Observations and analysis with the spline-based Rydberg-Klein-Rees approach for the 3 1 Σ g + state of Rb2

Standard

Observations and analysis with the spline-based Rydberg-Klein-Rees approach for the 3 1 Σ g + state of Rb₂. / Yang, Jinxin; Guan, Yafei; Zhao, Wei; Zhou, Zhaoyu; Han, Xiaomin; Ma, Jie; Sovkov, Vladimir B.; Ivanov, Valery S.; Ahmed, Ergin H.; Lyyra, A. Marjatta; Dai, Xingcan.

In: Journal of Chemical Physics, Vol. 144, No. 2, 024308, 14.01.2016.

Research output: Contribution to journal › Article › peer-review

Author

Yang, Jinxin ; Guan, Yafei ; Zhao, Wei ; Zhou, Zhaoyu ; Han, Xiaomin ; Ma, Jie ; Sovkov, Vladimir B. ; Ivanov, Valery S. ; Ahmed, Ergin H. ; Lyyra, A. Marjatta ; Dai, Xingcan. / Observations and analysis with the spline-based Rydberg-Klein-Rees approach for the 3 1 Σ g + state of Rb₂. In: Journal of Chemical Physics. 2016 ; Vol. 144, No. 2.

BibTeX

@article{42db6f5297964195984ac84b990537a1,

title = "Observations and analysis with the spline-based Rydberg-Klein-Rees approach for the 3 1 Σ g + state of Rb2",

abstract = "Ro-vibrational term values of the 3 1 Σ g + state of 85,85Rb2 and 85,87Rb2 and resolved fluorescence spectra to the A 1 Σ u + state are recorded following optical-optical double resonance excitation. The experimental data are heavily perturbed, and as a result, the standard analysis based on Dunham series representation of the energy levels fails. The analysis is done via modeling the adiabatic potential function with the Rydberg-Klein-Rees potential constructed from the generalized smoothing spline interpolation of the vibrational energies Gv and rotational constants Bv.",

author = "Jinxin Yang and Yafei Guan and Wei Zhao and Zhaoyu Zhou and Xiaomin Han and Jie Ma and Sovkov, {Vladimir B.} and Ivanov, {Valery S.} and Ahmed, {Ergin H.} and Lyyra, {A. Marjatta} and Xingcan Dai",

year = "2016",

month = jan,

day = "14",

doi = "10.1063/1.4939524",

language = "English",

volume = "144",

journal = "Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics",

number = "2",

}

RIS

TY - JOUR

T1 - Observations and analysis with the spline-based Rydberg-Klein-Rees approach for the 3 1 Σ g + state of Rb2

AU - Yang, Jinxin

AU - Guan, Yafei

AU - Zhao, Wei

AU - Zhou, Zhaoyu

AU - Han, Xiaomin

AU - Ma, Jie

AU - Sovkov, Vladimir B.

AU - Ivanov, Valery S.

AU - Ahmed, Ergin H.

AU - Lyyra, A. Marjatta

AU - Dai, Xingcan

PY - 2016/1/14

Y1 - 2016/1/14

N2 - Ro-vibrational term values of the 3 1 Σ g + state of 85,85Rb2 and 85,87Rb2 and resolved fluorescence spectra to the A 1 Σ u + state are recorded following optical-optical double resonance excitation. The experimental data are heavily perturbed, and as a result, the standard analysis based on Dunham series representation of the energy levels fails. The analysis is done via modeling the adiabatic potential function with the Rydberg-Klein-Rees potential constructed from the generalized smoothing spline interpolation of the vibrational energies Gv and rotational constants Bv.

AB - Ro-vibrational term values of the 3 1 Σ g + state of 85,85Rb2 and 85,87Rb2 and resolved fluorescence spectra to the A 1 Σ u + state are recorded following optical-optical double resonance excitation. The experimental data are heavily perturbed, and as a result, the standard analysis based on Dunham series representation of the energy levels fails. The analysis is done via modeling the adiabatic potential function with the Rydberg-Klein-Rees potential constructed from the generalized smoothing spline interpolation of the vibrational energies Gv and rotational constants Bv.

UR - http://www.scopus.com/inward/record.url?scp=84954492368&partnerID=8YFLogxK

U2 - 10.1063/1.4939524

DO - 10.1063/1.4939524

M3 - Article

VL - 144

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

SN - 0021-9606

IS - 2

M1 - 024308

ER -

ID: 7550935