Research output: Contribution to conference › Abstract › peer-review
NOVEL RED-EMITTING COLOR-TUNABLE PHOSPHORS BaBi2-xEuxB2O7 (x = 0–0.40): STUDY OF THE CRYSTAL STRUCTURE AND LUMINESCENCE. / Демина, Софья Владимировна; Шаблинский, Андрей Павлович; Поволоцкий, Алексей Валерьевич; Колесников, Илья Евгеньевич; Бирюков, Я.П.; Бубнова, Римма Сергеевна; Авдонцева, Маргарита Сергеевна; Филатов, Станислав Константинович.
2022. Abstract from Geological International Student Summit 2022 , Санкт-Петербург, Russian Federation.Research output: Contribution to conference › Abstract › peer-review
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TY - CONF
T1 - NOVEL RED-EMITTING COLOR-TUNABLE PHOSPHORS BaBi2-xEuxB2O7 (x = 0–0.40): STUDY OF THE CRYSTAL STRUCTURE AND LUMINESCENCE
AU - Демина, Софья Владимировна
AU - Шаблинский, Андрей Павлович
AU - Поволоцкий, Алексей Валерьевич
AU - Колесников, Илья Евгеньевич
AU - Бирюков, Я.П.
AU - Бубнова, Римма Сергеевна
AU - Авдонцева, Маргарита Сергеевна
AU - Филатов, Станислав Константинович
PY - 2022/4/9
Y1 - 2022/4/9
N2 - The novel polycrystalline phosphors BaBi2-xEuxB2O7 (Shablinskii et al., 2019) (x = 0, 0.05, 0.10, 0.15, 0.20, 0.30, 0.40) were obtained by crystallization from glass-ceramics. Single-crystal X-ray diffraction experiments were provided for the x = 0.10, 0.20 and 0.40 samples in order to investigate a distribution of the Eu3+ ions over cation sites. It is shown that the Eu3+ ions substitute the Bi3+ ones in the M1 and M2 sites. Luminescent properties of the BaBi2-xEuxB2O7 phosphors were investigated for the first time. The optimal concentration of the Eu3+ ions was revealed for the sample with x = 0.40, after that an immiscibility of the BaBi2-xEuxB2O7 solid solutions occurs, which is of a structure-dependent nature. Increase of the Eu3+ content leads to a gradual change of chromaticity from light red to orange-red/red. It is expected that the BaBi2B2O7:Eu3+ phosphors can be used as red-emitting ones under LED excitation.
AB - The novel polycrystalline phosphors BaBi2-xEuxB2O7 (Shablinskii et al., 2019) (x = 0, 0.05, 0.10, 0.15, 0.20, 0.30, 0.40) were obtained by crystallization from glass-ceramics. Single-crystal X-ray diffraction experiments were provided for the x = 0.10, 0.20 and 0.40 samples in order to investigate a distribution of the Eu3+ ions over cation sites. It is shown that the Eu3+ ions substitute the Bi3+ ones in the M1 and M2 sites. Luminescent properties of the BaBi2-xEuxB2O7 phosphors were investigated for the first time. The optimal concentration of the Eu3+ ions was revealed for the sample with x = 0.40, after that an immiscibility of the BaBi2-xEuxB2O7 solid solutions occurs, which is of a structure-dependent nature. Increase of the Eu3+ content leads to a gradual change of chromaticity from light red to orange-red/red. It is expected that the BaBi2B2O7:Eu3+ phosphors can be used as red-emitting ones under LED excitation.
M3 - тезисы
T2 - Геологический международный студенческий саммит 2022
Y2 - 8 April 2022 through 10 April 2022
ER -
ID: 98218959