 Elsevier B.V.",

year = "2022",

month = jan,

day = "15",

doi = "10.1016/j.fluid.2021.113265",

language = "English",

volume = "552",

journal = "Fluid Phase Equilibria",

issn = "0378-3812",

publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Phase equilibria liquid-liquid for ternary systems n-amyl alcohol – water – (acetic acid, n-amyl acetate), n-amyl acetate – water – acetic acid at 293.15 K, 303.15 K, 313.15 K and 323.15 K

AU - Misikov, Georgii

AU - Toikka, Maria

AU - Samarov, Artemiy

AU - Toikka, Alexander

PY - 2022/1/15

Y1 - 2022/1/15

N2 - Experimental data on liquid-liquid equilibrium for the ternary systems acetic acid – n-amyl alcohol – water, acetic acid – n-amyl acetate – water, n-amyl alcohol – n-amyl acetate – water and for the quaternary system acetic acid – n-amyl alcohol – n-amyl acetate – water at 293.15 K, 303.15 K, 313.15 K and 323.15 K and atmospheric pressure were obtained by gas chromatography method. Phase diagrams are presented using Gibbs composition triangle and composition tetrahedron. Sufficient agreement of experimental tie-lines with calculated by NRTL model is observed: standard deviation does not exceed 1.2%.

AB - Experimental data on liquid-liquid equilibrium for the ternary systems acetic acid – n-amyl alcohol – water, acetic acid – n-amyl acetate – water, n-amyl alcohol – n-amyl acetate – water and for the quaternary system acetic acid – n-amyl alcohol – n-amyl acetate – water at 293.15 K, 303.15 K, 313.15 K and 323.15 K and atmospheric pressure were obtained by gas chromatography method. Phase diagrams are presented using Gibbs composition triangle and composition tetrahedron. Sufficient agreement of experimental tie-lines with calculated by NRTL model is observed: standard deviation does not exceed 1.2%.

KW - Liquid-liquid equilibrium

KW - Modeling

KW - N-amyl acetate

KW - NRTL

UR - http://www.scopus.com/inward/record.url?scp=85117862506&partnerID=8YFLogxK

U2 - 10.1016/j.fluid.2021.113265

DO - 10.1016/j.fluid.2021.113265

M3 - Article

AN - SCOPUS:85117862506

VL - 552

JO - Fluid Phase Equilibria

JF - Fluid Phase Equilibria

SN - 0378-3812

M1 - 113265

ER -

ID: 88716659