Research output: Contribution to journal › Article › peer-review
Orbit-Orbit Interaction in Two-Electron Matrices of the Energy Operator for pf Configurations. / Anisimova, G. P.; Kapel'kina, E. L.
In: Optics and Spectroscopy (English translation of Optika i Spektroskopiya), Vol. 87, No. 6, 01.12.1999, p. 805-811.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Orbit-Orbit Interaction in Two-Electron Matrices of the Energy Operator for pf Configurations
AU - Anisimova, G. P.
AU - Kapel'kina, E. L.
PY - 1999/12/1
Y1 - 1999/12/1
N2 - Expressions are obtained for calculation of the direct and exchange matrix elements of the energy operator for the orbit-orbit and electrostatic interactions in the representation of uncoupled angular momenta for the pf configuration. Comparison of the expressions for exchange matrix elements of these interactions showed their similarity. This allows one to additionally verify the matrix elements of the orbit-orbit interaction, whose calculation is more complicated, compared to that of the electrostatic matrix elements. The angular parts of the matrix elements are calculated using the formalism of irreducible tensor operators. The correctness of the expressions derived for the pf electron configuration was also verified in the LSJM representation. The orbit-orbit interaction is represented in the matrix elements by the radial integrals of the Marvin spin interactions.
AB - Expressions are obtained for calculation of the direct and exchange matrix elements of the energy operator for the orbit-orbit and electrostatic interactions in the representation of uncoupled angular momenta for the pf configuration. Comparison of the expressions for exchange matrix elements of these interactions showed their similarity. This allows one to additionally verify the matrix elements of the orbit-orbit interaction, whose calculation is more complicated, compared to that of the electrostatic matrix elements. The angular parts of the matrix elements are calculated using the formalism of irreducible tensor operators. The correctness of the expressions derived for the pf electron configuration was also verified in the LSJM representation. The orbit-orbit interaction is represented in the matrix elements by the radial integrals of the Marvin spin interactions.
UR - http://www.scopus.com/inward/record.url?scp=0346499229&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0346499229
VL - 87
SP - 805
EP - 811
JO - OPTICS AND SPECTROSCOPY
JF - OPTICS AND SPECTROSCOPY
SN - 0030-400X
IS - 6
ER -
ID: 36206228