Research output: Contribution to journal › Article › peer-review
Oxysulfates of copper, sodium, and potassium in the lava flows of the 2012-2013 Tolbachik Fissure Eruption. / Karpov, G.A.; Krivovichev, S.V.; Vergasova, L.P.; Chernyat'eva, A.P.; Anikin, L.P.; Moskaleva, S.V.; Filatov, S.K.
In: Journal of Volcanology and Seismology, No. 6, 2013, p. 362-370.Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - Oxysulfates of copper, sodium, and potassium in the lava flows of the 2012-2013 Tolbachik Fissure Eruption
AU - Karpov, G.A.
AU - Krivovichev, S.V.
AU - Vergasova, L.P.
AU - Chernyat'eva, A.P.
AU - Anikin, L.P.
AU - Moskaleva, S.V.
AU - Filatov, S.K.
PY - 2013
Y1 - 2013
N2 - Samples from the surface of lava flows discharged by the 2012-2013 Tolbachik Fissure Eruption were found to contain oxysulfates of copper, sodium, and potassium: K2Cu3O(SO4)2 (fedotovite), NaKCu2O(SO4)2, and Na3K5Cu8O4(SO4)8. The last two phases have no naturally occurring or synthetic analogues that we are aware of. They form flattened crystals of prismatic to long-prismatic habits. The crystals of Na3K5Cu8O4(SO4)8 have a chemical composition corresponding to the empirical formula Na2.22K5.47Cu8.02S8.05O36. An X-ray analysis of this compound showed that it has a monoclinic symmetry, P2/c, a = 13.909(4), b = 4.977(1), c = 23.525(6) Å, β = 90.021(5)°, V = 1628.3(7) Å3. The crystal structure was determined by direct techniques and refined to yield R 1 for 3955 reflexes//web// with F 2 > 4σF. The compound NaKCu2O(SO4)2 also belongs to the monoclinic system, P2/c, a = 14.111(4), b = 4.946(1), c = 23.673(6) Å, β = 92.052(6)°, V = 1651.1(8) Å3. The structure was determined by direct techniques to yield a tentative
AB - Samples from the surface of lava flows discharged by the 2012-2013 Tolbachik Fissure Eruption were found to contain oxysulfates of copper, sodium, and potassium: K2Cu3O(SO4)2 (fedotovite), NaKCu2O(SO4)2, and Na3K5Cu8O4(SO4)8. The last two phases have no naturally occurring or synthetic analogues that we are aware of. They form flattened crystals of prismatic to long-prismatic habits. The crystals of Na3K5Cu8O4(SO4)8 have a chemical composition corresponding to the empirical formula Na2.22K5.47Cu8.02S8.05O36. An X-ray analysis of this compound showed that it has a monoclinic symmetry, P2/c, a = 13.909(4), b = 4.977(1), c = 23.525(6) Å, β = 90.021(5)°, V = 1628.3(7) Å3. The crystal structure was determined by direct techniques and refined to yield R 1 for 3955 reflexes//web// with F 2 > 4σF. The compound NaKCu2O(SO4)2 also belongs to the monoclinic system, P2/c, a = 14.111(4), b = 4.946(1), c = 23.673(6) Å, β = 92.052(6)°, V = 1651.1(8) Å3. The structure was determined by direct techniques to yield a tentative
U2 - 10.1134/S0742046313060031
DO - 10.1134/S0742046313060031
M3 - Article
SP - 362
EP - 370
JO - Journal of Volcanology and Seismology
JF - Journal of Volcanology and Seismology
SN - 0742-0463
IS - 6
ER -
ID: 7520774