Abstract: Electrochemical methods of analysis are usually characterized by high sensitivity, ease of automation, and a wide range of analytes and test samples. The development of electrochemical methods of analysis at the present stage is mostly determined by the creation of new nanostructured electrode materials with electrocatalytic properties. The use of such materials ensures an increase in the sensitivity and selectivity of the determination of a number of analytes. Another conventional way to decreasing the limit of detection for electrochemically active substances is the development of new measurement methods for improving the signal-to-noise ratio in nonequilibrium electrochemical methods of analysis. This article is devoted to the consideration of some new electrode materials and methods of electrochemical measurements.