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Non-adiabatic transitions from the I2(E) induced by the transition dipole moment of I2(E-D) and the electric dipole moment of collision partners. / Akopyan, M. E.; Lukashov, S. S.; Maslennikova, Yu D.; Poretsky, S. A.; Pravilov, A. M.; Torgashkova, A. S.

In: Chemical Physics Letters, Vol. 458, No. 1-3, 2008, p. 29-34.

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Akopyan, M. E. ; Lukashov, S. S. ; Maslennikova, Yu D. ; Poretsky, S. A. ; Pravilov, A. M. ; Torgashkova, A. S. / Non-adiabatic transitions from the I2(E) induced by the transition dipole moment of I2(E-D) and the electric dipole moment of collision partners. In: Chemical Physics Letters. 2008 ; Vol. 458, No. 1-3. pp. 29-34.

BibTeX

@article{d9e65a5aeee44e97b2f98736eb1b59eb,
title = "Non-adiabatic transitions from the I2(E) induced by the transition dipole moment of I2(E-D) and the electric dipole moment of collision partners",
abstract = "Optical-optical double resonance spectroscopy is used to obtain total rate constants, electronic branching ratios, and vibrational product state distributions for non-adiabatic transitions among the first-tier ion-pair states of the I2 molecule excited to the E 0g+, vE = 8, 13, 19;JE ≈ 55 rovibronic levels in collisions with M = CD3I and CH3COCH3. It is shown that I2 (E over(→, M) D) near-resonant transitions are caused by the interaction between the transition dipole moment of I2(E-D) and the permanent electric dipole moment of M. The I2(D) state vibrational levels populated due to polarization interaction accompanied by quasi-resonance excitation of the collision partner are also observed.",
author = "Akopyan, {M. E.} and Lukashov, {S. S.} and Maslennikova, {Yu D.} and Poretsky, {S. A.} and Pravilov, {A. M.} and Torgashkova, {A. S.}",
year = "2008",
doi = "10.1016/j.cplett.2008.04.062",
language = "English",
volume = "458",
pages = "29--34",
journal = "Chemical Physics Letters",
issn = "0009-2614",
publisher = "Elsevier",
number = "1-3",

}

RIS

TY - JOUR

T1 - Non-adiabatic transitions from the I2(E) induced by the transition dipole moment of I2(E-D) and the electric dipole moment of collision partners

AU - Akopyan, M. E.

AU - Lukashov, S. S.

AU - Maslennikova, Yu D.

AU - Poretsky, S. A.

AU - Pravilov, A. M.

AU - Torgashkova, A. S.

PY - 2008

Y1 - 2008

N2 - Optical-optical double resonance spectroscopy is used to obtain total rate constants, electronic branching ratios, and vibrational product state distributions for non-adiabatic transitions among the first-tier ion-pair states of the I2 molecule excited to the E 0g+, vE = 8, 13, 19;JE ≈ 55 rovibronic levels in collisions with M = CD3I and CH3COCH3. It is shown that I2 (E over(→, M) D) near-resonant transitions are caused by the interaction between the transition dipole moment of I2(E-D) and the permanent electric dipole moment of M. The I2(D) state vibrational levels populated due to polarization interaction accompanied by quasi-resonance excitation of the collision partner are also observed.

AB - Optical-optical double resonance spectroscopy is used to obtain total rate constants, electronic branching ratios, and vibrational product state distributions for non-adiabatic transitions among the first-tier ion-pair states of the I2 molecule excited to the E 0g+, vE = 8, 13, 19;JE ≈ 55 rovibronic levels in collisions with M = CD3I and CH3COCH3. It is shown that I2 (E over(→, M) D) near-resonant transitions are caused by the interaction between the transition dipole moment of I2(E-D) and the permanent electric dipole moment of M. The I2(D) state vibrational levels populated due to polarization interaction accompanied by quasi-resonance excitation of the collision partner are also observed.

UR - http://www.scopus.com/inward/record.url?scp=44449155856&partnerID=8YFLogxK

U2 - 10.1016/j.cplett.2008.04.062

DO - 10.1016/j.cplett.2008.04.062

M3 - Article

AN - SCOPUS:44449155856

VL - 458

SP - 29

EP - 34

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

IS - 1-3

ER -

ID: 87819679