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Optical population of free iodine molecule ion-pair states and their RgI2(IP) complexes via RgI2 vdW complexes of valence states correlating with the third dissociation limit. / Lukashov, S. S.; Novikova, I. Yu; Poretsky, S. A.; Pravilov, A. M.; Torgashkova, A. S.

In: Chemical Physics, Vol. 336, No. 2-3, 27.07.2007, p. 109-120.

Research output: Contribution to journal › Article › peer-review

Harvard

Lukashov, SS, Novikova, IY, Poretsky, SA, Pravilov, AM & Torgashkova, AS 2007, 'Optical population of free iodine molecule ion-pair states and their RgI2(IP) complexes via RgI2 vdW complexes of valence states correlating with the third dissociation limit', Chemical Physics, vol. 336, no. 2-3, pp. 109-120. https://doi.org/10.1016/j.chemphys.2007.05.017

APA

Lukashov, S. S., Novikova, I. Y., Poretsky, S. A., Pravilov, A. M., & Torgashkova, A. S. (2007). Optical population of free iodine molecule ion-pair states and their RgI2(IP) complexes via RgI2 vdW complexes of valence states correlating with the third dissociation limit. Chemical Physics, 336(2-3), 109-120. https://doi.org/10.1016/j.chemphys.2007.05.017

Vancouver

Lukashov SS, Novikova IY, Poretsky SA, Pravilov AM, Torgashkova AS. Optical population of free iodine molecule ion-pair states and their RgI2(IP) complexes via RgI2 vdW complexes of valence states correlating with the third dissociation limit. Chemical Physics. 2007 Jul 27;336(2-3):109-120. https://doi.org/10.1016/j.chemphys.2007.05.017

Author

Lukashov, S. S. ; Novikova, I. Yu ; Poretsky, S. A. ; Pravilov, A. M. ; Torgashkova, A. S. / Optical population of free iodine molecule ion-pair states and their RgI2(IP) complexes via RgI2 vdW complexes of valence states correlating with the third dissociation limit. In: Chemical Physics. 2007 ; Vol. 336, No. 2-3. pp. 109-120.

BibTeX

@article{56a4e5e20ad54ba7bf1c1e286d9194d2,
title = "Optical population of free iodine molecule ion-pair states and their RgI2(IP) complexes via RgI2 vdW complexes of valence states correlating with the third dissociation limit",
abstract = "Spectral and kinetic analysis of luminescence in the λ = 220-500 nm spectral range observed after three-step, 532.124 + 1024.48 + 532.24 nm, laser excitation of the I2 + Rg mixtures, Rg = He-Xe, in wide 2. 7-100 Torr Rg pressures shows that one cannot describe the spectral features as well as their dependences on Rg pressures in framework of competition of spontaneous and collision-induced processes in a free iodine molecule. The same conclusion has been drawn after analysis of the papers concerning one-photon laser photolysis of these mixtures. To explain all these data, one has to take into consideration photoexcitation of the RgI2(IP) complexes via the complexes and colliding pairs of rare gases and valence state iodine molecules.",
keywords = "Collisions, Iodine, Iodine laser, Ion-pair states, Kinetics, Luminescence, Non-adiabatic transitions, Valence states",
author = "Lukashov, {S. S.} and Novikova, {I. Yu} and Poretsky, {S. A.} and Pravilov, {A. M.} and Torgashkova, {A. S.}",
note = "Funding Information: This work was supported by the Russian Foundation for Basic Researches (Project 05-03-32371). Authors are very obliged to M.E. Akopyan for useful remarks. ",
year = "2007",
month = jul,
day = "27",
doi = "10.1016/j.chemphys.2007.05.017",
language = "English",
volume = "336",
pages = "109--120",
journal = "Chemical Physics",
issn = "0301-0104",
publisher = "Elsevier",
number = "2-3",

}

RIS

TY - JOUR

T1 - Optical population of free iodine molecule ion-pair states and their RgI2(IP) complexes via RgI2 vdW complexes of valence states correlating with the third dissociation limit

AU - Lukashov, S. S.

AU - Novikova, I. Yu

AU - Poretsky, S. A.

AU - Pravilov, A. M.

AU - Torgashkova, A. S.

N1 - Funding Information: This work was supported by the Russian Foundation for Basic Researches (Project 05-03-32371). Authors are very obliged to M.E. Akopyan for useful remarks.

PY - 2007/7/27

Y1 - 2007/7/27

N2 - Spectral and kinetic analysis of luminescence in the λ = 220-500 nm spectral range observed after three-step, 532.124 + 1024.48 + 532.24 nm, laser excitation of the I2 + Rg mixtures, Rg = He-Xe, in wide 2. 7-100 Torr Rg pressures shows that one cannot describe the spectral features as well as their dependences on Rg pressures in framework of competition of spontaneous and collision-induced processes in a free iodine molecule. The same conclusion has been drawn after analysis of the papers concerning one-photon laser photolysis of these mixtures. To explain all these data, one has to take into consideration photoexcitation of the RgI2(IP) complexes via the complexes and colliding pairs of rare gases and valence state iodine molecules.

AB - Spectral and kinetic analysis of luminescence in the λ = 220-500 nm spectral range observed after three-step, 532.124 + 1024.48 + 532.24 nm, laser excitation of the I2 + Rg mixtures, Rg = He-Xe, in wide 2. 7-100 Torr Rg pressures shows that one cannot describe the spectral features as well as their dependences on Rg pressures in framework of competition of spontaneous and collision-induced processes in a free iodine molecule. The same conclusion has been drawn after analysis of the papers concerning one-photon laser photolysis of these mixtures. To explain all these data, one has to take into consideration photoexcitation of the RgI2(IP) complexes via the complexes and colliding pairs of rare gases and valence state iodine molecules.

KW - Collisions

KW - Iodine

KW - Iodine laser

KW - Ion-pair states

KW - Kinetics

KW - Luminescence

KW - Non-adiabatic transitions

KW - Valence states

UR - http://www.scopus.com/inward/record.url?scp=34447505932&partnerID=8YFLogxK

U2 - 10.1016/j.chemphys.2007.05.017

DO - 10.1016/j.chemphys.2007.05.017

M3 - Article

AN - SCOPUS:34447505932

VL - 336

SP - 109

EP - 120

JO - Chemical Physics

JF - Chemical Physics

SN - 0301-0104

IS - 2-3

ER -

ID: 91127551