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New "turn-off" fluorescence sensors to detect vapors of nitro-explosives on the basis of 4,6-bis[5-(heteroaryl)thiophen-2-yl] substituted 5-(4-tert-butylphenyl)pyrimidines. / Verbitskiy, Egor V.; Baranova, Anna A.; Yakovleva, Yuliya A.; Chuvashov, Roman D.; Khokhlov, Konstantin O.; Dinastiya, Ekaterina M.; Rusinov, Gennady L.; Chupakhin, Oleg N.; Charushin, Valery N.

In: Arkivoc, Vol. 2017, No. 5, 01.01.2017, p. 341-355.

Research output: Contribution to journalArticlepeer-review

Harvard

Verbitskiy, EV, Baranova, AA, Yakovleva, YA, Chuvashov, RD, Khokhlov, KO, Dinastiya, EM, Rusinov, GL, Chupakhin, ON & Charushin, VN 2017, 'New "turn-off" fluorescence sensors to detect vapors of nitro-explosives on the basis of 4,6-bis[5-(heteroaryl)thiophen-2-yl] substituted 5-(4-tert-butylphenyl)pyrimidines', Arkivoc, vol. 2017, no. 5, pp. 341-355. https://doi.org/10.24820/ark.5550190.p010.353

APA

Verbitskiy, E. V., Baranova, A. A., Yakovleva, Y. A., Chuvashov, R. D., Khokhlov, K. O., Dinastiya, E. M., Rusinov, G. L., Chupakhin, O. N., & Charushin, V. N. (2017). New "turn-off" fluorescence sensors to detect vapors of nitro-explosives on the basis of 4,6-bis[5-(heteroaryl)thiophen-2-yl] substituted 5-(4-tert-butylphenyl)pyrimidines. Arkivoc, 2017(5), 341-355. https://doi.org/10.24820/ark.5550190.p010.353

Vancouver

Author

Verbitskiy, Egor V. ; Baranova, Anna A. ; Yakovleva, Yuliya A. ; Chuvashov, Roman D. ; Khokhlov, Konstantin O. ; Dinastiya, Ekaterina M. ; Rusinov, Gennady L. ; Chupakhin, Oleg N. ; Charushin, Valery N. / New "turn-off" fluorescence sensors to detect vapors of nitro-explosives on the basis of 4,6-bis[5-(heteroaryl)thiophen-2-yl] substituted 5-(4-tert-butylphenyl)pyrimidines. In: Arkivoc. 2017 ; Vol. 2017, No. 5. pp. 341-355.

BibTeX

@article{fe72b3cb608e40608fe34f346d80ef82,
title = "New {"}turn-off{"} fluorescence sensors to detect vapors of nitro-explosives on the basis of 4,6-bis[5-(heteroaryl)thiophen-2-yl] substituted 5-(4-tert-butylphenyl)pyrimidines",
abstract = "New D–π–A–π–D type dyes based on compounds of the pyrimidine family, bearing thiophene linkers, have been designed, synthesized and characterized. The fluorescence behavior of these fluorophores have been evaluated for fifteen nitro compounds. The detection limits for these fluorophores in relation to nitro explosives in acetonitrile solution proved to be in the range from 10-1 to 10-6 mol/L. The sensor prototypes for handheld sniffer «Nitroscan» (Plant «Promautomatika», Ekaterinburg, Russia), based on these fluorophores, have been fabricated and used, as illustrated by reversible and sensitive fast detection of nitrobenzene in vapor phase concentrations up to 0.06 ppm.",
keywords = "Carbazoles, Fluorescence quenching, Nitroaromatic explosives, Pyrene, Pyrimidines, Triphenylamines",
author = "Verbitskiy, {Egor V.} and Baranova, {Anna A.} and Yakovleva, {Yuliya A.} and Chuvashov, {Roman D.} and Khokhlov, {Konstantin O.} and Dinastiya, {Ekaterina M.} and Rusinov, {Gennady L.} and Chupakhin, {Oleg N.} and Charushin, {Valery N.}",
year = "2017",
month = jan,
day = "1",
doi = "10.24820/ark.5550190.p010.353",
language = "English",
volume = "2017",
pages = "341--355",
journal = "Arkivoc",
issn = "1551-7004",
publisher = "Arkat USA",
number = "5",

}

RIS

TY - JOUR

T1 - New "turn-off" fluorescence sensors to detect vapors of nitro-explosives on the basis of 4,6-bis[5-(heteroaryl)thiophen-2-yl] substituted 5-(4-tert-butylphenyl)pyrimidines

AU - Verbitskiy, Egor V.

AU - Baranova, Anna A.

AU - Yakovleva, Yuliya A.

AU - Chuvashov, Roman D.

AU - Khokhlov, Konstantin O.

AU - Dinastiya, Ekaterina M.

AU - Rusinov, Gennady L.

AU - Chupakhin, Oleg N.

AU - Charushin, Valery N.

PY - 2017/1/1

Y1 - 2017/1/1

N2 - New D–π–A–π–D type dyes based on compounds of the pyrimidine family, bearing thiophene linkers, have been designed, synthesized and characterized. The fluorescence behavior of these fluorophores have been evaluated for fifteen nitro compounds. The detection limits for these fluorophores in relation to nitro explosives in acetonitrile solution proved to be in the range from 10-1 to 10-6 mol/L. The sensor prototypes for handheld sniffer «Nitroscan» (Plant «Promautomatika», Ekaterinburg, Russia), based on these fluorophores, have been fabricated and used, as illustrated by reversible and sensitive fast detection of nitrobenzene in vapor phase concentrations up to 0.06 ppm.

AB - New D–π–A–π–D type dyes based on compounds of the pyrimidine family, bearing thiophene linkers, have been designed, synthesized and characterized. The fluorescence behavior of these fluorophores have been evaluated for fifteen nitro compounds. The detection limits for these fluorophores in relation to nitro explosives in acetonitrile solution proved to be in the range from 10-1 to 10-6 mol/L. The sensor prototypes for handheld sniffer «Nitroscan» (Plant «Promautomatika», Ekaterinburg, Russia), based on these fluorophores, have been fabricated and used, as illustrated by reversible and sensitive fast detection of nitrobenzene in vapor phase concentrations up to 0.06 ppm.

KW - Carbazoles

KW - Fluorescence quenching

KW - Nitroaromatic explosives

KW - Pyrene

KW - Pyrimidines

KW - Triphenylamines

UR - http://www.scopus.com/inward/record.url?scp=85042458271&partnerID=8YFLogxK

U2 - 10.24820/ark.5550190.p010.353

DO - 10.24820/ark.5550190.p010.353

M3 - Article

AN - SCOPUS:85042458271

VL - 2017

SP - 341

EP - 355

JO - Arkivoc

JF - Arkivoc

SN - 1551-7004

IS - 5

ER -

ID: 39452710