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Novel Red-Emitting BaBi2B4O10:Eu3+ Phosphors: Synthesis, Crystal Structure and Luminescence. / Shablinskii, Andrey P.; Povolotskiy, Alexey V.; Yuriev, Artem A.; Biryukov, Yaroslav P.; Bubnova, Rimma S.; Avdontceva, Margarita S.; Janson, Svetlana Yu.; Filatov, Stanislav K.

In: Symmetry, Vol. 15, No. 4, 918, 14.04.2023.

Research output: Contribution to journal › Article › peer-review

Harvard

Shablinskii, AP, Povolotskiy, AV, Yuriev, AA, Biryukov, YP, Bubnova, RS, Avdontceva, MS, Janson, SY & Filatov, SK 2023, 'Novel Red-Emitting BaBi2B4O10:Eu3+ Phosphors: Synthesis, Crystal Structure and Luminescence', Symmetry, vol. 15, no. 4, 918. https://doi.org/10.3390/sym15040918

APA

Shablinskii, A. P., Povolotskiy, A. V., Yuriev, A. A., Biryukov, Y. P., Bubnova, R. S., Avdontceva, M. S., Janson, S. Y., & Filatov, S. K. (2023). Novel Red-Emitting BaBi2B4O10:Eu3+ Phosphors: Synthesis, Crystal Structure and Luminescence. Symmetry, 15(4), [918]. https://doi.org/10.3390/sym15040918

Vancouver

Shablinskii AP, Povolotskiy AV, Yuriev AA, Biryukov YP, Bubnova RS, Avdontceva MS et al. Novel Red-Emitting BaBi2B4O10:Eu3+ Phosphors: Synthesis, Crystal Structure and Luminescence. Symmetry. 2023 Apr 14;15(4). 918. https://doi.org/10.3390/sym15040918

Author

Shablinskii, Andrey P. ; Povolotskiy, Alexey V. ; Yuriev, Artem A. ; Biryukov, Yaroslav P. ; Bubnova, Rimma S. ; Avdontceva, Margarita S. ; Janson, Svetlana Yu. ; Filatov, Stanislav K. / Novel Red-Emitting BaBi2B4O10:Eu3+ Phosphors: Synthesis, Crystal Structure and Luminescence. In: Symmetry. 2023 ; Vol. 15, No. 4.

BibTeX

@article{f236ff09ff3046ab9cd24395d1bff085,
title = "Novel Red-Emitting BaBi2B4O10:Eu3+ Phosphors: Synthesis, Crystal Structure and Luminescence",
abstract = "The novel red-emitting BaBi2−xEuxB4O10 (x = 0.05, 0.1, 0.2, 0.25, 0.3, 0.4, 0.5, 0.6) phosphors were obtained by a crystallization from a glass. Distribution of the Eu3+ ions over cation sites were refined for x = 0.1, 0.3 and 0.4 from single-crystal X-ray diffraction data. Emission and excitation spectra of the Eu3+-doped BaBi2B4O10 phosphors were investigated for the first time, where it was shown that characteristic lines are attributed to the intraconfigurational 4f-4f transitions. The optimal concentration for the BaBi2−xEuxB4O10 phosphors is x = 0.4, after which a luminescence intensity decreases. The CIE chromaticity coordinates for the BaBi2B4O10:Eu3+ (x = 0.4) phosphor (0.65, 0.35) are close to the NTSC standard values (0.67, 0.33) for commercial red phosphor. The obtained results show that the BaBi2B4O10:Eu3+ phosphors are promising candidates for solid state lighting application.",
keywords = "barium-bismuth borate, crystal structure, europium-activated phosphor, glasses, luminescence, phosphors",
author = "Shablinskii, {Andrey P.} and Povolotskiy, {Alexey V.} and Yuriev, {Artem A.} and Biryukov, {Yaroslav P.} and Bubnova, {Rimma S.} and Avdontceva, {Margarita S.} and Janson, {Svetlana Yu.} and Filatov, {Stanislav K.}",
year = "2023",
month = apr,
day = "14",
doi = "10.3390/sym15040918",
language = "English",
volume = "15",
journal = "Symmetry",
issn = "2073-8994",
publisher = "MDPI AG",
number = "4",

}

RIS

TY - JOUR

T1 - Novel Red-Emitting BaBi2B4O10:Eu3+ Phosphors: Synthesis, Crystal Structure and Luminescence

AU - Shablinskii, Andrey P.

AU - Povolotskiy, Alexey V.

AU - Yuriev, Artem A.

AU - Biryukov, Yaroslav P.

AU - Bubnova, Rimma S.

AU - Avdontceva, Margarita S.

AU - Janson, Svetlana Yu.

AU - Filatov, Stanislav K.

PY - 2023/4/14

Y1 - 2023/4/14

N2 - The novel red-emitting BaBi2−xEuxB4O10 (x = 0.05, 0.1, 0.2, 0.25, 0.3, 0.4, 0.5, 0.6) phosphors were obtained by a crystallization from a glass. Distribution of the Eu3+ ions over cation sites were refined for x = 0.1, 0.3 and 0.4 from single-crystal X-ray diffraction data. Emission and excitation spectra of the Eu3+-doped BaBi2B4O10 phosphors were investigated for the first time, where it was shown that characteristic lines are attributed to the intraconfigurational 4f-4f transitions. The optimal concentration for the BaBi2−xEuxB4O10 phosphors is x = 0.4, after which a luminescence intensity decreases. The CIE chromaticity coordinates for the BaBi2B4O10:Eu3+ (x = 0.4) phosphor (0.65, 0.35) are close to the NTSC standard values (0.67, 0.33) for commercial red phosphor. The obtained results show that the BaBi2B4O10:Eu3+ phosphors are promising candidates for solid state lighting application.

AB - The novel red-emitting BaBi2−xEuxB4O10 (x = 0.05, 0.1, 0.2, 0.25, 0.3, 0.4, 0.5, 0.6) phosphors were obtained by a crystallization from a glass. Distribution of the Eu3+ ions over cation sites were refined for x = 0.1, 0.3 and 0.4 from single-crystal X-ray diffraction data. Emission and excitation spectra of the Eu3+-doped BaBi2B4O10 phosphors were investigated for the first time, where it was shown that characteristic lines are attributed to the intraconfigurational 4f-4f transitions. The optimal concentration for the BaBi2−xEuxB4O10 phosphors is x = 0.4, after which a luminescence intensity decreases. The CIE chromaticity coordinates for the BaBi2B4O10:Eu3+ (x = 0.4) phosphor (0.65, 0.35) are close to the NTSC standard values (0.67, 0.33) for commercial red phosphor. The obtained results show that the BaBi2B4O10:Eu3+ phosphors are promising candidates for solid state lighting application.

KW - barium-bismuth borate

KW - crystal structure

KW - europium-activated phosphor

KW - glasses

KW - luminescence

KW - phosphors

UR - https://www.mendeley.com/catalogue/178e16dc-0d36-3c22-8ee4-d59dd8fc8f26/

U2 - 10.3390/sym15040918

DO - 10.3390/sym15040918

M3 - Article

VL - 15

JO - Symmetry

JF - Symmetry

SN - 2073-8994

IS - 4

M1 - 918

ER -

ID: 105152085