New Bis(salicylideneiminate) Nickel(II) Complexes with Carboxyethylene Linker Connecting Imine Groups and Their Electrochemical Polymerization

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New Bis(salicylideneiminate) Nickel(II) Complexes with Carboxyethylene Linker Connecting Imine Groups and Their Electrochemical Polymerization. / Samokhvalova, S. A.; Ershov, V. A.; Lukyanov, D. A.; Vlasov, P. S.; Levin, O. V.

In: Russian Journal of General Chemistry, Vol. 89, No. 4, 01.04.2019, p. 852-855.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{a8689d92b5784ed4bfcc41b6fdbac5e2,

title = "New Bis(salicylideneiminate) Nickel(II) Complexes with Carboxyethylene Linker Connecting Imine Groups and Their Electrochemical Polymerization",

abstract = "New nickel(II) bis(salicylideneiminate) complexes with carboxyethylene linker connecting imine groups were obtained. Polymer films based on these complexes were synthesized by electrochemical polymerization. When studying ionic transport in polymer films using cyclic voltammetry and microgravimetry, it was found that during oxidation, polymers pass into a self-doped state, in which a positive charge on the polymer chain is compensated by a negative charge of the carboxyl group, and a cation, forming an ionic pair with this group in neutral polymer form, leaves the film.",

keywords = "electrochemical polymerization, ion transport, salen complexes, Schiff bases, self-doping, FILMS, REDUCTION, SALEN, REDOX, HYDROGEN-PEROXIDE",

author = "Samokhvalova, {S. A.} and Ershov, {V. A.} and Lukyanov, {D. A.} and Vlasov, {P. S.} and Levin, {O. V.}",

year = "2019",

month = apr,

day = "1",

doi = "10.1134/S1070363219040352",

language = "English",

volume = "89",

pages = "852--855",

journal = "Russian Journal of General Chemistry",

issn = "1070-3632",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

number = "4",

}

RIS

TY - JOUR

T1 - New Bis(salicylideneiminate) Nickel(II) Complexes with Carboxyethylene Linker Connecting Imine Groups and Their Electrochemical Polymerization

AU - Samokhvalova, S. A.

AU - Ershov, V. A.

AU - Lukyanov, D. A.

AU - Vlasov, P. S.

AU - Levin, O. V.

PY - 2019/4/1

Y1 - 2019/4/1

N2 - New nickel(II) bis(salicylideneiminate) complexes with carboxyethylene linker connecting imine groups were obtained. Polymer films based on these complexes were synthesized by electrochemical polymerization. When studying ionic transport in polymer films using cyclic voltammetry and microgravimetry, it was found that during oxidation, polymers pass into a self-doped state, in which a positive charge on the polymer chain is compensated by a negative charge of the carboxyl group, and a cation, forming an ionic pair with this group in neutral polymer form, leaves the film.

AB - New nickel(II) bis(salicylideneiminate) complexes with carboxyethylene linker connecting imine groups were obtained. Polymer films based on these complexes were synthesized by electrochemical polymerization. When studying ionic transport in polymer films using cyclic voltammetry and microgravimetry, it was found that during oxidation, polymers pass into a self-doped state, in which a positive charge on the polymer chain is compensated by a negative charge of the carboxyl group, and a cation, forming an ionic pair with this group in neutral polymer form, leaves the film.

KW - electrochemical polymerization

KW - ion transport

KW - salen complexes

KW - Schiff bases

KW - self-doping

KW - FILMS

KW - REDUCTION

KW - SALEN

KW - REDOX

KW - HYDROGEN-PEROXIDE

UR - http://www.scopus.com/inward/record.url?scp=85067677368&partnerID=8YFLogxK

UR - http://www.mendeley.com/research/new-bissalicylideneiminate-nickelii-complexes-carboxyethylene-linker-connecting-imine-groups-electro

U2 - 10.1134/S1070363219040352

DO - 10.1134/S1070363219040352

M3 - Article

AN - SCOPUS:85067677368

VL - 89

SP - 852

EP - 855

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 4

ER -

ID: 43359066