Nanostructural models of micelles and primicellar aggregates

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Nanostructural models of micelles and primicellar aggregates. / Rusanov, A. I.; Grinin, A. P.; Kuni, F. M.; Shchekin, A. K.

In: Russian Journal of General Chemistry, Vol. 72, No. 4, 01.12.2002, p. 607-621.

Research output: Contribution to journal › Article › peer-review

Author

Rusanov, A. I. ; Grinin, A. P. ; Kuni, F. M. ; Shchekin, A. K. / Nanostructural models of micelles and primicellar aggregates. In: Russian Journal of General Chemistry. 2002 ; Vol. 72, No. 4. pp. 607-621.

BibTeX

@article{0aa7df83c19440b0a5c7c613c74297d0,

title = "Nanostructural models of micelles and primicellar aggregates",

abstract = "For the case of direct spherical micelles, two nanostructural models of molecular aggregates have been discussed: the classical drop model implying flexibility of hydrocarbon chains of molecules and their full immersion into the hydrocarbon core of an aggregate, and a quasi-drop model allowing partial outcropping of the chains in the strainless state from the core. For the sake of simplicity, a solution is assumed to contain only a single surfactant whose molecules possess only one, unbranched hydrocarbon radical. Within the frames of the models, the behavior of the chemical potential of surfactant molecules in a primicellar and micellar molecular aggregate has been analyzed, as well as the work of formation of the molecular aggregate as a function of the aggregation number and the solution concentration.",

author = "Rusanov, {A. I.} and Grinin, {A. P.} and Kuni, {F. M.} and Shchekin, {A. K.}",

year = "2002",

month = dec,

day = "1",

doi = "10.1023/A:1016348617547",

language = "English",

volume = "72",

pages = "607--621",

journal = "Russian Journal of General Chemistry",

issn = "1070-3632",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

number = "4",

}

RIS

TY - JOUR

T1 - Nanostructural models of micelles and primicellar aggregates

AU - Rusanov, A. I.

AU - Grinin, A. P.

AU - Kuni, F. M.

AU - Shchekin, A. K.

PY - 2002/12/1

Y1 - 2002/12/1

N2 - For the case of direct spherical micelles, two nanostructural models of molecular aggregates have been discussed: the classical drop model implying flexibility of hydrocarbon chains of molecules and their full immersion into the hydrocarbon core of an aggregate, and a quasi-drop model allowing partial outcropping of the chains in the strainless state from the core. For the sake of simplicity, a solution is assumed to contain only a single surfactant whose molecules possess only one, unbranched hydrocarbon radical. Within the frames of the models, the behavior of the chemical potential of surfactant molecules in a primicellar and micellar molecular aggregate has been analyzed, as well as the work of formation of the molecular aggregate as a function of the aggregation number and the solution concentration.

AB - For the case of direct spherical micelles, two nanostructural models of molecular aggregates have been discussed: the classical drop model implying flexibility of hydrocarbon chains of molecules and their full immersion into the hydrocarbon core of an aggregate, and a quasi-drop model allowing partial outcropping of the chains in the strainless state from the core. For the sake of simplicity, a solution is assumed to contain only a single surfactant whose molecules possess only one, unbranched hydrocarbon radical. Within the frames of the models, the behavior of the chemical potential of surfactant molecules in a primicellar and micellar molecular aggregate has been analyzed, as well as the work of formation of the molecular aggregate as a function of the aggregation number and the solution concentration.

UR - http://www.scopus.com/inward/record.url?scp=0141828411&partnerID=8YFLogxK

U2 - 10.1023/A:1016348617547

DO - 10.1023/A:1016348617547

M3 - Article

AN - SCOPUS:0141828411

VL - 72

SP - 607

EP - 621

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 4

ER -

ID: 26001928