Peculiarities of the Effect of Silver Chalcogenides on the Glass-Formation Temperature of Chalcogenide Glasses with Ionic Conduction

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Peculiarities of the Effect of Silver Chalcogenides on the Glass-Formation Temperature of Chalcogenide Glasses with Ionic Conduction. / Тверьянович, Юрий Станиславович ; Фазлетдинов, Тимур Равильевич; Томаев, Владимир Владимирович.

In: Russian Journal of Electrochemistry, Vol. 59, No. 8, 01.08.2023, p. 567-572.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{fb4054ff74eb4a1bb3fe05edf49a920a,

title = "Peculiarities of the Effect of Silver Chalcogenides on the Glass-Formation Temperature of Chalcogenide Glasses with Ionic Conduction",

abstract = "Abstract: The glass-formation temperature of chalcogenide glasses with silver-ionic conduction is analyzed as a function of the content of silver chalcogenides. The peculiarities of the changes in the glass-formation temperature for glasses based on silver chalcogenides are explained by the coexistence of covalent bonds silver–chalcogene (Ag–Ch) and metallophilic bonds silver–silver (Ag–Ag). A large number of systems demonstrate the general relationship that allows one to conclude that the connectivity factor of silver in chalcogenide glasses substantially exceeds its formal oxidation state because silver forms metallophilic bonds in addition to covalent bonds. It is assumed that the metallophilic interactions affect not only the glass-formation temperature but also many other important properties of these glasses including the mechanism of silver-ionic conduction.",

keywords = "chalcogenide glasses, glass network, ionic conduction, metallophilic bonds, plasticity, silver chalcogenides, silver ions",

author = "Тверьянович, {Юрий Станиславович} and Фазлетдинов, {Тимур Равильевич} and Томаев, {Владимир Владимирович}",

year = "2023",

month = aug,

day = "1",

doi = "10.1134/S1023193523080086",

language = "English",

volume = "59",

pages = "567--572",

journal = "Russian Journal of Electrochemistry",

issn = "1023-1935",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

number = "8",

}

RIS

TY - JOUR

T1 - Peculiarities of the Effect of Silver Chalcogenides on the Glass-Formation Temperature of Chalcogenide Glasses with Ionic Conduction

AU - Тверьянович, Юрий Станиславович

AU - Фазлетдинов, Тимур Равильевич

AU - Томаев, Владимир Владимирович

PY - 2023/8/1

Y1 - 2023/8/1

N2 - Abstract: The glass-formation temperature of chalcogenide glasses with silver-ionic conduction is analyzed as a function of the content of silver chalcogenides. The peculiarities of the changes in the glass-formation temperature for glasses based on silver chalcogenides are explained by the coexistence of covalent bonds silver–chalcogene (Ag–Ch) and metallophilic bonds silver–silver (Ag–Ag). A large number of systems demonstrate the general relationship that allows one to conclude that the connectivity factor of silver in chalcogenide glasses substantially exceeds its formal oxidation state because silver forms metallophilic bonds in addition to covalent bonds. It is assumed that the metallophilic interactions affect not only the glass-formation temperature but also many other important properties of these glasses including the mechanism of silver-ionic conduction.

AB - Abstract: The glass-formation temperature of chalcogenide glasses with silver-ionic conduction is analyzed as a function of the content of silver chalcogenides. The peculiarities of the changes in the glass-formation temperature for glasses based on silver chalcogenides are explained by the coexistence of covalent bonds silver–chalcogene (Ag–Ch) and metallophilic bonds silver–silver (Ag–Ag). A large number of systems demonstrate the general relationship that allows one to conclude that the connectivity factor of silver in chalcogenide glasses substantially exceeds its formal oxidation state because silver forms metallophilic bonds in addition to covalent bonds. It is assumed that the metallophilic interactions affect not only the glass-formation temperature but also many other important properties of these glasses including the mechanism of silver-ionic conduction.

KW - chalcogenide glasses

KW - glass network

KW - ionic conduction

KW - metallophilic bonds

KW - plasticity

KW - silver chalcogenides

KW - silver ions

UR - https://www.mendeley.com/catalogue/d0848420-edf9-33b9-85a5-7df3d38c5245/

U2 - 10.1134/S1023193523080086

DO - 10.1134/S1023193523080086

M3 - Article

VL - 59

SP - 567

EP - 572

JO - Russian Journal of Electrochemistry

JF - Russian Journal of Electrochemistry

SN - 1023-1935

IS - 8

ER -

ID: 113801200