Research output: Contribution to journal › Article › peer-review
The solubility in a ternary fullerenol-d (C60(OH)22–24)–SmCl3–H2O system at 25°C is studied via isothermal saturation in ampules. The solubility diagram is shown to be a simple eutonic one that consists of two branches corresponding to the crystallization of fullerenol-d (C60(OH)22–24 · 30H2O) and samarium(III) chloride SmCl3 · 6H2O crystallohydrates and contains one nonvariant eutonic point corresponding to saturation with both crystallohydrates. The long branch of C60(OH)22–24 · 30H2O crystallization shows the effect of fullerenol-d salting out of saturated solutions; in contrast, the short branch of SmCl3 · 6H2O crystallization shows the pronounced salting-in effect of samarium(III) chloride.
Original language | English |
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Pages (from-to) | 797-799 |
Number of pages | 3 |
Journal | Russian Journal of Physical Chemistry A |
Volume | 91 |
Issue number | 5 |
DOIs | |
State | Published - 1 May 2017 |
ID: 7749472