Standard

Nitrogen inserting in fluorinated graphene via annealing of acetonitrile intercalated graphite fluoride. / Fedoseeva, Yu. V.; Okotrub, A. V.; Asanov, I. P.; Pinakov, D. V.; Chekhova, G. N.; Tur, V. A.; Plyusnin, P. E.; Vyalikh, D. V.; Bulusheva, L. G.

In: Physica Status Solidi (B): Basic Research, Vol. 251, No. 12, 12.2014, p. 2530-2535.

Research output: Contribution to journal › Article › peer-review

Harvard

Fedoseeva, YV, Okotrub, AV, Asanov, IP, Pinakov, DV, Chekhova, GN, Tur, VA, Plyusnin, PE, Vyalikh, DV & Bulusheva, LG 2014, 'Nitrogen inserting in fluorinated graphene via annealing of acetonitrile intercalated graphite fluoride', Physica Status Solidi (B): Basic Research, vol. 251, no. 12, pp. 2530-2535. https://doi.org/10.1002/pssb.201451281

APA

Fedoseeva, Y. V., Okotrub, A. V., Asanov, I. P., Pinakov, D. V., Chekhova, G. N., Tur, V. A., Plyusnin, P. E., Vyalikh, D. V., & Bulusheva, L. G. (2014). Nitrogen inserting in fluorinated graphene via annealing of acetonitrile intercalated graphite fluoride. Physica Status Solidi (B): Basic Research, 251(12), 2530-2535. https://doi.org/10.1002/pssb.201451281

Vancouver

Fedoseeva YV, Okotrub AV, Asanov IP, Pinakov DV, Chekhova GN, Tur VA et al. Nitrogen inserting in fluorinated graphene via annealing of acetonitrile intercalated graphite fluoride. Physica Status Solidi (B): Basic Research. 2014 Dec;251(12):2530-2535. https://doi.org/10.1002/pssb.201451281

Author

Fedoseeva, Yu. V. ; Okotrub, A. V. ; Asanov, I. P. ; Pinakov, D. V. ; Chekhova, G. N. ; Tur, V. A. ; Plyusnin, P. E. ; Vyalikh, D. V. ; Bulusheva, L. G. / Nitrogen inserting in fluorinated graphene via annealing of acetonitrile intercalated graphite fluoride. In: Physica Status Solidi (B): Basic Research. 2014 ; Vol. 251, No. 12. pp. 2530-2535.

BibTeX

@article{a8d6488ed93646b9afb9774cc4a913b6,
title = "Nitrogen inserting in fluorinated graphene via annealing of acetonitrile intercalated graphite fluoride",
abstract = "Fluorinated graphite intercalation compounds (FGICs) with acetonitrile C2Fx-yCH3CN (x = 0.92, 0.69, and 0.49) have been synthesized using a gaseous mixture of BrF3 and Br-2 at room temperature and subsequent replacement of the reaction medium components on acetonitrile by isopiestic method. The change in functional composition and electronic structure of FGICs under annealing at 250-260 degrees C was studied by infrared, X-ray photoelectron, and near-edge X-ray absorption fine structure spectroscopy (NEXAFS) methods. Analysis of the data revealed interaction of acetonitrile with a C2Fx matrix. The X-ray spectra detected formation of new nitrogen species attributed to two-coordinated and mono hydrogenated three-coordinated atoms. Mechanism of nitrogen incorporation in the fluorinated graphene layers was proposed.[GRAPHICS]Schematic structure of graphite fluoride C2Fx intercalated with acetonitrile and NEXAFS N K-edge spectrum of C2F0.69 center dot(0).137CH(3)CN before and after annealing at 250 degrees C. (C) 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim",
keywords = "acetonitrile, fluorinated graphite intercalation compounds, heating, NEXAFS, XPS, ROOM-TEMPERATURE, ELECTRONIC-STRUCTURE, C2F, SPECTROSCOPY, CARBON, DECOMPOSITION, PERFORMANCE, EVOLUTION, XANES, MODEL",
author = "Fedoseeva, {Yu. V.} and Okotrub, {A. V.} and Asanov, {I. P.} and Pinakov, {D. V.} and Chekhova, {G. N.} and Tur, {V. A.} and Plyusnin, {P. E.} and Vyalikh, {D. V.} and Bulusheva, {L. G.}",
year = "2014",
month = dec,
doi = "10.1002/pssb.201451281",
language = "Английский",
volume = "251",
pages = "2530--2535",
journal = "Physica Status Solidi (B): Basic Research",
issn = "0370-1972",
publisher = "Wiley-Blackwell",
number = "12",

