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Monoprotonated Dimethyl Sulfoxide, [HOSMe2]+ : Synthesis, Crystal Structure, Spectroscopic and Theoretical Studies of [HOSMe2]2[OsCl6] ⋅ 2H2O. / Rudnitskaya, Olga V.; Tereshina, Tatiana A.; Dobrokhotova, Ekaterina V.; Kultyshkina, Ekaterina K.; Novikov, Alexander S.; Tskhovrebov, Alexander G.; Zubavichus, Yan V.; Khrustalev, Victor N.
In:
ChemistrySelect, Vol. 6, No. 21, 08.06.2021, p. 5211-5217.
Research output: Contribution to journal › Article › peer-review
Harvard
Rudnitskaya, OV, Tereshina, TA, Dobrokhotova, EV, Kultyshkina, EK
, Novikov, AS, Tskhovrebov, AG, Zubavichus, YV & Khrustalev, VN 2021, '
Monoprotonated Dimethyl Sulfoxide, [HOSMe2]+: Synthesis, Crystal Structure, Spectroscopic and Theoretical Studies of [HOSMe2]2[OsCl6] ⋅ 2H2O',
ChemistrySelect, vol. 6, no. 21, pp. 5211-5217.
https://doi.org/10.1002/slct.202100970,
https://doi.org/10.1002/slct.202100970,
https://doi.org/10.1002/slct.v6.21APA
Rudnitskaya, O. V., Tereshina, T. A., Dobrokhotova, E. V., Kultyshkina, E. K.
, Novikov, A. S., Tskhovrebov, A. G., Zubavichus, Y. V., & Khrustalev, V. N. (2021).
Monoprotonated Dimethyl Sulfoxide, [HOSMe2]+: Synthesis, Crystal Structure, Spectroscopic and Theoretical Studies of [HOSMe2]2[OsCl6] ⋅ 2H2O.
ChemistrySelect,
6(21), 5211-5217.
https://doi.org/10.1002/slct.202100970,
https://doi.org/10.1002/slct.202100970,
https://doi.org/10.1002/slct.v6.21Vancouver
Rudnitskaya OV, Tereshina TA, Dobrokhotova EV, Kultyshkina EK
, Novikov AS, Tskhovrebov AG et al.
Monoprotonated Dimethyl Sulfoxide, [HOSMe2]+: Synthesis, Crystal Structure, Spectroscopic and Theoretical Studies of [HOSMe2]2[OsCl6] ⋅ 2H2O.
ChemistrySelect. 2021 Jun 8;6(21):5211-5217.
https://doi.org/10.1002/slct.202100970,
https://doi.org/10.1002/slct.202100970,
https://doi.org/10.1002/slct.v6.21Author
Rudnitskaya, Olga V. ; Tereshina, Tatiana A. ; Dobrokhotova, Ekaterina V. ; Kultyshkina, Ekaterina K.
; Novikov, Alexander S. ; Tskhovrebov, Alexander G. ; Zubavichus, Yan V. ; Khrustalev, Victor N. /
Monoprotonated Dimethyl Sulfoxide, [HOSMe2]+ : Synthesis, Crystal Structure, Spectroscopic and Theoretical Studies of [HOSMe2]2[OsCl6] ⋅ 2H2O. In:
ChemistrySelect. 2021 ; Vol. 6, No. 21. pp. 5211-5217.
