DOI

  • Andrey N. Usoltsev
  • Nikita A. Korobeynikov
  • Boris A. Kolesov
  • Alexander S. Novikov
  • Pavel A. Abramov
  • Maxim N. Sokolov
  • Sergey A. Adonin

Reaction of SeO2, tetramethylammonium (TMA) chloride, aqueous HCl and Cl2 yields oxochloroselenate with incorporated Cl2 units, TMA3{[Se2O2Cl7](Cl2)}. The main feature of this compound is the strong (up to 3.5 kcal mol−1, according to DFT calculations) Cl⋅⋅⋅Cl bonding, which is also detected by Raman spectroscopy.

Original languageEnglish
Pages (from-to)9292-9294
Number of pages3
JournalChemistry - A European Journal
Volume27
Issue number36
Early online date22 Apr 2021
DOIs
StatePublished - 25 Jun 2021

    Scopus subject areas

  • Catalysis
  • Organic Chemistry

    Research areas

  • dichlorine, halides, halogen bonding, noncovalent interactions, selenium, PHENYLTRIMETHYLAMMONIUM SALTS, ANIONS, OXOTRIHALOGENOSELENATES(IV), CRYSTAL-STRUCTURE, COMPLEXES, NONABROMOANTIMONATE(V), NONCOVALENT INTERACTIONS, MONOANIONS, BROMINE, CENTER-DOT

ID: 77245150