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N-Boc-α-diazo glutarimide as efficient reagent for assembling N-heterocycle-glutarimide diads via Rh(II)-catalyzed N–H insertion reaction. / Кантин, Григорий Павлович; Голубев, Павел Романович; Сапегин, Александр Владимирович; Бунев, Александр Сиясатович; Дарьин, Дмитрий Викторович.

In: Beilstein Journal of Organic Chemistry, Vol. 19, No. 19, 07.12.2023, p. 1841–1848.

Research output: Contribution to journal › Article › peer-review

Harvard

Кантин, ГП, Голубев, ПР, Сапегин, АВ, Бунев, АС & Дарьин, ДВ 2023, 'N-Boc-α-diazo glutarimide as efficient reagent for assembling N-heterocycle-glutarimide diads via Rh(II)-catalyzed N–H insertion reaction', Beilstein Journal of Organic Chemistry, vol. 19, no. 19, pp. 1841–1848. https://doi.org/10.3762/bjoc.19.136

APA

Кантин, Г. П., Голубев, П. Р., Сапегин, А. В., Бунев, А. С., & Дарьин, Д. В. (2023). N-Boc-α-diazo glutarimide as efficient reagent for assembling N-heterocycle-glutarimide diads via Rh(II)-catalyzed N–H insertion reaction. Beilstein Journal of Organic Chemistry, 19(19), 1841–1848. https://doi.org/10.3762/bjoc.19.136

Vancouver

Кантин ГП, Голубев ПР, Сапегин АВ, Бунев АС, Дарьин ДВ. N-Boc-α-diazo glutarimide as efficient reagent for assembling N-heterocycle-glutarimide diads via Rh(II)-catalyzed N–H insertion reaction. Beilstein Journal of Organic Chemistry. 2023 Dec 7;19(19):1841–1848. https://doi.org/10.3762/bjoc.19.136

Author

Кантин, Григорий Павлович ; Голубев, Павел Романович ; Сапегин, Александр Владимирович ; Бунев, Александр Сиясатович ; Дарьин, Дмитрий Викторович. / N-Boc-α-diazo glutarimide as efficient reagent for assembling N-heterocycle-glutarimide diads via Rh(II)-catalyzed N–H insertion reaction. In: Beilstein Journal of Organic Chemistry. 2023 ; Vol. 19, No. 19. pp. 1841–1848.

BibTeX

@article{2c76c6b61b2140348dc8be2f178d626d,
title = "N-Boc-α-diazo glutarimide as efficient reagent for assembling N-heterocycle-glutarimide diads via Rh(II)-catalyzed N–H insertion reaction",
abstract = "A technique has been proposed for incorporating a heterocyclic component into a glutarimide framework employing a Rh 2(esp) 2-catalyzed N-H insertion with the involvement of N-Boc-α-diazo glutarimide. The new diazo reagent is more stable, soluble and convenient to prepare than the previously suggested one. The approach permits the application of diverse heterocycles, including both aromatic and saturated NH-substrates. This yields structures that are appealing for generating cereblon ubiquitin-ligase ligands and for potential use in crafting PROTAC molecules. ",
author = "Кантин, {Григорий Павлович} and Голубев, {Павел Романович} and Сапегин, {Александр Владимирович} and Бунев, {Александр Сиясатович} and Дарьин, {Дмитрий Викторович}",
year = "2023",
month = dec,
day = "7",
doi = "10.3762/bjoc.19.136",
language = "English",
volume = "19",
pages = "1841–1848",
journal = "Beilstein Journal of Organic Chemistry",
issn = "1860-5397",
publisher = "Beilstein-Institut Zur Forderung der Chemischen Wissenschaften",
number = "19",

}

RIS

TY - JOUR

T1 - N-Boc-α-diazo glutarimide as efficient reagent for assembling N-heterocycle-glutarimide diads via Rh(II)-catalyzed N–H insertion reaction

AU - Кантин, Григорий Павлович

AU - Голубев, Павел Романович

AU - Сапегин, Александр Владимирович

AU - Бунев, Александр Сиясатович

AU - Дарьин, Дмитрий Викторович

PY - 2023/12/7

Y1 - 2023/12/7

N2 - A technique has been proposed for incorporating a heterocyclic component into a glutarimide framework employing a Rh 2(esp) 2-catalyzed N-H insertion with the involvement of N-Boc-α-diazo glutarimide. The new diazo reagent is more stable, soluble and convenient to prepare than the previously suggested one. The approach permits the application of diverse heterocycles, including both aromatic and saturated NH-substrates. This yields structures that are appealing for generating cereblon ubiquitin-ligase ligands and for potential use in crafting PROTAC molecules.

AB - A technique has been proposed for incorporating a heterocyclic component into a glutarimide framework employing a Rh 2(esp) 2-catalyzed N-H insertion with the involvement of N-Boc-α-diazo glutarimide. The new diazo reagent is more stable, soluble and convenient to prepare than the previously suggested one. The approach permits the application of diverse heterocycles, including both aromatic and saturated NH-substrates. This yields structures that are appealing for generating cereblon ubiquitin-ligase ligands and for potential use in crafting PROTAC molecules.

U2 - 10.3762/bjoc.19.136

DO - 10.3762/bjoc.19.136

M3 - Article

C2 - 38090627

VL - 19

SP - 1841

EP - 1848

JO - Beilstein Journal of Organic Chemistry

JF - Beilstein Journal of Organic Chemistry

SN - 1860-5397

IS - 19

ER -

ID: 114716030