Standard

New wide rim phosphomethylated calix[4]arenes in extraction of Americium and Europium. / Klimchuk, O.; Atamas, L.; Miroshnichenko, S.; Kalchenko, V.; Smirnov, I.; Babain, V.; Varnek, A.; Wipff, G.

In: Journal of Inclusion Phenomena, Vol. 49, No. 1-2, 01.06.2004, p. 47-56.

Research output: Contribution to journal › Article › peer-review

Harvard

Klimchuk, O, Atamas, L, Miroshnichenko, S, Kalchenko, V, Smirnov, I, Babain, V, Varnek, A & Wipff, G 2004, 'New wide rim phosphomethylated calix[4]arenes in extraction of Americium and Europium', Journal of Inclusion Phenomena, vol. 49, no. 1-2, pp. 47-56. https://doi.org/10.1023/B:JIPH.0000031112.16272.17

APA

Klimchuk, O., Atamas, L., Miroshnichenko, S., Kalchenko, V., Smirnov, I., Babain, V., Varnek, A., & Wipff, G. (2004). New wide rim phosphomethylated calix[4]arenes in extraction of Americium and Europium. Journal of Inclusion Phenomena, 49(1-2), 47-56. https://doi.org/10.1023/B:JIPH.0000031112.16272.17

Vancouver

Klimchuk O, Atamas L, Miroshnichenko S, Kalchenko V, Smirnov I, Babain V et al. New wide rim phosphomethylated calix[4]arenes in extraction of Americium and Europium. Journal of Inclusion Phenomena. 2004 Jun 1;49(1-2):47-56. https://doi.org/10.1023/B:JIPH.0000031112.16272.17

Author

Klimchuk, O. ; Atamas, L. ; Miroshnichenko, S. ; Kalchenko, V. ; Smirnov, I. ; Babain, V. ; Varnek, A. ; Wipff, G. / New wide rim phosphomethylated calix[4]arenes in extraction of Americium and Europium. In: Journal of Inclusion Phenomena. 2004 ; Vol. 49, No. 1-2. pp. 47-56.

BibTeX

@article{031afc742cc8481db91d51bc0e78dbf0,
title = "New wide rim phosphomethylated calix[4]arenes in extraction of Americium and Europium",
abstract = "A new series of the cone-shaped tetraalkoxycalix[4]arenes substituted at the wide rim with four phosphomethyl groups have been synthesized by the Arbuzov, Michaelis-Becker and Aterthon-Todd reactions of the chloromethyl or phenylhydrophosphinylmethylcalix[4]arenes. Their binding properties towards Eu 3+ and Am 3+ cations were investigated by the liquid-liquid extraction method. Due to the 'calixarene effect' the tetraphosphorylated calixarenes are more effective extractants for the metal cations than their acyclic analogs or some industrial extractants such as trialkylphosphinoxides, carbamoylphosphinoxide, bis-2-diethylhexyl phosphoric acid.",
keywords = "americium, europium, extraction, phosphorylated calix[4]arenes, radioactive wastes",
author = "O. Klimchuk and L. Atamas and S. Miroshnichenko and V. Kalchenko and I. Smirnov and V. Babain and A. Varnek and G. Wipff",
year = "2004",
month = jun,
day = "1",
doi = "10.1023/B:JIPH.0000031112.16272.17",
language = "English",
volume = "49",
pages = "47--56",
journal = "Journal of Inclusion Phenomena and Macrocyclic Chemistry",
issn = "1388-3127",
publisher = "Wolters Kluwer",
number = "1-2",

}

RIS

TY - JOUR

T1 - New wide rim phosphomethylated calix[4]arenes in extraction of Americium and Europium

AU - Klimchuk, O.

AU - Atamas, L.

AU - Miroshnichenko, S.

AU - Kalchenko, V.

AU - Smirnov, I.

AU - Babain, V.

AU - Varnek, A.

AU - Wipff, G.

PY - 2004/6/1

Y1 - 2004/6/1

N2 - A new series of the cone-shaped tetraalkoxycalix[4]arenes substituted at the wide rim with four phosphomethyl groups have been synthesized by the Arbuzov, Michaelis-Becker and Aterthon-Todd reactions of the chloromethyl or phenylhydrophosphinylmethylcalix[4]arenes. Their binding properties towards Eu 3+ and Am 3+ cations were investigated by the liquid-liquid extraction method. Due to the 'calixarene effect' the tetraphosphorylated calixarenes are more effective extractants for the metal cations than their acyclic analogs or some industrial extractants such as trialkylphosphinoxides, carbamoylphosphinoxide, bis-2-diethylhexyl phosphoric acid.

AB - A new series of the cone-shaped tetraalkoxycalix[4]arenes substituted at the wide rim with four phosphomethyl groups have been synthesized by the Arbuzov, Michaelis-Becker and Aterthon-Todd reactions of the chloromethyl or phenylhydrophosphinylmethylcalix[4]arenes. Their binding properties towards Eu 3+ and Am 3+ cations were investigated by the liquid-liquid extraction method. Due to the 'calixarene effect' the tetraphosphorylated calixarenes are more effective extractants for the metal cations than their acyclic analogs or some industrial extractants such as trialkylphosphinoxides, carbamoylphosphinoxide, bis-2-diethylhexyl phosphoric acid.

KW - americium

KW - europium

KW - extraction

KW - phosphorylated calix[4]arenes

KW - radioactive wastes

UR - http://www.scopus.com/inward/record.url?scp=3042756996&partnerID=8YFLogxK

U2 - 10.1023/B:JIPH.0000031112.16272.17

DO - 10.1023/B:JIPH.0000031112.16272.17

M3 - Article

AN - SCOPUS:3042756996

VL - 49

SP - 47

EP - 56

JO - Journal of Inclusion Phenomena and Macrocyclic Chemistry

JF - Journal of Inclusion Phenomena and Macrocyclic Chemistry

SN - 1388-3127

IS - 1-2

ER -

ID: 53580134