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Novel Non-Centrosymmetric NdSr4O(BO3)3 Borate and Nd(Ca1−xSrx)4O(BO3)3 Solid Solutions: Preparation, Crystal Structures, Thermal Expansion and Optical Properties. / Bubnova, Rimma; Yukhno, Valentina; Yurev, Artem; Povolotskiy, Alexey; Krzhizhanovskaya, Maria; Volkov, Sergey; Ugolkov, Valery; Filatov, Stanislav.

In: Crystals, Vol. 13, No. 9, 1395, 19.09.2023.

Research output: Contribution to journal › Article › peer-review

Harvard

Bubnova, R, Yukhno, V, Yurev, A, Povolotskiy, A, Krzhizhanovskaya, M, Volkov, S, Ugolkov, V & Filatov, S 2023, 'Novel Non-Centrosymmetric NdSr4O(BO3)3 Borate and Nd(Ca1−xSrx)4O(BO3)3 Solid Solutions: Preparation, Crystal Structures, Thermal Expansion and Optical Properties', Crystals, vol. 13, no. 9, 1395. https://doi.org/10.3390/cryst13091395

APA

Bubnova, R., Yukhno, V., Yurev, A., Povolotskiy, A., Krzhizhanovskaya, M., Volkov, S., Ugolkov, V., & Filatov, S. (2023). Novel Non-Centrosymmetric NdSr4O(BO3)3 Borate and Nd(Ca1−xSrx)4O(BO3)3 Solid Solutions: Preparation, Crystal Structures, Thermal Expansion and Optical Properties. Crystals, 13(9), [1395]. https://doi.org/10.3390/cryst13091395

Vancouver

Bubnova R, Yukhno V, Yurev A, Povolotskiy A, Krzhizhanovskaya M, Volkov S et al. Novel Non-Centrosymmetric NdSr4O(BO3)3 Borate and Nd(Ca1−xSrx)4O(BO3)3 Solid Solutions: Preparation, Crystal Structures, Thermal Expansion and Optical Properties. Crystals. 2023 Sep 19;13(9). 1395. https://doi.org/10.3390/cryst13091395

Author

Bubnova, Rimma ; Yukhno, Valentina ; Yurev, Artem ; Povolotskiy, Alexey ; Krzhizhanovskaya, Maria ; Volkov, Sergey ; Ugolkov, Valery ; Filatov, Stanislav. / Novel Non-Centrosymmetric NdSr4O(BO3)3 Borate and Nd(Ca1−xSrx)4O(BO3)3 Solid Solutions: Preparation, Crystal Structures, Thermal Expansion and Optical Properties. In: Crystals. 2023 ; Vol. 13, No. 9.

BibTeX

@article{33c517a935654390bc969523879379e5,
title = "Novel Non-Centrosymmetric NdSr4O(BO3)3 Borate and Nd(Ca1−xSrx)4O(BO3)3 Solid Solutions: Preparation, Crystal Structures, Thermal Expansion and Optical Properties",
abstract = "A novel non-centrosymmetric NdSr4O(BO3)3 borate and solid solutions of Nd(Ca1−xSrx)4O(BO3)3 (x = 0.0, 0.1, 0.2, 0.3, 0.4, 0.5, 0.7, 1.0) were synthesized by solid-state reactions as well as crystallization from a melt. The crystal structures of the Nd(Ca1−xSrx)4O(BO3)3 solid solutions with x = 0.2, 0.5 and 1.0 were determined from single crystal X-ray diffraction data and refined in the monoclinic space group Cm to Robs = 0.028, 0.034 and 0.028, respectively. The thermal expansion of the samples with x = 0, 0.2 and 0.5 was investigated using powder high-temperature X-ray diffraction in the temperature range of 25–1000 °C. A similarity of the thermal and compositional (Ca-Sr substitution) deformations of Nd(Ca1−xSrx)4O(BO3)3 solid solutions is revealed: Heating of Nd(Ca0.5Sr0.5)4O(BO3)3 by 1 °C leads to the same deformations of the crystal structure as increasing the amount of Sr atoms in Nd(Ca0.5Sr0.5)4O(BO3)3 by 0.26 at% Sr. The SHG signal of the series of Nd(Ca1−xSrx)4O(BO3)3 solid solutions has a maximum at approximately x = 0.2.",
author = "Rimma Bubnova and Valentina Yukhno and Artem Yurev and Alexey Povolotskiy and Maria Krzhizhanovskaya and Sergey Volkov and Valery Ugolkov and Stanislav Filatov",
year = "2023",
month = sep,
day = "19",
doi = "10.3390/cryst13091395",
language = "English",
volume = "13",
journal = "Crystals",
issn = "2073-4352",
publisher = "MDPI AG",
number = "9",

