Research output: Contribution to journal › Article › peer-review
pH Sensitivity of a Porphyrin Film Electrode. / Abakumova, R. A.; Valiotti, A. B.; Vasil'va, O. E.; Kopylova, E. A.; Shumilova, G. I.; Mikhel'son, K. N.
In: Russian Journal of General Chemistry, Vol. 73, No. 2, 02.2003, p. 300-307.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - pH Sensitivity of a Porphyrin Film Electrode
AU - Abakumova, R. A.
AU - Valiotti, A. B.
AU - Vasil'va, O. E.
AU - Kopylova, E. A.
AU - Shumilova, G. I.
AU - Mikhel'son, K. N.
PY - 2003/2
Y1 - 2003/2
N2 - The response of plasticized polyvinyl chloride membranes containing tetraphenylporphyrin on the pH of the aqueous solution was systematically studied. The concentration of teraphenylporphyrin in the membrane, the polarity of the membrane solvent, and the background electrolyte of the aqueous solution (NaCl, NaNO3, and NaClO4) were varied. A model was proposed, that allow computer simulation of experimental E-pH curves for porphyrin membranes. The model calculations were shown to fairly fit experimental data. Parameters responsible for the shape of the E-pH curves were estimated.
AB - The response of plasticized polyvinyl chloride membranes containing tetraphenylporphyrin on the pH of the aqueous solution was systematically studied. The concentration of teraphenylporphyrin in the membrane, the polarity of the membrane solvent, and the background electrolyte of the aqueous solution (NaCl, NaNO3, and NaClO4) were varied. A model was proposed, that allow computer simulation of experimental E-pH curves for porphyrin membranes. The model calculations were shown to fairly fit experimental data. Parameters responsible for the shape of the E-pH curves were estimated.
UR - http://www.scopus.com/inward/record.url?scp=0037829650&partnerID=8YFLogxK
U2 - 10.1023/A:1024764726797
DO - 10.1023/A:1024764726797
M3 - Article
AN - SCOPUS:0037829650
VL - 73
SP - 300
EP - 307
JO - Russian Journal of General Chemistry
JF - Russian Journal of General Chemistry
SN - 1070-3632
IS - 2
ER -
ID: 92358923