Standard

Nanoscale hemispheres in novel mixed-valent uranyl chromate(V,VI), (C 3NH 10) 10[(UO 2) 13(Cr 12 5+O 42)(Cr 6+O 4) 6(H 2O) 6](H 2O) 6. / Siidra, Oleg I.; Nazarchuk, Evgeny V.; Petrunin, Anatoly A.; Kayukov, Roman A.; Krivovichev, Sergey V.

In: Inorganic Chemistry, Vol. 51, No. 17, 03.09.2012, p. 9162-9164.

Research output: Contribution to journal › Article › peer-review

Harvard

Siidra, OI, Nazarchuk, EV, Petrunin, AA, Kayukov, RA & Krivovichev, SV 2012, 'Nanoscale hemispheres in novel mixed-valent uranyl chromate(V,VI), (C 3NH 10) 10[(UO 2) 13(Cr 12 5+O 42)(Cr 6+O 4) 6(H 2O) 6](H 2O) 6', Inorganic Chemistry, vol. 51, no. 17, pp. 9162-9164. https://doi.org/10.1021/ic301288r

APA

Siidra, O. I., Nazarchuk, E. V., Petrunin, A. A., Kayukov, R. A., & Krivovichev, S. V. (2012). Nanoscale hemispheres in novel mixed-valent uranyl chromate(V,VI), (C 3NH 10) 10[(UO 2) 13(Cr 12 5+O 42)(Cr 6+O 4) 6(H 2O) 6](H 2O) 6. Inorganic Chemistry, 51(17), 9162-9164. https://doi.org/10.1021/ic301288r

Vancouver

Siidra OI, Nazarchuk EV, Petrunin AA, Kayukov RA, Krivovichev SV. Nanoscale hemispheres in novel mixed-valent uranyl chromate(V,VI), (C 3NH 10) 10[(UO 2) 13(Cr 12 5+O 42)(Cr 6+O 4) 6(H 2O) 6](H 2O) 6. Inorganic Chemistry. 2012 Sep 3;51(17):9162-9164. https://doi.org/10.1021/ic301288r

Author

Siidra, Oleg I. ; Nazarchuk, Evgeny V. ; Petrunin, Anatoly A. ; Kayukov, Roman A. ; Krivovichev, Sergey V. / Nanoscale hemispheres in novel mixed-valent uranyl chromate(V,VI), (C 3NH 10) 10[(UO 2) 13(Cr 12 5+O 42)(Cr 6+O 4) 6(H 2O) 6](H 2O) 6. In: Inorganic Chemistry. 2012 ; Vol. 51, No. 17. pp. 9162-9164.

BibTeX

@article{281b8105cdf8470c8778f55ea3e6060c,
title = "Nanoscale hemispheres in novel mixed-valent uranyl chromate(V,VI), (C 3NH 10) 10[(UO 2) 13(Cr 12 5+O 42)(Cr 6+O 4) 6(H 2O) 6](H 2O) 6",
abstract = "The structure of a novel mixed-valent chromium uranyl compound, (C 3NH 10) 10[(UO 2) 13(Cr 12 5+O 42)(Cr 6+O 4) 6(H 2O) 6](H 2O) 6 (1), obtained by the combination of a hydrothermal method and evaporation from aqueous solutions with isopropylammonium, contains uranyl chromate hemispheres with lateral dimensions of 18.9 × 18.5 {\AA} 2 and a height of about 8 {\AA}. The hemispheres are centered by a UO 8 hexagonal bipyramid surrounded by six dimers of Cr 5+O 5 square pyramids, UO 7 pentagonal bipyramids, and Cr 6+O 4 tetrahedra. The hemispheres are linked into two-dimensional layers so that two adjacent hemispheres are oriented in opposite directions relative to the plane of the layer. From a topological point of view, the hemispheres have the formula U 21Cr 23 and can be considered as derivatives of nanospherical cluster U 26Cr 36 composed of three-, four-, and five-membered rings.",
author = "Siidra, {Oleg I.} and Nazarchuk, {Evgeny V.} and Petrunin, {Anatoly A.} and Kayukov, {Roman A.} and Krivovichev, {Sergey V.}",
year = "2012",
month = sep,
day = "3",
doi = "10.1021/ic301288r",
language = "English",
volume = "51",
pages = "9162--9164",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "17",

}

RIS

TY - JOUR

T1 - Nanoscale hemispheres in novel mixed-valent uranyl chromate(V,VI), (C 3NH 10) 10[(UO 2) 13(Cr 12 5+O 42)(Cr 6+O 4) 6(H 2O) 6](H 2O) 6

AU - Siidra, Oleg I.

AU - Nazarchuk, Evgeny V.

AU - Petrunin, Anatoly A.

AU - Kayukov, Roman A.

AU - Krivovichev, Sergey V.

PY - 2012/9/3

Y1 - 2012/9/3

N2 - The structure of a novel mixed-valent chromium uranyl compound, (C 3NH 10) 10[(UO 2) 13(Cr 12 5+O 42)(Cr 6+O 4) 6(H 2O) 6](H 2O) 6 (1), obtained by the combination of a hydrothermal method and evaporation from aqueous solutions with isopropylammonium, contains uranyl chromate hemispheres with lateral dimensions of 18.9 × 18.5 Å 2 and a height of about 8 Å. The hemispheres are centered by a UO 8 hexagonal bipyramid surrounded by six dimers of Cr 5+O 5 square pyramids, UO 7 pentagonal bipyramids, and Cr 6+O 4 tetrahedra. The hemispheres are linked into two-dimensional layers so that two adjacent hemispheres are oriented in opposite directions relative to the plane of the layer. From a topological point of view, the hemispheres have the formula U 21Cr 23 and can be considered as derivatives of nanospherical cluster U 26Cr 36 composed of three-, four-, and five-membered rings.

AB - The structure of a novel mixed-valent chromium uranyl compound, (C 3NH 10) 10[(UO 2) 13(Cr 12 5+O 42)(Cr 6+O 4) 6(H 2O) 6](H 2O) 6 (1), obtained by the combination of a hydrothermal method and evaporation from aqueous solutions with isopropylammonium, contains uranyl chromate hemispheres with lateral dimensions of 18.9 × 18.5 Å 2 and a height of about 8 Å. The hemispheres are centered by a UO 8 hexagonal bipyramid surrounded by six dimers of Cr 5+O 5 square pyramids, UO 7 pentagonal bipyramids, and Cr 6+O 4 tetrahedra. The hemispheres are linked into two-dimensional layers so that two adjacent hemispheres are oriented in opposite directions relative to the plane of the layer. From a topological point of view, the hemispheres have the formula U 21Cr 23 and can be considered as derivatives of nanospherical cluster U 26Cr 36 composed of three-, four-, and five-membered rings.

UR - http://www.scopus.com/inward/record.url?scp=84865727923&partnerID=8YFLogxK

U2 - 10.1021/ic301288r

DO - 10.1021/ic301288r

M3 - Article

AN - SCOPUS:84865727923

VL - 51

SP - 9162

EP - 9164

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 17

ER -

ID: 9145009