Research output: Contribution to journal › Article › peer-review
Calculations by the PCM/B3LYP/6-311G++(3d5f7)&Xe- 3-111G(3d5)PCM/B3LYP/6-311G-(3d5f7)&Xe-3- 111G(d5) method show that, despite the higher electronegativity of the nitrogen atom, the interaction between the CN- anion and the (pentaphenyl)xenonium(II) cation forms a xenon-carbon bond which is stronger by 6 kcal mol-1 than the direct ionic bond between CN- and Xe+.
| Original language | English |
|---|---|
| Pages (from-to) | 1729-1731 |
| Number of pages | 3 |
| Journal | Russian Journal of General Chemistry |
| Volume | 76 |
| Issue number | 11 |
| DOIs | |
| State | Published - Nov 2006 |
ID: 13349558