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Oxidative monofluorination of 1,4-diiodo(dibromo)-2,3,5,6-tetramethylbenzenes in the system PbO2–HF–Py–CH2Cl2. / Каляев, Михаил Владимирович; Рябухин, Дмитрий Сергеевич; Васильев, Александр Викторович.

In: Russian Journal of Organic Chemistry, Vol. 60, No. 1, 2024, p. 56-60.

Research output: Contribution to journal › Article › peer-review

Harvard

Каляев, МВ, Рябухин, ДС & Васильев, АВ 2024, 'Oxidative monofluorination of 1,4-diiodo(dibromo)-2,3,5,6-tetramethylbenzenes in the system PbO2–HF–Py–CH2Cl2.', Russian Journal of Organic Chemistry, vol. 60, no. 1, pp. 56-60. https://doi.org/10.1134/s1070428024010081

APA

Каляев, М. В., Рябухин, Д. С., & Васильев, А. В. (2024). Oxidative monofluorination of 1,4-diiodo(dibromo)-2,3,5,6-tetramethylbenzenes in the system PbO2–HF–Py–CH2Cl2. Russian Journal of Organic Chemistry, 60(1), 56-60. https://doi.org/10.1134/s1070428024010081

Vancouver

Каляев МВ, Рябухин ДС, Васильев АВ. Oxidative monofluorination of 1,4-diiodo(dibromo)-2,3,5,6-tetramethylbenzenes in the system PbO2–HF–Py–CH2Cl2. Russian Journal of Organic Chemistry. 2024;60(1):56-60. https://doi.org/10.1134/s1070428024010081

Author

Каляев, Михаил Владимирович ; Рябухин, Дмитрий Сергеевич ; Васильев, Александр Викторович. / Oxidative monofluorination of 1,4-diiodo(dibromo)-2,3,5,6-tetramethylbenzenes in the system PbO2–HF–Py–CH2Cl2. In: Russian Journal of Organic Chemistry. 2024 ; Vol. 60, No. 1. pp. 56-60.

BibTeX

@article{2dad275ee0f5424685e386613ff48e1e,
title = "Oxidative monofluorination of 1,4-diiodo(dibromo)-2,3,5,6-tetramethylbenzenes in the system PbO2–HF–Py–CH2Cl2.",
abstract = "Abstract: The oxidation of 1,4-diiodo-2,3,5,6-tetramethylbenzene (diiododurene) and 1,4-dibromo-2,3,5,6-tetramethylbenzene (dibromodurene) with lead dioxide (PbO2) in a mixture of hydrogen fluoride and pyridine (Olahʼs reagent) and methylene chloride as co-solvent at room temperature for 96 h afforded the corresponding monofluorination products of one methyl group. This reaction is the first example of using the oxidative system PbO2–HF–Py–CH2Cl2 for the side-chain monofluorination of methylbenzenes.",
keywords = "hydrogen fluoride–pyridine, lead dioxide, monofluorination, oxidation, radical cations",
author = "Каляев, {Михаил Владимирович} and Рябухин, {Дмитрий Сергеевич} and Васильев, {Александр Викторович}",
note = "Kalyaev M.V., Ryabukhin D.S., Vasilyev A.V. Oxidative monofluorination of 1,4-diiodo(dibromo)-2,3,5,6-tetramethylbenzenes in the system PbO2–HF–Py–CH2Cl2. Russian Journal of Organic Chemistry. 2024, V. 60, No. 1, P. 56-60.",
year = "2024",
doi = "10.1134/s1070428024010081",
language = "English",
volume = "60",
pages = "56--60",
journal = "Russian Journal of Organic Chemistry",
issn = "1070-4280",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "1",

}

RIS

TY - JOUR

T1 - Oxidative monofluorination of 1,4-diiodo(dibromo)-2,3,5,6-tetramethylbenzenes in the system PbO2–HF–Py–CH2Cl2.

AU - Каляев, Михаил Владимирович

AU - Рябухин, Дмитрий Сергеевич

AU - Васильев, Александр Викторович

N1 - Kalyaev M.V., Ryabukhin D.S., Vasilyev A.V. Oxidative monofluorination of 1,4-diiodo(dibromo)-2,3,5,6-tetramethylbenzenes in the system PbO2–HF–Py–CH2Cl2. Russian Journal of Organic Chemistry. 2024, V. 60, No. 1, P. 56-60.

PY - 2024

Y1 - 2024

N2 - Abstract: The oxidation of 1,4-diiodo-2,3,5,6-tetramethylbenzene (diiododurene) and 1,4-dibromo-2,3,5,6-tetramethylbenzene (dibromodurene) with lead dioxide (PbO2) in a mixture of hydrogen fluoride and pyridine (Olahʼs reagent) and methylene chloride as co-solvent at room temperature for 96 h afforded the corresponding monofluorination products of one methyl group. This reaction is the first example of using the oxidative system PbO2–HF–Py–CH2Cl2 for the side-chain monofluorination of methylbenzenes.

AB - Abstract: The oxidation of 1,4-diiodo-2,3,5,6-tetramethylbenzene (diiododurene) and 1,4-dibromo-2,3,5,6-tetramethylbenzene (dibromodurene) with lead dioxide (PbO2) in a mixture of hydrogen fluoride and pyridine (Olahʼs reagent) and methylene chloride as co-solvent at room temperature for 96 h afforded the corresponding monofluorination products of one methyl group. This reaction is the first example of using the oxidative system PbO2–HF–Py–CH2Cl2 for the side-chain monofluorination of methylbenzenes.

KW - hydrogen fluoride–pyridine

KW - lead dioxide

KW - monofluorination

KW - oxidation

KW - radical cations

UR - https://www.mendeley.com/catalogue/be666a3d-2d0b-3a4a-9cf8-5489d0ed80ad/

U2 - 10.1134/s1070428024010081

DO - 10.1134/s1070428024010081

M3 - Article

VL - 60

SP - 56

EP - 60

JO - Russian Journal of Organic Chemistry

JF - Russian Journal of Organic Chemistry

SN - 1070-4280

IS - 1

ER -

ID: 126750903