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Novel cesium cerium (IV) iodate Cs2Ce(IO3)6: hydrothermal synthesis, crystal structure and thermal stability. / Grigorieva, Oksana; Shvanskaya, Larisa Victorovna; Shatalova, Tatiana; Zolotarev, Andrey A.; Berdonosov, Peter S; Dolgikh, Valery.

In: Crystengcomm, 02.09.2024.

Research output: Contribution to journal › Article › peer-review

Harvard

Grigorieva, O, Shvanskaya, LV, Shatalova, T, Zolotarev, AA, Berdonosov, PS & Dolgikh, V 2024, 'Novel cesium cerium (IV) iodate Cs2Ce(IO3)6: hydrothermal synthesis, crystal structure and thermal stability', Crystengcomm. https://doi.org/10.1039/d4ce00722k

APA

Grigorieva, O., Shvanskaya, L. V., Shatalova, T., Zolotarev, A. A., Berdonosov, P. S., & Dolgikh, V. (2024). Novel cesium cerium (IV) iodate Cs2Ce(IO3)6: hydrothermal synthesis, crystal structure and thermal stability. Crystengcomm. https://doi.org/10.1039/d4ce00722k

Vancouver

Grigorieva O, Shvanskaya LV, Shatalova T, Zolotarev AA, Berdonosov PS, Dolgikh V. Novel cesium cerium (IV) iodate Cs2Ce(IO3)6: hydrothermal synthesis, crystal structure and thermal stability. Crystengcomm. 2024 Sep 2. https://doi.org/10.1039/d4ce00722k

Author

Grigorieva, Oksana ; Shvanskaya, Larisa Victorovna ; Shatalova, Tatiana ; Zolotarev, Andrey A. ; Berdonosov, Peter S ; Dolgikh, Valery. / Novel cesium cerium (IV) iodate Cs2Ce(IO3)6: hydrothermal synthesis, crystal structure and thermal stability. In: Crystengcomm. 2024.

BibTeX

@article{ccb34b7c8e9640cea1640a4ec4bd50ae,
title = "Novel cesium cerium (IV) iodate Cs2Ce(IO3)6: hydrothermal synthesis, crystal structure and thermal stability",
abstract = " New cesium cerium (IV) iodate Cs 2 Ce(IO 3 ) 6 was successfully prepared by hydrothermal technique from starting reagents CsF, CeO 2 ,H 5 IO 6 and HIO 3 at 230°C. Cs 2 Ce(IO 3 ) 6 were analyzed by single crystal and powder XRD,... New cesium cerium (IV) iodate Cs 2 Ce(IO 3 ) 6 was successfully prepared by hydrothermal technique from starting reagents CsF, CeO 2 ,H 5 IO 6 and HIO 3 at 230°C. Cs 2 Ce(IO 3 ) 6 were analyzed by single crystal and powder XRD, EDX, IR spectroscopy and thermal analysis. New compound crystallizes in the monoclinic space group C 2/ c with a = 14.0652 (3) {\AA}, b = 8.1890 (2) {\AA}, c = 17.7211 (4) {\AA}, β = 103.601 (2) o , V = 1983.99(8) {\AA} 3 , Z = 4. Crystal structure of Cs 2 Ce(IO 3 ) 6 consists from CeO 8 square antiprisms which sharing their apexes and edges with trigonal pyramidal IO 3 — groups to form layers [Ce(IO 3 ) 6 ] 2 — parallel to ab plane. These layers are furher stabilised by 12-vertex polyhedra, CsO 12 , situated in their voids. The IR spectrum of Cs 2 Ce(IO 3 ) 6 possess iodate groups bands. According to DTA analysis cesium cerium (IV) iodate shows high thermal stability on air up to 414°C. ",
author = "Oksana Grigorieva and Shvanskaya, {Larisa Victorovna} and Tatiana Shatalova and Zolotarev, {Andrey A.} and Berdonosov, {Peter S} and Valery Dolgikh",
year = "2024",
month = sep,
day = "2",
doi = "10.1039/d4ce00722k",
language = "English",
journal = "CrystEngComm",
issn = "1466-8033",
publisher = "Royal Society of Chemistry",

}

RIS

TY - JOUR

T1 - Novel cesium cerium (IV) iodate Cs2Ce(IO3)6: hydrothermal synthesis, crystal structure and thermal stability

AU - Grigorieva, Oksana

AU - Shvanskaya, Larisa Victorovna

AU - Shatalova, Tatiana

AU - Zolotarev, Andrey A.

