Both thermodynamic and kinetic approaches are employed to interpret data revealing a hysteresis effect during the growth/evaporation of hygroscopic particles in an ambient solvent vapour. For given thermodynamic parameters and material constants, the deliquescence humidity can be determined from the generalised Gibbs-Kelvin-Köhler and Oswald-Freundlich equations. Additionally employing the quasi-steady nucleation kinetics, we can estimate the efflorescence hu-midity. The predictive power of this approach is demonstrated for the sodium chloride-water system.
Original languageEnglish
Title of host publication18th International Conference "Nucleation and Atmospheric Aerosols", 10-14 August 2009, Prague, Chech Republic. Eds. J.Smolik and C. O’Dowd, A16.4
Editors J. Smolik, C. O’Dowd
PublisherElsevier
Pages419-422
StatePublished - 2009
Event18th International Conference "Nucleation and Atmospheric Aerosols", 10-14 August 2009, Prague, Czech Republic. - Прага, Прага, Czech Republic
Duration: 10 Aug 200914 Aug 2009
Conference number: 18
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Conference

Conference18th International Conference "Nucleation and Atmospheric Aerosols", 10-14 August 2009, Prague, Czech Republic.
Abbreviated titleICNAA 18
Country/TerritoryCzech Republic
CityПрага
Period10/08/0914/08/09
Internet address

ID: 4424953