}

RIS

TY - JOUR

T1 - Nitrogen inserting in fluorinated graphene via annealing of acetonitrile intercalated graphite fluoride

AU - Fedoseeva, Yu. V.

AU - Okotrub, A. V.

AU - Asanov, I. P.

AU - Pinakov, D. V.

AU - Chekhova, G. N.

AU - Tur, V. A.

AU - Plyusnin, P. E.

AU - Vyalikh, D. V.

AU - Bulusheva, L. G.

PY - 2014/12

Y1 - 2014/12

N2 - Fluorinated graphite intercalation compounds (FGICs) with acetonitrile C2Fx-yCH3CN (x = 0.92, 0.69, and 0.49) have been synthesized using a gaseous mixture of BrF3 and Br-2 at room temperature and subsequent replacement of the reaction medium components on acetonitrile by isopiestic method. The change in functional composition and electronic structure of FGICs under annealing at 250-260 degrees C was studied by infrared, X-ray photoelectron, and near-edge X-ray absorption fine structure spectroscopy (NEXAFS) methods. Analysis of the data revealed interaction of acetonitrile with a C2Fx matrix. The X-ray spectra detected formation of new nitrogen species attributed to two-coordinated and mono hydrogenated three-coordinated atoms. Mechanism of nitrogen incorporation in the fluorinated graphene layers was proposed.[GRAPHICS]Schematic structure of graphite fluoride C2Fx intercalated with acetonitrile and NEXAFS N K-edge spectrum of C2F0.69 center dot(0).137CH(3)CN before and after annealing at 250 degrees C. (C) 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

AB - Fluorinated graphite intercalation compounds (FGICs) with acetonitrile C2Fx-yCH3CN (x = 0.92, 0.69, and 0.49) have been synthesized using a gaseous mixture of BrF3 and Br-2 at room temperature and subsequent replacement of the reaction medium components on acetonitrile by isopiestic method. The change in functional composition and electronic structure of FGICs under annealing at 250-260 degrees C was studied by infrared, X-ray photoelectron, and near-edge X-ray absorption fine structure spectroscopy (NEXAFS) methods. Analysis of the data revealed interaction of acetonitrile with a C2Fx matrix. The X-ray spectra detected formation of new nitrogen species attributed to two-coordinated and mono hydrogenated three-coordinated atoms. Mechanism of nitrogen incorporation in the fluorinated graphene layers was proposed.[GRAPHICS]Schematic structure of graphite fluoride C2Fx intercalated with acetonitrile and NEXAFS N K-edge spectrum of C2F0.69 center dot(0).137CH(3)CN before and after annealing at 250 degrees C. (C) 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

KW - acetonitrile

KW - fluorinated graphite intercalation compounds

KW - heating

KW - NEXAFS

KW - XPS

KW - ROOM-TEMPERATURE

KW - ELECTRONIC-STRUCTURE

KW - C2F

KW - SPECTROSCOPY

KW - CARBON

KW - DECOMPOSITION

KW - PERFORMANCE

KW - EVOLUTION

KW - XANES

KW - MODEL

U2 - 10.1002/pssb.201451281

DO - 10.1002/pssb.201451281

M3 - статья

VL - 251

SP - 2530

EP - 2535

JO - Physica Status Solidi (B): Basic Research

JF - Physica Status Solidi (B): Basic Research

SN - 0370-1972

IS - 12

ER -

ID: 126348413