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Oxidation of aromatic compounds : VII oxidation of symmetrically substituted 1,3-diarylpropynones in the system CF3COOH-CH2Cl2-PbO2. New synthesis method of 1,1,2,2-tetraaroylethenes. / Vasil'ev, A. V.; Rudenko, A. P.; Grinenko, E. V.

In: Russian Journal of Organic Chemistry, Vol. 36, No. 8, 01.08.2000, p. 1157-1162.

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@article{101cacba55754cf5928d3e966aaf2453,
title = "Oxidation of aromatic compounds: VII oxidation of symmetrically substituted 1,3-diarylpropynones in the system CF3COOH-CH2Cl2-PbO2. New synthesis method of 1,1,2,2-tetraaroylethenes",
abstract = "Preparative oxidation of 1,3-diarypropynones ArC≡CCOAr in a system CF3COOH-CH2Cl2-PbO2 at 18-20°C within 1.5-25 h results in 1,1,2,2-tetraaroylethenes (ArCO)2C= C(COAr)2 in yields up to 75%. The most easily and efficiently the products form from the substrates where the aryl moiety conjugated with the triple bond contains electron-donating substituents p-MeO, p-Me, and p-t-Bu. On heating with hydrazine 1,1,2,2-tetrakis(4-methoxyphenylcarbonyl)ethene is converted into heterocyclic structures: pyridazine and 2,3,6,7-tetraazanaphthalene derivatives.",
author = "Vasil'ev, {A. V.} and Rudenko, {A. P.} and Grinenko, {E. V.}",
year = "2000",
month = aug,
day = "1",
language = "English",
volume = "36",
pages = "1157--1162",
journal = "Russian Journal of Organic Chemistry",
issn = "1070-4280",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "8",

}

RIS

TY - JOUR

T1 - Oxidation of aromatic compounds

T2 - VII oxidation of symmetrically substituted 1,3-diarylpropynones in the system CF3COOH-CH2Cl2-PbO2. New synthesis method of 1,1,2,2-tetraaroylethenes

AU - Vasil'ev, A. V.

AU - Rudenko, A. P.

AU - Grinenko, E. V.

PY - 2000/8/1

Y1 - 2000/8/1

N2 - Preparative oxidation of 1,3-diarypropynones ArC≡CCOAr in a system CF3COOH-CH2Cl2-PbO2 at 18-20°C within 1.5-25 h results in 1,1,2,2-tetraaroylethenes (ArCO)2C= C(COAr)2 in yields up to 75%. The most easily and efficiently the products form from the substrates where the aryl moiety conjugated with the triple bond contains electron-donating substituents p-MeO, p-Me, and p-t-Bu. On heating with hydrazine 1,1,2,2-tetrakis(4-methoxyphenylcarbonyl)ethene is converted into heterocyclic structures: pyridazine and 2,3,6,7-tetraazanaphthalene derivatives.

AB - Preparative oxidation of 1,3-diarypropynones ArC≡CCOAr in a system CF3COOH-CH2Cl2-PbO2 at 18-20°C within 1.5-25 h results in 1,1,2,2-tetraaroylethenes (ArCO)2C= C(COAr)2 in yields up to 75%. The most easily and efficiently the products form from the substrates where the aryl moiety conjugated with the triple bond contains electron-donating substituents p-MeO, p-Me, and p-t-Bu. On heating with hydrazine 1,1,2,2-tetrakis(4-methoxyphenylcarbonyl)ethene is converted into heterocyclic structures: pyridazine and 2,3,6,7-tetraazanaphthalene derivatives.

UR - http://www.scopus.com/inward/record.url?scp=0034239448&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0034239448

VL - 36

SP - 1157

EP - 1162

JO - Russian Journal of Organic Chemistry

JF - Russian Journal of Organic Chemistry

SN - 1070-4280

IS - 8

ER -

ID: 44015066