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On the formulation of the material equilibrium condition for a dissolving solid nanoparticle. / Rusanov, A. I.; Shchekin, A. K.

In: Journal of Chemical Physics, Vol. 127, No. 19, 191102, 29.11.2007.

Research output: Contribution to journal › Article › peer-review

Harvard

Rusanov, AI & Shchekin, AK 2007, 'On the formulation of the material equilibrium condition for a dissolving solid nanoparticle', Journal of Chemical Physics, vol. 127, no. 19, 191102. https://doi.org/10.1063/1.2818049

APA

Rusanov, A. I., & Shchekin, A. K. (2007). On the formulation of the material equilibrium condition for a dissolving solid nanoparticle. Journal of Chemical Physics, 127(19), [191102]. https://doi.org/10.1063/1.2818049

Vancouver

Rusanov AI, Shchekin AK. On the formulation of the material equilibrium condition for a dissolving solid nanoparticle. Journal of Chemical Physics. 2007 Nov 29;127(19). 191102. https://doi.org/10.1063/1.2818049

Author

Rusanov, A. I. ; Shchekin, A. K. / On the formulation of the material equilibrium condition for a dissolving solid nanoparticle. In: Journal of Chemical Physics. 2007 ; Vol. 127, No. 19.

BibTeX

@article{a35a8b148db3400aa1692a26f0c3ffb5,
title = "On the formulation of the material equilibrium condition for a dissolving solid nanoparticle",
abstract = "Widely known Gibbs' relationship predicting a difference of chemical potentials in a small solid particle and in a surrounding fluid phase at equilibrium is shown to refer to a real or imaginary bulk phase inside the particle. A similar relationship derived for the real surface monolayer of a nanoparticle exhibits the equality of chemical potentials at equilibrium, which allows for experimental measurement of the surface chemical potential of a dissolving solid nanoparticle.",
author = "Rusanov, {A. I.} and Shchekin, {A. K.}",
year = "2007",
month = nov,
day = "29",
doi = "10.1063/1.2818049",
language = "English",
volume = "127",
journal = "Journal of Chemical Physics",
issn = "0021-9606",
publisher = "American Institute of Physics",
number = "19",

}

RIS

TY - JOUR

T1 - On the formulation of the material equilibrium condition for a dissolving solid nanoparticle

AU - Rusanov, A. I.

AU - Shchekin, A. K.

PY - 2007/11/29

Y1 - 2007/11/29

N2 - Widely known Gibbs' relationship predicting a difference of chemical potentials in a small solid particle and in a surrounding fluid phase at equilibrium is shown to refer to a real or imaginary bulk phase inside the particle. A similar relationship derived for the real surface monolayer of a nanoparticle exhibits the equality of chemical potentials at equilibrium, which allows for experimental measurement of the surface chemical potential of a dissolving solid nanoparticle.

AB - Widely known Gibbs' relationship predicting a difference of chemical potentials in a small solid particle and in a surrounding fluid phase at equilibrium is shown to refer to a real or imaginary bulk phase inside the particle. A similar relationship derived for the real surface monolayer of a nanoparticle exhibits the equality of chemical potentials at equilibrium, which allows for experimental measurement of the surface chemical potential of a dissolving solid nanoparticle.

UR - http://www.scopus.com/inward/record.url?scp=36348956089&partnerID=8YFLogxK

U2 - 10.1063/1.2818049

DO - 10.1063/1.2818049

M3 - Article

VL - 127

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

SN - 0021-9606

IS - 19

M1 - 191102

ER -

ID: 5102882