A new method of visualization of lone pairs is proposed using fluorine atoms in fluoroacetylene, trifluoroethylene, and fluoroform (sp, sp ², and sp ³ hybridized carbons) as an example. The space around fluorines was probed by a helium atom and at each point ³He NMR chemical shift δ _He and its Laplacian ∇ ²δ _He were calculated. The ∇ ²δ _He isosurfaces have symmetrical toroidal shapes along CF axes; the maximum values of ∇ ²δ _He are reached at about 1.5 Å from fluorine atom center in the direction roughly coinciding with the lone pair localization. The absolute values of the ∇ ²δ _He could be used to quantify the electron-rich regions of lone pairs. The results are compared with more common visualization methods—3D maps of the molecular electrostatic potential and the electron localization function. We show that a helium atom could be used for evaluation of fine features of molecular electronic shell, since ³He NMR spectral characteristics remain sensitive at relatively large distances.