AU - Berdonosov, Peter S

AU - Dolgikh, Valery

PY - 2024/9/2

Y1 - 2024/9/2

N2 - New cesium cerium (IV) iodate Cs 2 Ce(IO 3 ) 6 was successfully prepared by hydrothermal technique from starting reagents CsF, CeO 2 ,H 5 IO 6 and HIO 3 at 230°C. Cs 2 Ce(IO 3 ) 6 were analyzed by single crystal and powder XRD,... New cesium cerium (IV) iodate Cs 2 Ce(IO 3 ) 6 was successfully prepared by hydrothermal technique from starting reagents CsF, CeO 2 ,H 5 IO 6 and HIO 3 at 230°C. Cs 2 Ce(IO 3 ) 6 were analyzed by single crystal and powder XRD, EDX, IR spectroscopy and thermal analysis. New compound crystallizes in the monoclinic space group C 2/ c with a = 14.0652 (3) Å, b = 8.1890 (2) Å, c = 17.7211 (4) Å, β = 103.601 (2) o , V = 1983.99(8) Å 3 , Z = 4. Crystal structure of Cs 2 Ce(IO 3 ) 6 consists from CeO 8 square antiprisms which sharing their apexes and edges with trigonal pyramidal IO 3 — groups to form layers [Ce(IO 3 ) 6 ] 2 — parallel to ab plane. These layers are furher stabilised by 12-vertex polyhedra, CsO 12 , situated in their voids. The IR spectrum of Cs 2 Ce(IO 3 ) 6 possess iodate groups bands. According to DTA analysis cesium cerium (IV) iodate shows high thermal stability on air up to 414°C.

AB - New cesium cerium (IV) iodate Cs 2 Ce(IO 3 ) 6 was successfully prepared by hydrothermal technique from starting reagents CsF, CeO 2 ,H 5 IO 6 and HIO 3 at 230°C. Cs 2 Ce(IO 3 ) 6 were analyzed by single crystal and powder XRD,... New cesium cerium (IV) iodate Cs 2 Ce(IO 3 ) 6 was successfully prepared by hydrothermal technique from starting reagents CsF, CeO 2 ,H 5 IO 6 and HIO 3 at 230°C. Cs 2 Ce(IO 3 ) 6 were analyzed by single crystal and powder XRD, EDX, IR spectroscopy and thermal analysis. New compound crystallizes in the monoclinic space group C 2/ c with a = 14.0652 (3) Å, b = 8.1890 (2) Å, c = 17.7211 (4) Å, β = 103.601 (2) o , V = 1983.99(8) Å 3 , Z = 4. Crystal structure of Cs 2 Ce(IO 3 ) 6 consists from CeO 8 square antiprisms which sharing their apexes and edges with trigonal pyramidal IO 3 — groups to form layers [Ce(IO 3 ) 6 ] 2 — parallel to ab plane. These layers are furher stabilised by 12-vertex polyhedra, CsO 12 , situated in their voids. The IR spectrum of Cs 2 Ce(IO 3 ) 6 possess iodate groups bands. According to DTA analysis cesium cerium (IV) iodate shows high thermal stability on air up to 414°C.

UR - https://www.mendeley.com/catalogue/34b6d2e8-73b4-3b77-b8d2-77cf97142747/

U2 - 10.1039/d4ce00722k

DO - 10.1039/d4ce00722k

M3 - Article

JO - CrystEngComm

JF - CrystEngComm

SN - 1466-8033

ER -

ID: 124317737