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Organically Templated Layered Uranyl Molybdate [C3H9NH+]4[(UO2)3(MoO4)5] Structurally Based on Mineral-Related Modular Units. / Nazarchuk, Evgeny ; Charkin, Dmitri ; Siidra, Oleg ; Kalmykov , Stepan .

In: Minerals, Vol. 10, No. 8, 659, 08.2020, p. 1-12.

Research output: Contribution to journal › Article › peer-review

Harvard

Nazarchuk, E, Charkin, D, Siidra, O & Kalmykov , S 2020, 'Organically Templated Layered Uranyl Molybdate [C3H9NH+]4[(UO2)3(MoO4)5] Structurally Based on Mineral-Related Modular Units', Minerals, vol. 10, no. 8, 659, pp. 1-12. https://doi.org/10.3390/min10080659

APA

Nazarchuk, E., Charkin, D., Siidra, O., & Kalmykov , S. (2020). Organically Templated Layered Uranyl Molybdate [C3H9NH+]4[(UO2)3(MoO4)5] Structurally Based on Mineral-Related Modular Units. Minerals, 10(8), 1-12. [659]. https://doi.org/10.3390/min10080659

Vancouver

Nazarchuk E, Charkin D, Siidra O, Kalmykov S. Organically Templated Layered Uranyl Molybdate [C3H9NH+]4[(UO2)3(MoO4)5] Structurally Based on Mineral-Related Modular Units. Minerals. 2020 Aug;10(8):1-12. 659. https://doi.org/10.3390/min10080659

Author

Nazarchuk, Evgeny ; Charkin, Dmitri ; Siidra, Oleg ; Kalmykov , Stepan . / Organically Templated Layered Uranyl Molybdate [C3H9NH+]4[(UO2)3(MoO4)5] Structurally Based on Mineral-Related Modular Units. In: Minerals. 2020 ; Vol. 10, No. 8. pp. 1-12.

BibTeX

@article{fe22083351b54a7d8239c3323fea10e4,
title = "Organically Templated Layered Uranyl Molybdate [C3H9NH+]4[(UO2)3(MoO4)5] Structurally Based on Mineral-Related Modular Units",
abstract = "A new organically templated uranyl molybdate [C3H9NH+]4[(UO2)3(MoO4)5] was prepared by a hydrothermal method at 220 °C. The compound is monoclinic, Сс, a = 16.768(6), b = 20.553(8), c = 11.897(4) {\AA}, β = 108.195(7), V = 3895(2) {\AA}3, R1 = 0.05. The crystal structure is based upon [(UO2)3(MoO4)5]4− uranyl molybdate layers. The isopropylammonium cations are located in the interlayer. The layers in the structure of [C3H9NH+]4[(UO2)3(MoO4)5] are considered as modular architectures. Topological analysis of layers with UO2:TO4 ratio of 3:5 (TVI = S, Cr, Se, Mo) was performed. Modular description is employed to elucidate the relationships between different structural topologies of [(UO2)3(TO4)5]4− layers and inorganic uranyl-based nanotubules. The possible existence of uranyl molybdate nanotubules is discussed.",
keywords = "Crystal structure, Layered structures, Minerals, Nanotubules, Uranyl molybdates, Uranyl selenates, Uranyl sulfates",
author = "Evgeny Nazarchuk and Dmitri Charkin and Oleg Siidra and Stepan Kalmykov",
note = "Funding Information: Funding: This work was financially supported by the Russian Science Foundation through the grant 16-17-10085. Funding Information: Acknowledgments: Technical support by the SPbSU X-ray Diffraction and Microscopy and Microanalysis Resource Centers is gratefully acknowledged.",
year = "2020",
month = aug,
doi = "10.3390/min10080659",
language = "English",
volume = "10",
pages = "1--12",
journal = "Minerals",
issn = "2075-163X",
publisher = "MDPI AG",
number = "8",

}

RIS

TY - JOUR

T1 - Organically Templated Layered Uranyl Molybdate [C3H9NH+]4[(UO2)3(MoO4)5] Structurally Based on Mineral-Related Modular Units

AU - Nazarchuk, Evgeny

AU - Charkin, Dmitri

AU - Siidra, Oleg

AU - Kalmykov , Stepan

N1 - Funding Information: Funding: This work was financially supported by the Russian Science Foundation through the grant 16-17-10085. Funding Information: Acknowledgments: Technical support by the SPbSU X-ray Diffraction and Microscopy and Microanalysis Resource Centers is gratefully acknowledged.

PY - 2020/8

Y1 - 2020/8

N2 - A new organically templated uranyl molybdate [C3H9NH+]4[(UO2)3(MoO4)5] was prepared by a hydrothermal method at 220 °C. The compound is monoclinic, Сс, a = 16.768(6), b = 20.553(8), c = 11.897(4) Å, β = 108.195(7), V = 3895(2) Å3, R1 = 0.05. The crystal structure is based upon [(UO2)3(MoO4)5]4− uranyl molybdate layers. The isopropylammonium cations are located in the interlayer. The layers in the structure of [C3H9NH+]4[(UO2)3(MoO4)5] are considered as modular architectures. Topological analysis of layers with UO2:TO4 ratio of 3:5 (TVI = S, Cr, Se, Mo) was performed. Modular description is employed to elucidate the relationships between different structural topologies of [(UO2)3(TO4)5]4− layers and inorganic uranyl-based nanotubules. The possible existence of uranyl molybdate nanotubules is discussed.

AB - A new organically templated uranyl molybdate [C3H9NH+]4[(UO2)3(MoO4)5] was prepared by a hydrothermal method at 220 °C. The compound is monoclinic, Сс, a = 16.768(6), b = 20.553(8), c = 11.897(4) Å, β = 108.195(7), V = 3895(2) Å3, R1 = 0.05. The crystal structure is based upon [(UO2)3(MoO4)5]4− uranyl molybdate layers. The isopropylammonium cations are located in the interlayer. The layers in the structure of [C3H9NH+]4[(UO2)3(MoO4)5] are considered as modular architectures. Topological analysis of layers with UO2:TO4 ratio of 3:5 (TVI = S, Cr, Se, Mo) was performed. Modular description is employed to elucidate the relationships between different structural topologies of [(UO2)3(TO4)5]4− layers and inorganic uranyl-based nanotubules. The possible existence of uranyl molybdate nanotubules is discussed.

KW - Crystal structure

KW - Layered structures

KW - Minerals

KW - Nanotubules

KW - Uranyl molybdates

KW - Uranyl selenates

KW - Uranyl sulfates

UR - http://www.scopus.com/inward/record.url?scp=85090694107&partnerID=8YFLogxK

U2 - 10.3390/min10080659

DO - 10.3390/min10080659

M3 - Article

VL - 10

SP - 1

EP - 12

JO - Minerals

JF - Minerals

SN - 2075-163X

IS - 8

M1 - 659

ER -

ID: 61398132