}

RIS

TY - JOUR

T1 - Novel Non-Centrosymmetric NdSr4O(BO3)3 Borate and Nd(Ca1−xSrx)4O(BO3)3 Solid Solutions: Preparation, Crystal Structures, Thermal Expansion and Optical Properties

AU - Bubnova, Rimma

AU - Yukhno, Valentina

AU - Yurev, Artem

AU - Povolotskiy, Alexey

AU - Krzhizhanovskaya, Maria

AU - Volkov, Sergey

AU - Ugolkov, Valery

AU - Filatov, Stanislav

PY - 2023/9/19

Y1 - 2023/9/19

N2 - A novel non-centrosymmetric NdSr4O(BO3)3 borate and solid solutions of Nd(Ca1−xSrx)4O(BO3)3 (x = 0.0, 0.1, 0.2, 0.3, 0.4, 0.5, 0.7, 1.0) were synthesized by solid-state reactions as well as crystallization from a melt. The crystal structures of the Nd(Ca1−xSrx)4O(BO3)3 solid solutions with x = 0.2, 0.5 and 1.0 were determined from single crystal X-ray diffraction data and refined in the monoclinic space group Cm to Robs = 0.028, 0.034 and 0.028, respectively. The thermal expansion of the samples with x = 0, 0.2 and 0.5 was investigated using powder high-temperature X-ray diffraction in the temperature range of 25–1000 °C. A similarity of the thermal and compositional (Ca-Sr substitution) deformations of Nd(Ca1−xSrx)4O(BO3)3 solid solutions is revealed: Heating of Nd(Ca0.5Sr0.5)4O(BO3)3 by 1 °C leads to the same deformations of the crystal structure as increasing the amount of Sr atoms in Nd(Ca0.5Sr0.5)4O(BO3)3 by 0.26 at% Sr. The SHG signal of the series of Nd(Ca1−xSrx)4O(BO3)3 solid solutions has a maximum at approximately x = 0.2.

AB - A novel non-centrosymmetric NdSr4O(BO3)3 borate and solid solutions of Nd(Ca1−xSrx)4O(BO3)3 (x = 0.0, 0.1, 0.2, 0.3, 0.4, 0.5, 0.7, 1.0) were synthesized by solid-state reactions as well as crystallization from a melt. The crystal structures of the Nd(Ca1−xSrx)4O(BO3)3 solid solutions with x = 0.2, 0.5 and 1.0 were determined from single crystal X-ray diffraction data and refined in the monoclinic space group Cm to Robs = 0.028, 0.034 and 0.028, respectively. The thermal expansion of the samples with x = 0, 0.2 and 0.5 was investigated using powder high-temperature X-ray diffraction in the temperature range of 25–1000 °C. A similarity of the thermal and compositional (Ca-Sr substitution) deformations of Nd(Ca1−xSrx)4O(BO3)3 solid solutions is revealed: Heating of Nd(Ca0.5Sr0.5)4O(BO3)3 by 1 °C leads to the same deformations of the crystal structure as increasing the amount of Sr atoms in Nd(Ca0.5Sr0.5)4O(BO3)3 by 0.26 at% Sr. The SHG signal of the series of Nd(Ca1−xSrx)4O(BO3)3 solid solutions has a maximum at approximately x = 0.2.

UR - https://www.mendeley.com/catalogue/2bc849e0-a2bc-3215-8f93-32fb0cce4f6a/

U2 - 10.3390/cryst13091395

DO - 10.3390/cryst13091395

M3 - Article

VL - 13

JO - Crystals

JF - Crystals

SN - 2073-4352

IS - 9

M1 - 1395

ER -

ID: 111863119