Novel chromeno[2,3-c]pyrroles synthesized via intramolecular rhodium(ii) carbene trapping

DOI

https://doi.org/10.1016/j.mencom.2022.05.030
Final published version

Evgeny Chupakhin
Grigory Kantin
Dmitry Dar'in
Mikhail Krasavin

Rhodium(ii) carbenes generated from (E)-3-diazo-4-(2-hydroxybenzylidene)-1-phenylpyrrolidine-2,5-dione under- went a facile transformation into novel succinimide-fused 2H-chromenes, chromeno[2,3-c]pyrrole-1,3(2H,3aH)-diones. The process presumably involves an intramolecular O-H insertion reaction.

Original language	English
Pages (from-to)	382-383
Number of pages	2
Journal	Mendeleev Communications
Volume	32
Issue number	3
DOIs	https://doi.org/10.1016/j.mencom.2022.05.030
State	Published - 1 May 2022

Scopus subject areas

Chemistry(all)

Research areas

2H-chromenes, 5-diones, chromeno[2,3-c]pyrroles, intramolecular O-H insertion, pyrrolidine-2, rhodium(u) complexes, α-diazo carbonyl compounds

ID: 96210554