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Palladium(II) and Platinum(II) Complexes of Novel Water-Soluble Phosphane CAP: Structure, Interligand Hydrogen-Hydrogen Bonding and in Vitro Cytotoxicity. / Бритвин, Сергей Николаевич; Румянцев, Андрей Михайлович; Silyutina (Силютина), Anna (Анна); Падкина, Марина Владимировна.

In: ChemistrySelect, Vol. 2, 02.10.2017, p. 8721-8725.

Research output: Contribution to journal › Article › peer-review

Harvard

Бритвин, СН, Румянцев, АМ, Silyutina (Силютина), AА & Падкина, МВ 2017, 'Palladium(II) and Platinum(II) Complexes of Novel Water-Soluble Phosphane CAP: Structure, Interligand Hydrogen-Hydrogen Bonding and in Vitro Cytotoxicity', ChemistrySelect, vol. 2, pp. 8721-8725. https://doi.org/10.1002/slct.201701819

APA

Бритвин, С. Н., Румянцев, А. М., Silyutina (Силютина), A. А., & Падкина, М. В. (2017). Palladium(II) and Platinum(II) Complexes of Novel Water-Soluble Phosphane CAP: Structure, Interligand Hydrogen-Hydrogen Bonding and in Vitro Cytotoxicity. ChemistrySelect, 2, 8721-8725. https://doi.org/10.1002/slct.201701819

Vancouver

Бритвин СН, Румянцев АМ, Silyutina (Силютина) AА, Падкина МВ. Palladium(II) and Platinum(II) Complexes of Novel Water-Soluble Phosphane CAP: Structure, Interligand Hydrogen-Hydrogen Bonding and in Vitro Cytotoxicity. ChemistrySelect. 2017 Oct 2;2:8721-8725. https://doi.org/10.1002/slct.201701819

Author

Бритвин, Сергей Николаевич ; Румянцев, Андрей Михайлович ; Silyutina (Силютина), Anna (Анна) ; Падкина, Марина Владимировна. / Palladium(II) and Platinum(II) Complexes of Novel Water-Soluble Phosphane CAP: Structure, Interligand Hydrogen-Hydrogen Bonding and in Vitro Cytotoxicity. In: ChemistrySelect. 2017 ; Vol. 2. pp. 8721-8725.

BibTeX

@article{61a61fbb16c6456a954186373ba8ede9,
title = "Palladium(II) and Platinum(II) Complexes of Novel Water-Soluble Phosphane CAP: Structure, Interligand Hydrogen-Hydrogen Bonding and in Vitro Cytotoxicity",
abstract = "Palladium(II) and platinum(II) chloro complexes of novel water‐soluble cage‐like phosphane CAP (1,4,7‐triaza‐9‐phosphatricyclo[5.3.2.14,9]tridecane) have been synthesized and characterized in comparison with their counterparts bearing well known PTA (1,3,5‐triaza‐7‐phosphaadamantane) ligand. A peculiar structural feature of studied cis‐[MCl2L2] complexes is the occurrence of interligand C−Hσ+⋅⋅⋅σ+H−C interactions (hydrogen‐hydrogen bonds) between the phosphane cages: the first case encountered so far among metal‐phosphane complexes. Due to substantial stabilizing contribution to the net molecular energy of the complexes (∼ 20 kcal mol−1), hydrogen‐hydrogen bonding is sufficient to maintain sterically overcrowded cis conformations of the complexes. The interplay between protonation stage of the ligands and their conformations can be a reason of significant differences in in‐vitro cytotoxicity between CAP complexes and their PTA‐bearing counterparts.",
author = "Бритвин, {Сергей Николаевич} and Румянцев, {Андрей Михайлович} and {Silyutina (Силютина)}, {Anna (Анна)} and Падкина, {Марина Владимировна}",
year = "2017",
month = oct,
day = "2",
doi = "10.1002/slct.201701819",
language = "English",
volume = "2",
pages = "8721--8725",
journal = "ChemistrySelect",
issn = "2365-6549",
publisher = "Wiley-Blackwell",

}

RIS

TY - JOUR

T1 - Palladium(II) and Platinum(II) Complexes of Novel Water-Soluble Phosphane CAP: Structure, Interligand Hydrogen-Hydrogen Bonding and in Vitro Cytotoxicity

AU - Бритвин, Сергей Николаевич

AU - Румянцев, Андрей Михайлович

AU - Silyutina (Силютина), Anna (Анна)

AU - Падкина, Марина Владимировна

PY - 2017/10/2

Y1 - 2017/10/2

N2 - Palladium(II) and platinum(II) chloro complexes of novel water‐soluble cage‐like phosphane CAP (1,4,7‐triaza‐9‐phosphatricyclo[5.3.2.14,9]tridecane) have been synthesized and characterized in comparison with their counterparts bearing well known PTA (1,3,5‐triaza‐7‐phosphaadamantane) ligand. A peculiar structural feature of studied cis‐[MCl2L2] complexes is the occurrence of interligand C−Hσ+⋅⋅⋅σ+H−C interactions (hydrogen‐hydrogen bonds) between the phosphane cages: the first case encountered so far among metal‐phosphane complexes. Due to substantial stabilizing contribution to the net molecular energy of the complexes (∼ 20 kcal mol−1), hydrogen‐hydrogen bonding is sufficient to maintain sterically overcrowded cis conformations of the complexes. The interplay between protonation stage of the ligands and their conformations can be a reason of significant differences in in‐vitro cytotoxicity between CAP complexes and their PTA‐bearing counterparts.

AB - Palladium(II) and platinum(II) chloro complexes of novel water‐soluble cage‐like phosphane CAP (1,4,7‐triaza‐9‐phosphatricyclo[5.3.2.14,9]tridecane) have been synthesized and characterized in comparison with their counterparts bearing well known PTA (1,3,5‐triaza‐7‐phosphaadamantane) ligand. A peculiar structural feature of studied cis‐[MCl2L2] complexes is the occurrence of interligand C−Hσ+⋅⋅⋅σ+H−C interactions (hydrogen‐hydrogen bonds) between the phosphane cages: the first case encountered so far among metal‐phosphane complexes. Due to substantial stabilizing contribution to the net molecular energy of the complexes (∼ 20 kcal mol−1), hydrogen‐hydrogen bonding is sufficient to maintain sterically overcrowded cis conformations of the complexes. The interplay between protonation stage of the ligands and their conformations can be a reason of significant differences in in‐vitro cytotoxicity between CAP complexes and their PTA‐bearing counterparts.

U2 - 10.1002/slct.201701819

DO - 10.1002/slct.201701819

M3 - Article

VL - 2

SP - 8721

EP - 8725

JO - ChemistrySelect

JF - ChemistrySelect

SN - 2365-6549

ER -

ID: 9151522