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NMR and dielectric studies of ferroelectric nanocomposites with KDP. / Uskova, N. I.; Podorozhkin, D. Yu; Charnaya, E. V.; Baryshnikov, S. V.; Milinskiy, A. Yu; Nefedov, D. Yu; Bugaev, A. S.; Lee, M. K.; Chang, L. J.

In: Ferroelectrics, Vol. 514, No. 1, 04.07.2017, p. 50-60.

Research output: Contribution to journal › Article › peer-review

Harvard

Uskova, NI, Podorozhkin, DY, Charnaya, EV, Baryshnikov, SV, Milinskiy, AY, Nefedov, DY, Bugaev, AS, Lee, MK & Chang, LJ 2017, 'NMR and dielectric studies of ferroelectric nanocomposites with KDP', Ferroelectrics, vol. 514, no. 1, pp. 50-60. https://doi.org/10.1080/00150193.2017.1357980

APA

Uskova, N. I., Podorozhkin, D. Y., Charnaya, E. V., Baryshnikov, S. V., Milinskiy, A. Y., Nefedov, D. Y., Bugaev, A. S., Lee, M. K., & Chang, L. J. (2017). NMR and dielectric studies of ferroelectric nanocomposites with KDP. Ferroelectrics, 514(1), 50-60. https://doi.org/10.1080/00150193.2017.1357980

Vancouver

Uskova NI, Podorozhkin DY, Charnaya EV, Baryshnikov SV, Milinskiy AY, Nefedov DY et al. NMR and dielectric studies of ferroelectric nanocomposites with KDP. Ferroelectrics. 2017 Jul 4;514(1):50-60. https://doi.org/10.1080/00150193.2017.1357980

Author

Uskova, N. I. ; Podorozhkin, D. Yu ; Charnaya, E. V. ; Baryshnikov, S. V. ; Milinskiy, A. Yu ; Nefedov, D. Yu ; Bugaev, A. S. ; Lee, M. K. ; Chang, L. J. / NMR and dielectric studies of ferroelectric nanocomposites with KDP. In: Ferroelectrics. 2017 ; Vol. 514, No. 1. pp. 50-60.

BibTeX

@article{412d34144c0245b08ecaccbf0635a6cd,
title = "NMR and dielectric studies of ferroelectric nanocomposites with KDP",
abstract = "Ferroelectricity was studied for the nanocomposites consisted of KDP loaded MCM-41 molecular sieves and porous glass with pore sizes 3.8 and 7 nm, respectively. Studies were carried out by NMR and dielectric techniques. The ferroelectric phase transition in the MCM-41 nanocomposite was shifted by 0.4 K to high temperature, while the ferroelectric transition in the porous glass nanocomposite was not found. The different ferroelectric behavior of the MCM-41 and porous glass nanocomposites with KDP was ascribed to the impact of the interparticle coupling. The 31P MAS NMR measurements showed that the isotropic chemical shift at room temperature was the same for nanocomposites and bulk KDP. This result confirmed the similarity of the crystalline structure of confined particles and bulk KDP. The chemical shift tensor parameters below the ferroelectric phase transition were calculated for bulk KDP and KDP confined to MCM-41 molecular sieves.",
keywords = "Ferroelectric nanocomposite, KDP, NMR, permittivity, phase transition",
author = "Uskova, {N. I.} and Podorozhkin, {D. Yu} and Charnaya, {E. V.} and Baryshnikov, {S. V.} and Milinskiy, {A. Yu} and Nefedov, {D. Yu} and Bugaev, {A. S.} and Lee, {M. K.} and Chang, {L. J.}",
year = "2017",
month = jul,
day = "4",
doi = "10.1080/00150193.2017.1357980",
language = "English",
volume = "514",
pages = "50--60",
journal = "Ferroelectrics",
issn = "0015-0193",
publisher = "Taylor & Francis",
number = "1",

}

RIS

TY - JOUR

T1 - NMR and dielectric studies of ferroelectric nanocomposites with KDP

AU - Uskova, N. I.

AU - Podorozhkin, D. Yu

AU - Charnaya, E. V.

AU - Baryshnikov, S. V.

AU - Milinskiy, A. Yu

AU - Nefedov, D. Yu

AU - Bugaev, A. S.

AU - Lee, M. K.

AU - Chang, L. J.

PY - 2017/7/4

Y1 - 2017/7/4

N2 - Ferroelectricity was studied for the nanocomposites consisted of KDP loaded MCM-41 molecular sieves and porous glass with pore sizes 3.8 and 7 nm, respectively. Studies were carried out by NMR and dielectric techniques. The ferroelectric phase transition in the MCM-41 nanocomposite was shifted by 0.4 K to high temperature, while the ferroelectric transition in the porous glass nanocomposite was not found. The different ferroelectric behavior of the MCM-41 and porous glass nanocomposites with KDP was ascribed to the impact of the interparticle coupling. The 31P MAS NMR measurements showed that the isotropic chemical shift at room temperature was the same for nanocomposites and bulk KDP. This result confirmed the similarity of the crystalline structure of confined particles and bulk KDP. The chemical shift tensor parameters below the ferroelectric phase transition were calculated for bulk KDP and KDP confined to MCM-41 molecular sieves.

AB - Ferroelectricity was studied for the nanocomposites consisted of KDP loaded MCM-41 molecular sieves and porous glass with pore sizes 3.8 and 7 nm, respectively. Studies were carried out by NMR and dielectric techniques. The ferroelectric phase transition in the MCM-41 nanocomposite was shifted by 0.4 K to high temperature, while the ferroelectric transition in the porous glass nanocomposite was not found. The different ferroelectric behavior of the MCM-41 and porous glass nanocomposites with KDP was ascribed to the impact of the interparticle coupling. The 31P MAS NMR measurements showed that the isotropic chemical shift at room temperature was the same for nanocomposites and bulk KDP. This result confirmed the similarity of the crystalline structure of confined particles and bulk KDP. The chemical shift tensor parameters below the ferroelectric phase transition were calculated for bulk KDP and KDP confined to MCM-41 molecular sieves.

KW - Ferroelectric nanocomposite

KW - KDP

KW - NMR

KW - permittivity

KW - phase transition

UR - http://www.scopus.com/inward/record.url?scp=85029700250&partnerID=8YFLogxK

U2 - 10.1080/00150193.2017.1357980

DO - 10.1080/00150193.2017.1357980

M3 - Article

AN - SCOPUS:85029700250

VL - 514

SP - 50

EP - 60

JO - Ferroelectrics

JF - Ferroelectrics

SN - 0015-0193

IS - 1

ER -

ID: 36148643