Research output: Contribution to journal › Article › peer-review
Nd3+ concentration effect on luminescent properties of MgAl2O4 nanopowders synthesized by modified Pechini method. / Golyeva, E. V.; Vaishlia, E. I.; Kurochkin, M. A.; Kolesnikov, E. Yu; Lähderanta, E.; Semencha, A. V.; Kolesnikov, I. E.
In: Journal of Solid State Chemistry, Vol. 289, 121486, 09.2020.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Nd3+ concentration effect on luminescent properties of MgAl2O4 nanopowders synthesized by modified Pechini method
AU - Golyeva, E. V.
AU - Vaishlia, E. I.
AU - Kurochkin, M. A.
AU - Kolesnikov, E. Yu
AU - Lähderanta, E.
AU - Semencha, A. V.
AU - Kolesnikov, I. E.
N1 - Publisher Copyright: © 2020 Elsevier Inc.
PY - 2020/9
Y1 - 2020/9
N2 - In this paper, the concentration series of MgAl2O4:Nd3+ nanocrystalline powders have been synthesized by modified Pechini method. Neodymium doping concentration was varied within range of 0.05–5 at.%. The obtained samples have been analyzed using the various experimental methods: X-Ray diffraction, scanning electron microscopy, energy dispersive X-Ray spectroscopy, as well as steady-state and kinetics photoluminescence spectroscopy. According to XRD, all synthesized samples are monophasic without any structural impurities. The doping concentration effect on the luminescent characteristics of MgAl2O4:Nd3+ nanocrystalline particles has been studied in terms of emission intensity and lifetime. The optimal doping Nd3+ concentration was determined to be 0.1 at.%. Concentration quenching in MgAl2O4:Nd3+ powders occurred via energy transfer among the nearest neighbor ions. Performed studies shed the light on behavior of Nd3+ ions in nanoscale magnesium aluminum spinel.
AB - In this paper, the concentration series of MgAl2O4:Nd3+ nanocrystalline powders have been synthesized by modified Pechini method. Neodymium doping concentration was varied within range of 0.05–5 at.%. The obtained samples have been analyzed using the various experimental methods: X-Ray diffraction, scanning electron microscopy, energy dispersive X-Ray spectroscopy, as well as steady-state and kinetics photoluminescence spectroscopy. According to XRD, all synthesized samples are monophasic without any structural impurities. The doping concentration effect on the luminescent characteristics of MgAl2O4:Nd3+ nanocrystalline particles has been studied in terms of emission intensity and lifetime. The optimal doping Nd3+ concentration was determined to be 0.1 at.%. Concentration quenching in MgAl2O4:Nd3+ powders occurred via energy transfer among the nearest neighbor ions. Performed studies shed the light on behavior of Nd3+ ions in nanoscale magnesium aluminum spinel.
KW - Concentration quenching
KW - Lifetime
KW - Luminescence
KW - MgAlO
KW - Nanopowders
KW - Neodymium
UR - http://www.scopus.com/inward/record.url?scp=85087105911&partnerID=8YFLogxK
U2 - 10.1016/j.jssc.2020.121486
DO - 10.1016/j.jssc.2020.121486
M3 - Article
VL - 289
JO - Journal of Solid State Chemistry
JF - Journal of Solid State Chemistry
SN - 0022-4596
M1 - 121486
ER -
ID: 78516157