Research output: Contribution to journal › Article › peer-review
Reaction of SeO2, tetramethylammonium (TMA) chloride, aqueous HCl and Cl2 yields oxochloroselenate with incorporated Cl2 units, TMA3{[Se2O2Cl7](Cl2)}. The main feature of this compound is the strong (up to 3.5 kcal mol−1, according to DFT calculations) Cl⋅⋅⋅Cl bonding, which is also detected by Raman spectroscopy.
Original language | English |
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Pages (from-to) | 9292-9294 |
Number of pages | 3 |
Journal | Chemistry - A European Journal |
Volume | 27 |
Issue number | 36 |
Early online date | 22 Apr 2021 |
DOIs | |
State | Published - 25 Jun 2021 |
ID: 77245150