New chalcogenide glasses of the system 0.5AgI-(0.5 - x)Sb ₂S _3-xMS containing cadmium, man- ganese, and zinc sulfides were obtained. The high purity of these materials and their glassy state were proved by X-ray analysis and X-ray fluorescence energy-dispersive spectroscopy. The impedance of the glasses obtained was measured within a wide range of frequencies, and the dependences of the conductivity on the composition of glasses were studied. New potentiometric sensors based the new glasses were developed, and an electrochemical experiment was carried out.