Research output: Contribution to journal › Article › peer-review
Optical properties of dextran in solution and in films. / Pavlov, G. M.; Grishchenko, A. E.; Rjumtsev, E. I.; Yevlampieva, N. P.
In: Carbohydrate Polymers, Vol. 38, No. 3, 03.1999, p. 267-271.Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - Optical properties of dextran in solution and in films
AU - Pavlov, G. M.
AU - Grishchenko, A. E.
AU - Rjumtsev, E. I.
AU - Yevlampieva, N. P.
PY - 1999/3
Y1 - 1999/3
N2 - Flow birefringence of dextran solutions in dimethylsulphoxide was studied and the intrinsic optical anisotropy (α1-α2) of its chains was determined to be +12.5×10-25 cm3. The dependence of birefringence in dextran films of different thickness on the angle of incidence of polarized light was then studied and the surface birefringence of the film was determined. The dependence of surface birefringence on film thickness has made it possible to determine the effective thickness of the anisotropic near-surface layer, while the comparison of the surface birefringence with the value of (α1-α2) enabled the estimation of the orientation of the molecular fragments with respect to the film surface.
AB - Flow birefringence of dextran solutions in dimethylsulphoxide was studied and the intrinsic optical anisotropy (α1-α2) of its chains was determined to be +12.5×10-25 cm3. The dependence of birefringence in dextran films of different thickness on the angle of incidence of polarized light was then studied and the surface birefringence of the film was determined. The dependence of surface birefringence on film thickness has made it possible to determine the effective thickness of the anisotropic near-surface layer, while the comparison of the surface birefringence with the value of (α1-α2) enabled the estimation of the orientation of the molecular fragments with respect to the film surface.
KW - Birefringence
KW - Dextran
KW - Film
KW - Solution
UR - http://www.scopus.com/inward/record.url?scp=0033098966&partnerID=8YFLogxK
U2 - 10.1016/S0144-8617(98)00101-5
DO - 10.1016/S0144-8617(98)00101-5
M3 - Article
AN - SCOPUS:0033098966
VL - 38
SP - 267
EP - 271
JO - Carbohydrate Polymers
JF - Carbohydrate Polymers
SN - 0144-8617
IS - 3
ER -
ID: 94263769