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Perturbations in the Rotational Structure of the 4p Complex of H2 Molecule Terms. / Lavrov, B. P.

In: Russian Journal of Physical Chemistry B, Vol. 6, No. 2, 2012, p. 239-248.

Research output: Contribution to journal › Article › peer-review

Harvard

Lavrov, BP 2012, 'Perturbations in the Rotational Structure of the 4p Complex of H2 Molecule Terms', Russian Journal of Physical Chemistry B, vol. 6, no. 2, pp. 239-248. https://doi.org/DOI: 10.1134/S1990793112020194

APA

Lavrov, B. P. (2012). Perturbations in the Rotational Structure of the 4p Complex of H2 Molecule Terms. Russian Journal of Physical Chemistry B, 6(2), 239-248. https://doi.org/DOI: 10.1134/S1990793112020194

Vancouver

Lavrov BP. Perturbations in the Rotational Structure of the 4p Complex of H2 Molecule Terms. Russian Journal of Physical Chemistry B. 2012;6(2):239-248. https://doi.org/DOI: 10.1134/S1990793112020194

Author

Lavrov, B. P. / Perturbations in the Rotational Structure of the 4p Complex of H2 Molecule Terms. In: Russian Journal of Physical Chemistry B. 2012 ; Vol. 6, No. 2. pp. 239-248.

BibTeX

@article{3574b4aaf50e4dc886b1465504c906c5,
title = "Perturbations in the Rotational Structure of the 4p Complex of H2 Molecule Terms",
abstract = "A statistical analysis of all the available data on the wave numbers of spectral lines related to triplet-triplet electronic-vibrational-rotational (rovibronic) radiation transitions into the H2 molecule (1sσ2sσ) a3SIGMAg+ electronic state was performed for the first time. This allowed us to check and refine the controversial identification of several spectral lines. Optimum rovibronic term values were found for 15 electronic states, including the (4pσ)f 3SIGMAu+ , (4pπ)k3PIu+ , and (4pπ)k3PIu- states studied in this work. The ratios between the oscillator strengths of R- and P-branch lines with common upper levels (branching coefficients) for the f3SIGMAu+ ->a3SIGMAg+ and k3PIu+ -> a3SIGMAg+ systems of H2 molecule bands were measured for the first time. Substantial deviations of the measured branching coefficients from the corresponding ratios between the Henl–London factors were observed. The deviations monotonically increased as the rotational quantum number N grew, which, in combination with substantial Λ",
keywords = "rovibronic terms, H2 molecule, spontaneous transition probabilities, perturbations in spectra, electron-rotational interaction",
author = "Lavrov, {B. P.}",
year = "2012",
doi = "DOI: 10.1134/S1990793112020194",
language = "не определен",
volume = "6",
pages = "239--248",
journal = "Russian Journal of Physical Chemistry B",
issn = "1990-7931",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "2",

}

RIS

TY - JOUR

T1 - Perturbations in the Rotational Structure of the 4p Complex of H2 Molecule Terms

AU - Lavrov, B. P.

PY - 2012

Y1 - 2012

N2 - A statistical analysis of all the available data on the wave numbers of spectral lines related to triplet-triplet electronic-vibrational-rotational (rovibronic) radiation transitions into the H2 molecule (1sσ2sσ) a3SIGMAg+ electronic state was performed for the first time. This allowed us to check and refine the controversial identification of several spectral lines. Optimum rovibronic term values were found for 15 electronic states, including the (4pσ)f 3SIGMAu+ , (4pπ)k3PIu+ , and (4pπ)k3PIu- states studied in this work. The ratios between the oscillator strengths of R- and P-branch lines with common upper levels (branching coefficients) for the f3SIGMAu+ ->a3SIGMAg+ and k3PIu+ -> a3SIGMAg+ systems of H2 molecule bands were measured for the first time. Substantial deviations of the measured branching coefficients from the corresponding ratios between the Henl–London factors were observed. The deviations monotonically increased as the rotational quantum number N grew, which, in combination with substantial Λ

AB - A statistical analysis of all the available data on the wave numbers of spectral lines related to triplet-triplet electronic-vibrational-rotational (rovibronic) radiation transitions into the H2 molecule (1sσ2sσ) a3SIGMAg+ electronic state was performed for the first time. This allowed us to check and refine the controversial identification of several spectral lines. Optimum rovibronic term values were found for 15 electronic states, including the (4pσ)f 3SIGMAu+ , (4pπ)k3PIu+ , and (4pπ)k3PIu- states studied in this work. The ratios between the oscillator strengths of R- and P-branch lines with common upper levels (branching coefficients) for the f3SIGMAu+ ->a3SIGMAg+ and k3PIu+ -> a3SIGMAg+ systems of H2 molecule bands were measured for the first time. Substantial deviations of the measured branching coefficients from the corresponding ratios between the Henl–London factors were observed. The deviations monotonically increased as the rotational quantum number N grew, which, in combination with substantial Λ

KW - rovibronic terms

KW - H2 molecule

KW - spontaneous transition probabilities

KW - perturbations in spectra

KW - electron-rotational interaction

U2 - DOI: 10.1134/S1990793112020194

DO - DOI: 10.1134/S1990793112020194

M3 - статья

VL - 6

SP - 239

EP - 248

JO - Russian Journal of Physical Chemistry B

JF - Russian Journal of Physical Chemistry B

SN - 1990-7931

IS - 2

ER -

ID: 5378172