Novel pervaporation membranes based on hydroxyethyl cellulose/polyvinyl alcohol modified with fullerene derivatives for enhanced isopropanol dehydration

Standard

Novel pervaporation membranes based on hydroxyethyl cellulose/polyvinyl alcohol modified with fullerene derivatives for enhanced isopropanol dehydration. / Dmitrenko, Mariia ; Kuzminova, Anna ; Zolotarev, Andrey ; Liamin, Vladislav ; Markelov, Denis ; Семёнов, Константин Николаевич; Plisko, Tatiana ; Bildyukevich, Alexandr ; Penkova, Anastasia.

In: Journal of Materials Research, 30.11.2021.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{993a295ce68c4c7b8d511e42c2b1661a,

title = "Novel pervaporation membranes based on hydroxyethyl cellulose/polyvinyl alcohol modified with fullerene derivatives for enhanced isopropanol dehydration",

abstract = "The rapid implementation of membrane processes in the industry requires novel membrane materials.One of the promising ways to obtain a membrane material with improved properties is to combinethe advantages of a polymer and a modifier (in particular, carbon nanoparticles). In the present work,novel pervaporation membranes based on hydroxyethyl cellulose (HEC)/polyvinyl alcohol (PVA)blend and HEC/PVA/fullerene derivative (polyhydroxylated fullerene, carboxyfullerene, and fullerenederivative with l-arginine) composites were developed for dehydration. The membrane compositionand the cross-linking with maleic acid were optimized. The membranes were studied by Fouriertransforminfrared spectroscopy, scanning electron and atomic force microscopies, thermogravimetricanalysis, contact angle and swelling measurements. Transport properties of the membranes werestudied in the pervaporation dehydration of isopropanol. The cross-linked dense HEC/PVA(30/70 wt%)/carboxyfullerene (5 wt%) membrane had the optimal transport properties in pervaporation dehydrationof isopropanol (12–100 wt% water) at 22 °C: permeation flux of 24–1633 g/(m2 h), 99.99–98.3 wt% waterin permeate.",

keywords = "Composite, Fullerene derivatives, Membrane, Pervaporation dehydration, Polymer blend, Sustainability",

author = "Mariia Dmitrenko and Anna Kuzminova and Andrey Zolotarev and Vladislav Liamin and Denis Markelov and Семёнов, {Константин Николаевич} and Tatiana Plisko and Alexandr Bildyukevich and Anastasia Penkova",

note = "Publisher Copyright: {\textcopyright} 2021, The Author(s), under exclusive licence to The Materials Research Society.",

year = "2021",

month = nov,

day = "30",

doi = "10.1557/s43578-021-00432-x",

language = "English",

journal = "Journal of Materials Research",

issn = "0884-2914",

publisher = "Cambridge University Press",

}

RIS

TY - JOUR

T1 - Novel pervaporation membranes based on hydroxyethyl cellulose/polyvinyl alcohol modified with fullerene derivatives for enhanced isopropanol dehydration

AU - Dmitrenko, Mariia

AU - Kuzminova, Anna

AU - Zolotarev, Andrey

AU - Liamin, Vladislav

AU - Markelov, Denis

AU - Семёнов, Константин Николаевич

AU - Plisko, Tatiana

AU - Bildyukevich, Alexandr

AU - Penkova, Anastasia

PY - 2021/11/30

Y1 - 2021/11/30

N2 - The rapid implementation of membrane processes in the industry requires novel membrane materials.One of the promising ways to obtain a membrane material with improved properties is to combinethe advantages of a polymer and a modifier (in particular, carbon nanoparticles). In the present work,novel pervaporation membranes based on hydroxyethyl cellulose (HEC)/polyvinyl alcohol (PVA)blend and HEC/PVA/fullerene derivative (polyhydroxylated fullerene, carboxyfullerene, and fullerenederivative with l-arginine) composites were developed for dehydration. The membrane compositionand the cross-linking with maleic acid were optimized. The membranes were studied by Fouriertransforminfrared spectroscopy, scanning electron and atomic force microscopies, thermogravimetricanalysis, contact angle and swelling measurements. Transport properties of the membranes werestudied in the pervaporation dehydration of isopropanol. The cross-linked dense HEC/PVA(30/70 wt%)/carboxyfullerene (5 wt%) membrane had the optimal transport properties in pervaporation dehydrationof isopropanol (12–100 wt% water) at 22 °C: permeation flux of 24–1633 g/(m2 h), 99.99–98.3 wt% waterin permeate.

AB - The rapid implementation of membrane processes in the industry requires novel membrane materials.One of the promising ways to obtain a membrane material with improved properties is to combinethe advantages of a polymer and a modifier (in particular, carbon nanoparticles). In the present work,novel pervaporation membranes based on hydroxyethyl cellulose (HEC)/polyvinyl alcohol (PVA)blend and HEC/PVA/fullerene derivative (polyhydroxylated fullerene, carboxyfullerene, and fullerenederivative with l-arginine) composites were developed for dehydration. The membrane compositionand the cross-linking with maleic acid were optimized. The membranes were studied by Fouriertransforminfrared spectroscopy, scanning electron and atomic force microscopies, thermogravimetricanalysis, contact angle and swelling measurements. Transport properties of the membranes werestudied in the pervaporation dehydration of isopropanol. The cross-linked dense HEC/PVA(30/70 wt%)/carboxyfullerene (5 wt%) membrane had the optimal transport properties in pervaporation dehydrationof isopropanol (12–100 wt% water) at 22 °C: permeation flux of 24–1633 g/(m2 h), 99.99–98.3 wt% waterin permeate.

KW - Composite

KW - Fullerene derivatives

KW - Membrane

KW - Pervaporation dehydration

KW - Polymer blend

KW - Sustainability

UR - http://www.scopus.com/inward/record.url?scp=85120316480&partnerID=8YFLogxK

U2 - 10.1557/s43578-021-00432-x

DO - 10.1557/s43578-021-00432-x

M3 - Article

JO - Journal of Materials Research

JF - Journal of Materials Research

SN - 0884-2914

ER -

ID: 88599248