New Polymorph of Tetrakis(pentafluorophenyl)diboroxane (C6F5)2BOB(C6F5)2

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New Polymorph of Tetrakis(pentafluorophenyl)diboroxane (C₆F₅)₂BOB(C₆F₅)₂. / Gugin, N. Y.; Virovets, A. V.; Peresypkina, E. V.; Timoshkin, A. Y.

In: Russian Journal of General Chemistry, Vol. 90, No. 12, 12.2020, p. 2528-2530.

Research output: Contribution to journal › Article › peer-review

Author

Gugin, N. Y. ; Virovets, A. V. ; Peresypkina, E. V. ; Timoshkin, A. Y. / New Polymorph of Tetrakis(pentafluorophenyl)diboroxane (C₆F₅)₂BOB(C₆F₅)₂. In: Russian Journal of General Chemistry. 2020 ; Vol. 90, No. 12. pp. 2528-2530.

BibTeX

@article{7c436ba88b9741babb4ef856f76b3bd5,

title = "New Polymorph of Tetrakis(pentafluorophenyl)diboroxane (C6F5)2BOB(C6F5)2",

abstract = "Abstract: The crystal structure of a new polymorphic modification oftetrakis(pentafluorophenyl)diboroxane(C6F5)2BOB(C6F5)2was determined by X-ray single crystal structure analysis. A comparison of thecalculated crystal densities of the monoclinic and triclinic modifications at150 K suggests the metastability of the monoclinic modification. Molecules ofthe different polymorphic modifications have similar characteristics andconformations, while the polymorphism manifests itself primarily in differentcrystal packings.",

keywords = "molecular structure, polymorphism, tetrakis(pentafluorophenyl)diboroxane",

author = "Gugin, {N. Y.} and Virovets, {A. V.} and Peresypkina, {E. V.} and Timoshkin, {A. Y.}",

note = "Funding Information: The work was financially supported by the Russian Science Foundation (grant no. 18-13-00196). Publisher Copyright: {\textcopyright} 2020, Pleiades Publishing, Ltd. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.",

year = "2020",

month = dec,

doi = "10.1134/S1070363220120348",

language = "English",

volume = "90",

pages = "2528--2530",

journal = "Russian Journal of General Chemistry",

issn = "1070-3632",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

number = "12",

}

RIS

TY - JOUR

T1 - New Polymorph of Tetrakis(pentafluorophenyl)diboroxane (C6F5)2BOB(C6F5)2

AU - Gugin, N. Y.

AU - Virovets, A. V.

AU - Peresypkina, E. V.

AU - Timoshkin, A. Y.

N1 - Funding Information: The work was financially supported by the Russian Science Foundation (grant no. 18-13-00196). Publisher Copyright: © 2020, Pleiades Publishing, Ltd. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.

PY - 2020/12

Y1 - 2020/12

N2 - Abstract: The crystal structure of a new polymorphic modification oftetrakis(pentafluorophenyl)diboroxane(C6F5)2BOB(C6F5)2was determined by X-ray single crystal structure analysis. A comparison of thecalculated crystal densities of the monoclinic and triclinic modifications at150 K suggests the metastability of the monoclinic modification. Molecules ofthe different polymorphic modifications have similar characteristics andconformations, while the polymorphism manifests itself primarily in differentcrystal packings.

AB - Abstract: The crystal structure of a new polymorphic modification oftetrakis(pentafluorophenyl)diboroxane(C6F5)2BOB(C6F5)2was determined by X-ray single crystal structure analysis. A comparison of thecalculated crystal densities of the monoclinic and triclinic modifications at150 K suggests the metastability of the monoclinic modification. Molecules ofthe different polymorphic modifications have similar characteristics andconformations, while the polymorphism manifests itself primarily in differentcrystal packings.

KW - molecular structure

KW - polymorphism

KW - tetrakis(pentafluorophenyl)diboroxane

UR - http://www.scopus.com/inward/record.url?scp=85100515946&partnerID=8YFLogxK

U2 - 10.1134/S1070363220120348

DO - 10.1134/S1070363220120348

M3 - Article

AN - SCOPUS:85100515946

VL - 90

SP - 2528

EP - 2530

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 12

ER -

ID: 74538406