A chemical reaction front where an oxidation reaction is localized is considered as an internal surface dividing two solid deformable constituents. The reaction is sustained and controlled by the diffusion of the gas constituent through the oxide layer. The transformation strains produced by the chemical reaction lead to internal stresses which in turn affect the chemical reactions front kinetics. Analitical solution of axially-symmetric mechano-chemistry problems in a case of small strain approach are obtained. We examine how stress state affects the reaction front kinetics and demonstrate reaction locking effects due to internal stresses. We also study how the reaction rate depends on the chemical reaction front curvature.
Original languageEnglish
Title of host publicationSurface Effects in Solid Mechanics
Subtitle of host publicationModels, Simulations and Applications
PublisherSpringer Nature
Pages181-194
ISBN (Print)978-3-642-35782-4 (Print) 978-3-642-35783-1 (Online)
DOIs
StatePublished - 2013

Publication series

NameAdvanced Structured Materials
Volume30

ID: 4666103