BibTeX
@article{0e050ce51a88448f901427fe3eed1885,
title = "Monoprotonated Dimethyl Sulfoxide, [HOSMe2]+: Synthesis, Crystal Structure, Spectroscopic and Theoretical Studies of [HOSMe2]2[OsCl6] ⋅ 2H2O",
abstract = "Complex [H(dmso)]2[OsIVCl6] ⋅ 2H2O (1) was synthesized by refluxing of [H(dmso)2]2[OsCl6] in concentrated HCl and characterized by the IR and UV/Vis spectroscopy and X-ray powder and single-crystal diffraction studies. In this complex, rare highly electrophilic [Me2S=O⋅⋅⋅H]+ cation is stabilized by multiple chalcogen bonds including bifurcated S⋅⋅⋅(Cl)3 and S⋅⋅⋅Cl non-covalent interactions. DFT calculations and topological analysis of the electron density distribution within the formalism of Bader's theory (QTAIM method) support the presence of intermolecular non-covalent interactions S⋅⋅⋅Cl and O⋅⋅⋅Cl in the solid state.",
keywords = "chalcogen bond, DFT calculations., hydroxy(dimethyl)sulfonium cation, IR spectroscopy, osmium, structure elucidation, COMPLEX, HYDROGEN-CHLORIDE, ACID, MOLECULAR-STRUCTURE, DIMETHYLSULFOXIDE, DFT calculations, BONDS",
author = "Rudnitskaya, {Olga V.} and Tereshina, {Tatiana A.} and Dobrokhotova, {Ekaterina V.} and Kultyshkina, {Ekaterina K.} and Novikov, {Alexander S.} and Tskhovrebov, {Alexander G.} and Zubavichus, {Yan V.} and Khrustalev, {Victor N.}",
note = "Publisher Copyright: {\textcopyright} 2021 Wiley-VCH GmbH",
year = "2021",
month = jun,
day = "8",
doi = "10.1002/slct.202100970",
language = "English",
volume = "6",
pages = "5211--5217",
journal = "ChemistrySelect",
issn = "2365-6549",
publisher = "Wiley-Blackwell",
number = "21",
}
RIS
TY - JOUR
T1 - Monoprotonated Dimethyl Sulfoxide, [HOSMe2]+
T2 - Synthesis, Crystal Structure, Spectroscopic and Theoretical Studies of [HOSMe2]2[OsCl6] ⋅ 2H2O
AU - Rudnitskaya, Olga V.
AU - Tereshina, Tatiana A.
AU - Dobrokhotova, Ekaterina V.
AU - Kultyshkina, Ekaterina K.
AU - Novikov, Alexander S.
AU - Tskhovrebov, Alexander G.
AU - Zubavichus, Yan V.
AU - Khrustalev, Victor N.
N1 - Publisher Copyright:
© 2021 Wiley-VCH GmbH
PY - 2021/6/8
Y1 - 2021/6/8
N2 - Complex [H(dmso)]2[OsIVCl6] ⋅ 2H2O (1) was synthesized by refluxing of [H(dmso)2]2[OsCl6] in concentrated HCl and characterized by the IR and UV/Vis spectroscopy and X-ray powder and single-crystal diffraction studies. In this complex, rare highly electrophilic [Me2S=O⋅⋅⋅H]+ cation is stabilized by multiple chalcogen bonds including bifurcated S⋅⋅⋅(Cl)3 and S⋅⋅⋅Cl non-covalent interactions. DFT calculations and topological analysis of the electron density distribution within the formalism of Bader's theory (QTAIM method) support the presence of intermolecular non-covalent interactions S⋅⋅⋅Cl and O⋅⋅⋅Cl in the solid state.
AB - Complex [H(dmso)]2[OsIVCl6] ⋅ 2H2O (1) was synthesized by refluxing of [H(dmso)2]2[OsCl6] in concentrated HCl and characterized by the IR and UV/Vis spectroscopy and X-ray powder and single-crystal diffraction studies. In this complex, rare highly electrophilic [Me2S=O⋅⋅⋅H]+ cation is stabilized by multiple chalcogen bonds including bifurcated S⋅⋅⋅(Cl)3 and S⋅⋅⋅Cl non-covalent interactions. DFT calculations and topological analysis of the electron density distribution within the formalism of Bader's theory (QTAIM method) support the presence of intermolecular non-covalent interactions S⋅⋅⋅Cl and O⋅⋅⋅Cl in the solid state.
KW - chalcogen bond
KW - DFT calculations.
KW - hydroxy(dimethyl)sulfonium cation
KW - IR spectroscopy
KW - osmium
KW - structure elucidation
KW - COMPLEX
KW - HYDROGEN-CHLORIDE
KW - ACID
KW - MOLECULAR-STRUCTURE
KW - DIMETHYLSULFOXIDE
KW - DFT calculations
KW - BONDS
UR - http://www.scopus.com/inward/record.url?scp=85108155992&partnerID=8YFLogxK
U2 - 10.1002/slct.202100970
DO - 10.1002/slct.202100970
M3 - Article
AN - SCOPUS:85108155992
VL - 6
SP - 5211
EP - 5217
JO - ChemistrySelect
JF - ChemistrySelect
SN - 2365-6549
IS - 21
ER -
