On Changes in the Chemical Affinity during the Reaction

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On Changes in the Chemical Affinity during the Reaction. / Toikka, Alexander ; Misikov, Georgii; Volodina, Natalia; Samarov, Artemiy.

In: Russian Journal of Physical Chemistry A, Vol. 98, No. 7, 01.07.2024, p. 1478 - 1487.

Research output: Contribution to journal › Article › peer-review

Author

Toikka, Alexander ; Misikov, Georgii ; Volodina, Natalia ; Samarov, Artemiy. / On Changes in the Chemical Affinity during the Reaction. In: Russian Journal of Physical Chemistry A. 2024 ; Vol. 98, No. 7. pp. 1478 - 1487.

BibTeX

@article{41de8d54a84048c698892170ecb97da1,

title = "On Changes in the Chemical Affinity during the Reaction",

abstract = "Abstract: A brief review and analysis of research on the relationship between the chemical affinity and the kinetic characteristics of chemical reactions are presented. It is noted that there is a lack of experimental data necessary for the development of the theory, including for correlating the affinity of the chemical process with its rate. Some tendencies of variation of the chemical affinity, as well as the kinetic coefficients correlating the reaction path with its affinity, are considered using the experimental data obtained by the authors on a system with ester synthesis as an example. The potential for developing research in this area is shown.",

keywords = "chemical affinity, chemical reactions, kinetic coefficients, n-butyl acetate, vapor–liquid equilibrium",

author = "Alexander Toikka and Georgii Misikov and Natalia Volodina and Artemiy Samarov",

year = "2024",

month = jul,

day = "1",

doi = "10.1134/s003602442470047x",

language = "English",

volume = "98",

pages = " 1478 -- 1487",

journal = "Russian Journal of Physical Chemistry A",

issn = "0036-0244",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

number = "7",

}

RIS

TY - JOUR

T1 - On Changes in the Chemical Affinity during the Reaction

AU - Toikka, Alexander

AU - Misikov, Georgii

AU - Volodina, Natalia

AU - Samarov, Artemiy

PY - 2024/7/1

Y1 - 2024/7/1

N2 - Abstract: A brief review and analysis of research on the relationship between the chemical affinity and the kinetic characteristics of chemical reactions are presented. It is noted that there is a lack of experimental data necessary for the development of the theory, including for correlating the affinity of the chemical process with its rate. Some tendencies of variation of the chemical affinity, as well as the kinetic coefficients correlating the reaction path with its affinity, are considered using the experimental data obtained by the authors on a system with ester synthesis as an example. The potential for developing research in this area is shown.

AB - Abstract: A brief review and analysis of research on the relationship between the chemical affinity and the kinetic characteristics of chemical reactions are presented. It is noted that there is a lack of experimental data necessary for the development of the theory, including for correlating the affinity of the chemical process with its rate. Some tendencies of variation of the chemical affinity, as well as the kinetic coefficients correlating the reaction path with its affinity, are considered using the experimental data obtained by the authors on a system with ester synthesis as an example. The potential for developing research in this area is shown.

KW - chemical affinity

KW - chemical reactions

KW - kinetic coefficients

KW - n-butyl acetate

KW - vapor–liquid equilibrium

UR - https://www.mendeley.com/catalogue/01b07616-2a9f-31e9-9fba-298854afbe9c/

U2 - 10.1134/s003602442470047x

DO - 10.1134/s003602442470047x

M3 - Article

VL - 98

SP - 1478

EP - 1487

JO - Russian Journal of Physical Chemistry A

JF - Russian Journal of Physical Chemistry A

SN - 0036-0244

IS - 7

ER -

ID: 126924119